Ionic medium effects in sea water — A comparison of acidity constants of carbonic acid and boric acid in sodium chloride and synthetic sea water

It is shown that the values of pK_1C and pK_2C for carbonic acid, pK_B for boric acid and the ionic product of water, pK_w, in sea water may be explained on the basis of their determination in 0.7 M_w sodium chloride and the formation of the following ion-pairs: NaSO₄^?, MgSO₄, CaSO₄, MgCO₃, CaCO₃, MgHCO₃⁺, CaHCO₃⁺, MgOH⁺, HSO₄^?, MgB(OH)₄⁺ and CaB(OH)₄⁺. On the whole the calculated stability constants are lower than those given by Garrels and Thompson (1962).     

Seasonal dynamics in pelagic fish abundance in a Baltic Sea coastal area

The spring-spawning Baltic Sea herring spawn in coastal areas that also serve as nursery areas for the young fish during their first summer. In a bay known as a herring spawning and nursery area, the pelagic fish abundance was quantified using hydroacoustics every second week from late spring to autumn in 2000 and 2001. A dense system of survey transects allowed determination of the acoustic index (the nautical area scattering coefficient) for fish abundance with high precision. The variation, expressed as the geostatistical coefficient of variation, was on average 5% both years and ranged from 3–11% (2000) and 3–8% (2001). Through the hydroacoustic data intra-annual dynamics in acoustic fish abundance, densities and size composition could be followed, which showed similar trends in both years. In spring and early summer acoustic fish densities were low, followed by a drastic, 20-fold increase in late summer. Hydroacoustic data and biological samples suggest that the increase was caused mainly by the recruitment of young-of-the-year herring to the acoustically assessable pelagic fish community. This age class is commonly not well represented in catches when using traditional sampling gears such as gill nets and trawls, and hydroacoustics may help to improve quantitative estimates of small juvenile fish in order to increase the understanding of biological processes in coastal nursery areas.     

Finite deformation analysis of geomaterials

The mathematical structure and numerical analysis of classical small deformation elasto–plasticity is generally well established. However, development of large deformation elastic–plastic numerical formulation for dilatant, pressure sensitive material models is still a research area. In this paper we present development of the finite element formulation and implementation for large deformation, elastic–plastic analysis of geomaterials. Our developments are based on the multiplicative decomposition of the deformation gradient into elastic and plastic parts. A consistent linearization of the right deformation tensor together with the Newton method at the constitutive and global levels leads toward an efficient and robust numerical algorithm. The presented numerical formulation is capable of accurately modelling dilatant, pressure sensitive isotropic and anisotropic geomaterials subjected to large deformations. In particular, the formulation is capable of simulating the behaviour of geomaterials in which eigentriads of stress and strain do not coincide during the loading process. The algorithm is tested in conjunction with the novel hyperelasto–plastic model termed the B material model, which is a single surface (single yield surface, affine single ultimate surface and affine single potential surface) model for dilatant, pressure sensitive, hardening and softening geomaterials. It is specifically developed to model large deformation hyperelasto–plastic problems in geomechanics. We present an application of this formulation to numerical analysis of low confinement tests on cohesionless granular soil specimens recently performed in a SPACEHAB module aboard the Space Shuttle during the STS‐89 mission. We compare numerical modelling with test results and show the significance of added confinement by the thin hyperelastic latex membrane undergoing large stretching. Copyright © 2001 John Wiley & Sons, Ltd.     

Ejecta from impacts at 0.2-2.3 m/s in low gravity

Collisions between planetary ring particles and in some protoplanetary disk environments occur at speeds below 10 m/s. The particles involved in these low-velocity collisions have negligible gravity and may be made of or coated with smaller dust grains and aggregates. We undertook microgravity impact experiments to better understand the dissipation of energy and production of ejecta in these collisions. Here we report the results of impact experiments of solid projectiles into beds of granular material at impact velocities from 0.2 to 2.3 m/s performed under near-weightless conditions on the NASA KC-135 Weightless Wonder V. Impactors of various densities and radii of 1 and 2 cm were launched into targets of quartz sand, JSC-1 lunar regolith simulant, and JSC-Mars-1 martian regolith simulant. Most impacts were at normal or near-normal incidence angles, though some impacts were at oblique angles. Oblique impacts led to much higher ejection velocities and ejecta masses than normal impacts. For normal incidence impacts, characteristic ejecta velocities increase with impactor kinetic energy, KE, as approximately KE^0.5. Ejecta masses could not be measured accurately due to the nature of the experiment, but qualitatively also increased with impactor kinetic energy. Some experiments were near the threshold velocity of 0.2 m/s identified in previous microgravity impact experiments as the minimum velocity needed to produce ejecta [Colwell, J.E., 2003. Icarus 164, 188-196], and the experimental scatter is large at these low speeds in the airplane experiment. A more precise exploration of the transition from low-ejecta-mass impacts to high-ejecta-mass impacts requires a longer and smoother period of reduced gravity. Coefficient of restitution measurements are not possible due to the varying acceleration of the airplane throughout the experiment.     

Numerical modeling of cyclic mobility based on fuzzy-set concepts in plasticity theory

In this paper, the application of an efficient, transparent and accurate kinematic-cyclic constitutive model based on the fuzzy-set concepts and incremental plasticity theory is presented to show its capability in modeling cyclic mobility of saturated granular soil. The nature and kinematic mechanism of the membership functions in the fuzzy-set constitutive model are illustrated. The model’s capability of modeling soil dilatancy is investigated. Important features of volume change and pore water pressure build-up related to soil cyclic mobility are captured. The formulation of the proposed model is relatively simple and it can be readily implemented in finite element codes. The enhanced fuzzy-set model is capable of simulating ground motion problems particularly related to cyclic mobility, soil liquefaction, and spreading behavior.