Geology and Metal Contents of the Ruttan volcanogenic massive sulfide deposit, northern Manitoba, Canada

The Paleoproterozoic Ruttan Cu–Zn volcanogenic massive-sulfide (VMS) deposit is a large, relatively low grade, bimodal-siliciclastic type deposit in the Rusty Lake volcanic belt of northern Manitoba. The deposit contained over 82.8 million tonnes of massive sulfide, of which 55.7 million tonnes were mined from 1973 to 2002. The deposit consists of a series of moderately to steeply dipping, south-facing lenses that extend along strike at the surface for 1.1 km and to a depth of 1.0 km. These lenses occur within a steeply dipping, bimodal volcanic, volcaniclastic and siliciclastic sequence. In the immediate mine area, transitional calc-alkalic to high-silica (tholeiitic), felsic, and intermediate volcanic/volcaniclastic rocks of the Mine Sequence are host to, and intercalated with, the massive-sulfide lenses. Transitional tholeiitic to calc-alkalic basalt and andesite are present in the footwall sequence, approximately 500 m down-section from the ore horizon. The overlying rocks are predominantly fine-grained volcaniclastics and siliciclastics, but include polyfragmental agglomerate that contains mafic bombs and scoriaceous felsic fragments. Syn-depositional felsic and mafic dikes, sills, and apophyses are ubiquitous throughout the Mine Sequence, including the ore lenses, indicating continued, near-vent magmatism, and volcanism during ore formation. Fabrics in altered hostrocks have consistent, down-plunge stretching lineations to the SSE that suggest the deposit has been elongated by a factor of ~1.2–1.5; otherwise, the deposit is remarkably undeformed. Syn- and post-depositional faults in the mine area have relatively minor displacements up to tens of meters. Proximal (within 200 m) footwall rocks exhibit moderate to strong chloritization, characterized by the upper greenschist to lower amphibolite facies assemblages that include cordierite–almandine–andalusite–sillimanite–biotite ± staurolite ± anthophyllite ± talc, and local silicification. The proximal hanging wall rocks are characterized by sericite ± gahnite alteration, which is restricted to within approximately 75 m of the uppermost lenses. Additional gangue minerals are anhydrite and carbonate minerals (siderite, dolomite, ankerite, and calcite), as well as chlorite, sericite, biotite, talc, and quartz. Carbonate (excluding siderite), potassium feldspar, silicification and epidotization are common distal alteration zones in the footwall to the Mine Sequence several kilometers to the northeast. There are three principal groups of massive sulfide lenses; the East lenses, the West lenses, and the Western Anomaly lenses to the far west. In general, Cu is relatively enriched at the stratigraphic base and in the center of the deposit, whereas Zn is enriched upsection and at the outer margins. Some of the Zn-rich ore exhibits primary mineralogical layering. Parts of the West and Western Anomaly lenses show two layers with Cu-rich bases and Zn-rich tops. The massive sulfide is typically 10–40-m thick; one area along the margin of the main lenses is over 130-m thick and may represent deposition adjacent to a syn-depositional fault. The main sulfide phases are pyrite, pyrrhotite, chalcopyrite, sphalerite, and galena, with tetrahedrite as the most abundant trace phase. Gahnite is ubiquitous in the chlorite-rich assemblages adjacent to the ore lenses. The average base, precious and trace metal contents estimated from Cu and Zn concentrates, and from millhead grades and recoveries. Metals easily transported as chloride and bisulfide complexes in hydrothermal fluids including: Pb, Ag, In, Cu, Cd, Au, and Zn are enriched by 1.5–2.5 orders of magnitude in comparison to the bulk continental crust. Other elements such as Sn, Mo, and As are at near-crustal concentrations, whereas Mn, Ga, and Co are significantly depleted in comparison to the crust. Calculated metal concentrations in the average hydrothermal fluid based on the average metal contents are comparable to, or higher than those measured at sediment covered ridge hydrothermal systems, which precipitate much of their metal budget in the subsurface. Average rare earth element contents for the sulfide are light rare earth element enriched (La_N/Yb_N=22) and range from 0.45 to 0.02x chondritic values, with a moderate negative Eu anomaly (Eu*=0.51). Metal and trace element contents in the Ruttan exhalite horizon, and in proximal (within 1–2 km) exhalites along strike from the 0.6 million tonne Dar-2 Cu–Zn deposit 12 km south of Ruttan, have positive Eu anomalies, whereas negative Eu anomalies are present at distance. The positive Eu anomalies reflect high temperature paleoseafloor hydrothermal venting and precipitation of Eu²⁺-enriched clays and possibly carbonates, and indicate proximity to base-metal deposits. Silver and lead are also enriched in the exhalites near the deposits, whereas Mn is enriched at ~1–3 km along strike, but not consistently. Editorial handling: B. Gemmel An erratum to this article is available at .     

Origin of granite at Cabo de Santo Agostinho,Northeast Brazil

A 4 km² exposure of shallowly-emplaced leucogranite on the Atlantic coast at Cabo de Santo Agostinho, 30 km south of Recife, Brazil has been extensively studied chemically and isotopically. Twenty-three major-element analyses indicate that the Cabo granite ranges from peralkaline to peraluminous; Na₂O+K₂O is very high (7.4 to 10.4 wt.%), with CaO low (0.3%) and MgO vanishing (<0.06%). Microprobe analyses confirm the presence of arfvedsonite (biotite absent), and nearly total absence of plagioclase. The rocks are moderately to highly enriched in LREE (La 45 to 350 times chondritic), with extremely pronounced negative Eu anomalies (Eu/Eu^*=0.02 to 0.07). Whole-rock ¹⁸O is consistent at +8.5±0.3%._oSMOW A Rb-Sr isochron age of isotopically slightly disturbed samples is 104.8±1.8 Ma, with initial⁸⁷Sr/⁸⁶Sr=0.7084±0.0011. Sr is depleted (2–20 ppm) but Ba is 200–750 ppm.Crystallization path calculations and petrographic observations suggest that magma formed at a pressure close to 6 kbar but rose to a crustal level equivalent to roughly 1 kbar. Quartz, the liquidus phase at moderate H₂O concentrations and pressures above 2 kbar, was resorbed during decompression as the magma moved upwards. Ultimately, quartz and alkali feldspar coprecipitated. Feldspar was not retained in the source rock nor removed early from the fractionating magma. Therefore the strong negative Eu anomaly and low Sr abundance are characteristics inherited from the source. A high H₂O concentration necessary for a large degree of melting was lacking, hence the Cabo magma composition must reflect a small degree of partial melting of a rather quartz-rich rock such as a feldspathic arenite.In a pre-drift reconstruction of Gondwanaland, the Cabo granite fits on the southernmost and youngest end of the trend of the Niger-Nigerian igneous centers with which it has close affinity. The Cabo granite occupies the western end of the trace of the ancestral Ascension mantle plume which presumably served as the heat source.     

Chemostratigraphy of the Tamengo Formation (Corumbá Group,Brazil): A contribution to the calibration of the Ediacaran carbon-isotope curve

The Corumbá Group, cropping out in the southern Paraguay Belt in Brazil, is one of the most complete Ediacaran sedimentary archives of palaeogeographic, climatic, biogeochemical and biotic evolution in southwestern Gondwana. The unit hosts a rich fossil record, including acritarchs, vendotaenids (Vendotaenia, Eoholynia), soft-bodied metazoans (Corumbella) and skeletal fossils (Cloudina, Titanotheca). The Tamengo Formation, made up mainly of limestones and marls, provides a rich bio- and chemostratigraphic record. Several outcrops, formerly assigned to the Cuiabá Group, are here included in the Tamengo Formation on the basis of lithological and chemostratigraphical criteria. High-resolution carbon isotopic analyses are reported for the Tamengo Formation, showing (from base to top): (1) a positive δ¹³C excursion to +4‰ PDB above post-glacial negative values, (2) a negative excursion to −3.5‰ associated with a marked regression and subsequent transgression, (3) a positive excursion to +5.5‰, and (4) a plateau characterized by δ¹³C around +3‰. A U-Pb SHRIMP zircon age of an ash bed interbedded in the upper part of the δ¹³C positive plateau yielded 543 ± 3 Ma, which is considered as the depositional age ( Babinski et al., 2008a). The positive plateau in the upper Tamengo Formation and the preceding positive excursion are ubiquitous features in several successions worldwide, including the Nama Group (Namibia), the Dengying Formation (South China) and the Nafun and Ara groups (Oman). This plateau is constrained between 542 and 551 Ma, thus consistent with the age of the upper Tamengo Formation. The negative excursion of the lower Tamengo Formation may be correlated to the Shuram–Wonoka negative anomaly, although δ¹³C values do not fall beyond −3.5‰ in the Brazilian sections. Sedimentary breccias occur just beneath this negative excursion in the lower Tamengo Formation. One possible interpretation of the origin of these breccias is a glacioeustatic sea-level fall, but a tectonic interpretation cannot be completely ruled out.     

Holocene sea-level changes along the North Carolina Coastline and their implications for glacial isostatic adjustment models

We have synthesized new and existing relative sea-level (RSL) data to produce a quality-controlled, spatially comprehensive database from the North Carolina coastline. The RSL database consists of 54 sea-level index points that are quantitatively related to an appropriate tide level and assigned an error estimate, and a further 33 limiting dates that confine the maximum and minimum elevations of RSL. The temporal distribution of the index points is very uneven with only five index points older than 4000 cal a BP, but the form of the Holocene sea-level trend is constrained by both terrestrial and marine limiting dates. The data illustrate RSL rapidly rising during the early and mid Holocene from an observed elevation of ?35.7 ± 1.1 m MSL at 11062–10576 cal a BP to ?4.2 m ± 0.4 m MSL at 4240–3592 cal a BP.We restricted comparisons between observations and predictions from the ICE-5G(VM2) with rotational feedback Glacial Isostatic Adjustment (GIA) model to the Late Holocene RSL (last 4000 cal a BP) because of the wealth of sea-level data during this time interval. The ICE-5G(VM2) model predicts significant spatial variations in RSL across North Carolina, thus we subdivided the observations into two regions. The model forecasts an increase in the rate of sea-level rise in Region 1 (Albemarle, Currituck, Roanoke, Croatan, and northern Pamlico sounds) compared to Region 2 (southern Pamlico, Core and Bogue sounds, and farther south to Wilmington). The observations show Late Holocene sea-level rising at 1.14 ± 0.03 mm year^?1 and 0.82 ± 0.02 mm year^?1 in Regions 1 and 2, respectively. The ICE-5G(VM2) predictions capture the general temporal trend of the observations, although there is an apparent misfit for index points older than 2000 cal a BP. It is presently unknown whether these misfits are caused by possible tectonic uplift associated with the mid-Carolina Platform High or a flaw in the GIA model. A comparison of local tide gauge data with the Late Holocene RSL trends from Regions 1 and 2 support the spatial variation in RSL across North Carolina, and imply an additional increase of mean sea level of greater than 2 mm year^?1 during the latter half of the 20th century; this is in general agreement with historical tide gauge and satellite altimetry data.     

Using the Newly‐created ILE DBMS to Better Represent Temporal and Historical GIS Data

This article introduces a type of DBMS called the Intentionally‐Linked Entities (ILE) DBMS for use as the basis for temporal and historical Geographical Information Systems. ILE represents each entity in a database only once, thereby mostly eliminating redundancy and fragmentation, two major problems in Relational and other database systems. These advantages of ILE are realized by using relationship objects and pointers to implement all of the relationships among data entities in a native fashion using dynamically‐allocated linked data structures. ILE can be considered to be a modern and extended implementation of the E/R data model. ILE also facilitates storage of things that are more faithful to the historical records, such as gazetteer entries of places with imprecisely known or unknown locations. This is difficult in Relational database systems but is a routine task using ILE because ILE is implemented using modern memory allocation techniques. We use the China Historical GIS (CHGIS) and other databases to illustrate the advantages of ILE. This is accomplished by modeling these databases in ILE and comparing them to the existing Relational implementations.     

Isotope geochemistry of Paleoproterozoic metacarbonates from Itatuba,Borborema Province,Northeastern Brazil: Evidence of marble melting within a collisional suture

Strongly-deformed marbles may be easily confused with linear and elongated carbonatite intrusions. Both rocks may present similar texture and foliation to the host rock, or even cross cutting field relationships, which could be interpreted either as igneous or high-grade metamorphosed marble. Diagnostic criteria are even more complex when there is evidence of melting of the metasedimentary carbonate rock, such as has been described in the Himalayas and in the Eastern Ghats, India.In the Alto Moxotó Terrane, a high-grade gneissic domain of the Borborema Province, Northeastern Brazil, there are metacarbonates associated with banded gneisses and different metaplutonic rocks. Field evidence indicates the absence of other metasedimentary rocks associated with these marbles, thus suggesting that these carbonates were separated from other siliciclastic metasedimentary rocks. The presence of marble also suggests that it may represent the initial stage of a crustal carbon recycling into the mantle. These marbles present many field similarities to carbonatites (e.g., fluid-flow structure) and, together with metagranites and metamafic intrusions, may represent a major collisional tectonic suture.A detailed study of the carbon, oxygen and strontium isotopic composition of these marbles is presented. This study aims to identify the origin of the different isotopic components. It is argued that these rocks were subjected to temperature and pressure conditions that were sufficiently high to have melted them. The isotopic data presented here support this interpretation and indicate the mixing of two components: (i) one characterized by radiogenic Sr isotopes and mantle-like carbon isotopes, which is associated with the gneissic and mafic rocks, and (ii) another characterized by low ⁸⁷Sr/⁸⁶Sr ratios and highly positive δ¹³C values. Available geochemical data for the upper Paleoproterozoic indicate that the ⁸⁷Sr/⁸⁶Sr ratio of ocean water, varying between 0.7050 (2.25 ± 0.25 Ga) and 0.7047 (1.91 Ga), falls within the lower range of the samples from Itatuba and thus reinforces the interpretation that these marbles are sedimentary-derived and were partially contaminated by interaction with the host gneissic and mafic rocks.     

C-, Sr-isotope and Hg chemostratigraphy of Neoproterozoic cap carbonates of the Sergipano Belt,Northeastern Brazil

Two cap carbonates overlying glaciogenic diamictites crop out extensively in the eastern Vaza Barris Domain of the Sergipano Belt, northeastern Brazil. They are represented by carbonates of the Jacoca Formation, resting on top of diamictite of the Ribeiropolis Formation, and by the Olhos D’Agua Formation (carbonates, organic-rich towards the top), which overlies diamictite of the Palestina Formation. These two sequences were deformed and metamorphosed at sub-greenschist facies-conditions during the Brasiliano cycle (650–600 Ma).     

High-pressure thermal aureoles around two Neoproterozoic synorogenic magmatic epidote-bearing granitoids,Northeastern Brazil

Unusual high-pressure inner thermal aureoles are described from the Minador and Angico Torto epidote-bearing tonalitic plutons that emplaced into greenschist-facies metasedimentary rocks of the Neoproterozoic Cachoeirinha-Salgueiro belt, northeastern Brazil. The foliated pelitic hornfelses display the mineral assemblage garnet, kyanite, staurolite, muscovite, biotite, plagioclase ± quartz. Rare fibrolite is only found very close to the contacts. Hornfelses display steep mineral lineations and steeply-dipping foliations concordant with magmatic contacts. Leucocratic veinlets containing quartz, oligoclase, garnet, kyanite, staurolite, rutile and ilmenite suggest that limited melting conditions were reached very close to magmatic contacts (T ? 650 °C, P around 8 kbar). These high-pressure hornfelses form a few meters thick, rigid envelopes around the two plutons. Contrary to known examples of kyanite-bearing hornfelses that recorded high-temperature decompression, the nearly isobaric cooling down to ca. 450 °C is constrained by 3.20–3.30 Si contents of retrogressive phengites from both inner hornfelses and ductilely-deformed tonalite at the pluton margins. Isograds and bathograds are, therefore, apparently telescoped due to HP/LT shearing, possibly caused by subsequent differential vertical movements affecting these two solidified plutons. The unusual depth of emplacement of these syn-kinematic calc-alkaline plutons is explained by a tentative geodynamic model involving a pre-620 Ma-subduction setting.ResumenLas aureolas internas que rodean dos plutones tonalíticos emplazados dentro de rocas cajas en facies esquistos verdes del Cinturón-plegado Cachoeirinha-Salgueiro al noreste de Brasil, contienen hornfelses pelíticos foliados con granate, kyanita, estaurolita, muscovita, biotita, plagioclasa ± cuarzo. Fibrolita es rara ó es encontrada solamente cerca de las zonas de contacto. Los hornfelses desarrollaron foliaciones concordantes con buzamiento fuerte cerca de los contactos magmáticos y muestran lineaciones minerales casi verticales. Venillas leucocraticas contienen cuarzo, oligoclasa, granate, kyanita, estaurolita, rutilo e ilmenita sugiriendo que el límite en las condiciones de fusión fueron cercanas a los contactos magmáticos (T ? 650 °C, P entorno 8 kbar). Estos hornfelses de alta presión forman una cobertura rígida de poco metros entorno a los dos plutones. Contrariamente a lo conocido en diferentes ejemplos de hornfelses con kyanita con registro de descompresión, la isóbara de enfriamiento para cerca de 450 °C está controlada por el contenido de Si 3.20–3.30 de fengitas retrógradas, en los hornfelses internos y en las márgenes de los plutones donde las tonalitas están deformadas ductilmente. Isógradas y batógradas son, por lo tanto, aparentemente telescopadas debido a cizalla de alta presión/baja temperatura, posiblemente causado por subsecuentes movimientos verticales diferenciales afectando estos dos plutones solidificados. El emplazamiento a una profundidad inusual de estos plutones calci-alcalinos syn-cinemáticos es explicado por un modelo geodinámico tentativo que involucra un escenario de subducción pre-620 Ma.     

Magnetic mineralogy of the Yaxcopoil‐1 core,Chicxulub

Abstract— Core from the Yaxcopoil‐1 (Yax‐1) hole, drilled as a result of the Chicxulub Scientific Drilling Project (CSDP), has been analyzed to investigate the relationship between opaque mineralogy and rock magnetic properties. Twenty one samples of suevite recovered from the depth range 818–894 m are generally paramagnetic, with an average susceptibility of 2000 times 10^?6 SI and have weak remanent magnetization intensities (average 0.1 A/m). The predominant magnetic phase is secondary magnetite formed as a result of low temperature (<150 °C) alteration. It occurs in a variety of forms, including vesicle infillings associated with quartz and clay minerals and fine aggregates between plagioclase/diopside laths in the melt. Exceptional magnetic properties are found in a basement clast (metamorphosed quartz gabbro), which has a susceptibility of >45000 times 10^?6 SI and a remanent magnetization of 77.5 A/m. Magnetic mafic basement clasts are a common component in the Yax‐1 impactite sequence. The high susceptibility and remanence in the mafic basement clasts are caused by the replacement of amphiboles and pyroxenes by an assemblage with fine <1 μm magnetite, ilmenite, K‐feldspar, and stilpnomelane. Replacement of the mafic minerals by the magnetic alteration assemblage occurred before impact. Similar alteration mechanisms, if operative within the melt sheet, could explain the presence of the high amplitude magnetic anomalies observed at Chicxulub.