White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

Solar internal rotation rate and the latitudinal variation of the tachocline

A new set of accurately measured frequencies of solar oscillations is used to infer the rotation rate inside the Sun, as a function of radial distance as well as latitude. We have adopted a regularized least-squares technique with iterative refinement for both 1.5D inversion, using the splitting coefficients, and 2D inversion using individual m splittings. The inferred rotation rate agrees well with earlier estimates showing a shear layer just below the surface and another one around the base of the convection zone. The tachocline or the transition layer where the rotation rate changes from differential rotation in the convection zone to an almost latitudinally independent rotation rate in the radiative interior is studied in detail. No compelling evidence for any latitudinal variation in the position and width of the tachocline is found, although it appears that the tachocline probably shifts to a slightly larger radial distance at higher latitudes and possibly also becomes thicker. However, these variations are within the estimated errors and more accurate data would be needed to make a definitive statement about latitudinal variations.     

Prediction of overland flow and seepage zones associated with the interaction of multiple infiltration devices (cascading infiltration devices)

Infiltration devices are traditionally evaluated as standalone entities that do not interact with each other. A model is outlined that will allow interactions between proposed infiltration devices to be predicted prior to a development commencing. The model allows prediction of seepage into downslope devices and the assessment of the locations where the combined ground‐water mound will reach the surface and result in overland flow. The volume of overland flow discharged by the seepage zone may exceed the overland and piped flow received by the infiltration devices. Copyright © 2007 John Wiley & Sons, Ltd.     

Possibility of Excitation of Low-ℓ P-Modes by Energetic Solar Transients

We examine the temporal variation of power in low-ℓ modes using GONG data for the period of May 1995–October 2005 and compare this with disk-integrated flare and CME indices. A poor correlation between the running means of Flare Index and mode power is found. A similar result is found for CME Index also. Variations in the running mean mode power corresponding to ℓ = 0 modes with different radial orders are generally stochastic in nature. This behaviour is also reflected in the distribution of mode power.     

Seismic view of the solar interior

The interior of the Sun is not directly observable to us. Nevertheless, it is possible to infer the physical conditions prevailing in the solar interior with the help of theoretical models coupled with observational input provided by measured frequencies of solar oscillations. The frequencies of these solar oscillations depend on the internal structure and dynamics of the Sun and from the knowledge of these frequencies it is possible to infer the internal structure as well as the large scale flows inside the Sun, in the same way as the observations of seismic waves on the surface of Earth help us in the study of its interior. With the accumulation of seismic data over the last six years it has also become possible to study temporal variations in the solar interior. Some of these seismic inferences would be described.     

A study of possible temporal and latitudinal variations in the properties of the solar tachocline

Temporal variations of the structure and the rotation rate of the solar tachocline region are studied using helioseismic data from the Global Oscillation Network Group (GONG) and the Michelson Doppler Imager (MDI) obtained during the period 1995–2000. We do not find any significant temporal variation in the depth of the convection zone, the position of the tachocline or the extent of overshoot below the convection zone. No systematic variation in any other properties of the tachocline, like width, etc., is found either. The possibility of periodic variations in these properties is also investigated. Time-averaged results show that the tachocline is prolate with a variation of about 0.02 R_⊙ in its position. Neither the depth of the convection zone nor the extent of overshoot shows any significant variation with latitude.     

Waves in the sunspot umbra

The magnetoacoustic modes excited in a thermally conducting polytropic fluid layer in the presence of a vertical magnetic field are examined with a view to classify them with the help of phase diagrams. The possibility of identifying the umbral flashes with overstable magnetoacoustic modes is explored.     

Waves in the sunspot penumbra

The stability of a plane-parallel polytropic fluid layer in the presence of a uniform horizontal magnetic field is investigated to explore the possibility of identifying the running penumbral waves and the penumbral filaments with different types of instabilities.     

Possible solar cycle variations in the convection zone

Using data from the Global Oscillations Network Group (GONG) that covers the period from 1995 to 1998 we study the change in frequencies of solar oscillations with solar activity. From these frequencies we attempt to determine any possible variation in solar structure with solar activity. We do not find any evidence of a change in the convection zone depth or extent of overshoot below the convection zone during the solar cycle.