On the survivability of an enantiomeric excess of amino acids in comet nuclei during the decay of26Al and other radionuclides

We present a computer model calculation for the racemization of a possible excess of amino acids in the icy fraction of comet nuclei bring about by ionizing radiation released during the decay of²⁶Al,⁴⁰K,²³⁵U,²³⁸U and²³²Th. The model takes into account a total of 110 chemical reactions, of which 91 are needed to explain the radiation chemical processing of the major constituents of comet nuclei (Navarro-Gonzálezet al., 1992) and 19 are necessary to simulate the radiolysis of glycine/alanine mixtures in aqueous solutions (Navarro-Gonzálezet al., 1994 and 1996). It is predicted that an enantiomeric excess of alanine would not be destroyed by radioracemization during the decay of embedded radionuclides. Nevertheless, this enantiomeric excess could be attenuated by the formation of racemic amino acids in the interior of comet nuclei as a result of the radiation-induced polymerization of HCN.     

Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain)

Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of the Iberian Pyrite Belt. Concentrations were 19–994 mg kg⁻¹ for As, 41–4,890 mg kg⁻¹ for Pb, 95–897 mg kg⁻¹ for Zn and of 27–1,160 mg kg⁻¹ for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input, such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction. According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn, Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where the concentrations are not so high.     

Response of zooid size in Cupuladria exfragminis (Bryozoa) to simulated upwelling temperatures

We investigate the effect of the temperature–size rule upon zooids of the tropical American bryozoan Cupuladria exfragminis. Results show that mean zooid length, zooid width and zooid area vary significantly between clonal replicates of C. exfragminis kept under different controlled temperature conditions. Significantly larger zooids are produced during times of lowered water temperature that are comparable with the temperatures that occur during seasonal upwelling along the Pacific coast of Panama where the animal lives in abundance. Interpolation of data suggests that a drop of 1 °C causes a 5% increase in zooid size, and that almost all variation in zooid size in natural populations can be explained by temperature. Results are discussed in context of the potential use of zooid size variation in cupuladriid bryozoans to measure the strength of seasonal upwelling in ancient seas by analysing zooid size changes in fossil colonies. The technique of cloning cupuladriid colonies by fragmentation is also discussed with reference to its benefits in experimental studies where genotypes need to be controlled or replicated.     

Hydrochemical and isotopical tracers in the lacustrine aquifer of the Cerro Prieto area, Baja California, México

A series of patterns in the chemical and isotopic composition of the groundwater of the Cerro Prieto area have been recognized. These patterns were used to define four hydrochemical and isotopical zones in the area. One of these areas located at the east side was found to be the source of recharge, while another in the central part is where an older aquifer exist in lacustrine deposits. The low permeability of the area causes the aquifer to act as an aquitard, which at least is partly surrounded by an interface zone where mixing of waters occurs. Tritium and radiocarbon method revealed that the aquitard is an isolate system whose residence time is of 32 ka.     

Yucatán karst features and the size of Chicxulub crater

The buried Chicxulub impact structure is marked by a dramatic ring of sinkholes (called cenotes if containing water), and adjacent less prominent partial rings, which have been shown to coincide with maxima in horizontal gravity gradients and a topographic depression. These observations, along with the discreteness and spacing of the features, suggest a formation mechanism involving faulting in the outer slump zone of the crater, which would thus have a diameter of approximately 180 km.
An opposing view, based primarily on the interpretation of gravity data, is that (he crater is much larger than the cenote ring implies. Given the association of the known cenote ring with faults, we here examine northern Yucatan for similar rings in gravity, surface features and elevation, which we might expect to be associated with outer concentric faults in the case of a larger, possibly multiring, structure.
No such outer rings have been found, although definite patterns are seen in the distribution of karst features outside the crater rim. We explain these patterns as resulting mainly from deformation related to the block fault zone that parallels tbe shelf edge of eastern Yucatan.     

A calderas field at the Marifil Formation, new volcanogenic interpretation, Norpatagonian Massif, Argentina

Major volcanogenic structures within the Marifil Formation allowed to determine the location of a claderas field that spreads along 400 kilometers. This field has at least three large calderas with diameters near to 100 kilometers, recognizable by regional distribution of associated dikes and rhyolite lava flows present at the caldera border that separates a monotonous ignimbritic plateau from a depressed (150 meters) inner volcanic collapsed caldera. The Marifil ignimbritic plateau cover more than 50,000 square kilometers with thicknesses that reach 800 meters. Associated with these plateau ignimbrites there is an important fluorite mineralization.     

Mid‐Miocene initiation of E‐W extension and recoupling of the Himalaya

The Tibetan plateau is host to numerous ~N‐S striking graben that have accommodated E‐W directed extension. The development of these structures has been interpreted to reflect a variety of different geological processes including plateau collapse, oroclinal bending or mid‐to‐lower crustal flow. New ⁴⁰Ar/³⁹Ar thermochronology and quartz c‐axis data from the Thakkhola graben of west‐central Nepal show that E‐W extension was ongoing at least locally by the early Miocene (ca. 17 Ma). Our new, and previously published chronologic information on the initiation of graben across the orogen shows that they typically developed immediately after cessation of the South Tibetan detachment system, a structural network that facilitated differential southward movement of the upper and middle crust. We interpret this fundamental switch in orogen kinematics to reflect recoupling of the middle and upper Himalayan crust such that the subsequent widespread flow of the mid‐to‐lower crust out of the system to the east forced brittle accommodation in the upper crust.     

The Juchatengo complex: an upper-level ophiolite assemblage of late Paleozoic age in Oaxaca,southern Mexico

International Journal of Earth Sciences - The Juchatengo complex (JC) suite is located between the Proterozoic Oaxacan complex to the north and the Xolapa complex to the south, and was amalgamated...