The charge distribution on interstellar grains—The effect of induced charge

A calculation of the equilibrium charge acquired by interstellar grains is given, which takes account of polarization charges that are induced in a grain by incident ions and electrons.Both metal and dielectric grains are considered and photoionization of the latter grains by UV radiation is taken into account where necessary. It is found that the inclusion of the polarization charges in the calculation is only important in gas clouds where the mean charge on a grain is low (<1e); that is, for HI regions and dense molecular clouds. In such clouds, the effect of the polarization charges is to increase the amount of negative charge acquired by a grain. A discussion is given concerning the validity of the classical electrostatic theory employed in the paper for small grains of radius 10^–6 cm, and some astrophysical consequences of the modification of the grain charge by polarization effects are considered.     

Spherical Slepian functions and the polar gap in geodesy

The estimation of potential fields such as the gravitational or magnetic potential at the surface of a spherical planet from noisy observations taken at an altitude over an incomplete portion of the globe is a classic example of an ill-posed inverse problem. We show that this potential-field estimation problem has deep-seated connections to Slepian's spatiospectral localization problem which seeks bandlimited spherical functions whose energy is optimally concentrated in some closed portion of the unit sphere. This allows us to formulate an alternative solution to the traditional damped least-squares spherical harmonic approach in geodesy, whereby the source field is now expanded in a truncated Slepian function basis set. We discuss the relative performance of both methods with regard to standard statistical measures such as bias, variance and mean squared error, and pay special attention to the algorithmic efficiency of computing the Slepian functions on the region complementary to the axisymmetric polar gap characteristic of satellite surveys. The ease, speed, and accuracy of our method make the use of spherical Slepian functions in earth and planetary geodesy practical.     

High resolution electron microscopic studies on ferrosilite III

High resolution transmission electron microscopic (HRTEM) studies on ferrosilite (Fs) III confirmed the periodicity nine (p=9) of the tetrahedral chains in this silicate. Various chain periodicity faults (CPFs) have been observed and faults with “elfer” units (p′=11) dominate. CPFs with p′?9 were observed and are interpreted as pyroxene like slabs. Synthesis of Fs III under extended run duration demonstrated that Fs III actually is the stable phase in the system FeSiO₃ at high pressures and high temperatures. However, the stability fields of Fs III and orthoferrosilite might be separated by a narrow field of a FeSiO₃ polymorph with “elfer” single chain. This field has not been bracketed so far. New structure variants of Fs are discussed. Reconnaissance experiments on the kinetics of CPFs are reported.     

Thermal expansion and high-temperature P21/c–C2/c phase transition in clinopyroxene-type LiFeGe2O6 and comparison to NaFe(Si,Ge)2O6

A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) Å, β = 108.844(6)°, V = 442.75(16) ų, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the $(\bar{1}\,0\,1) A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) ?, β = 108.844(6)°, V = 442.75(16) ?³, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the ([`1] 0 1)(\bar{1}\,0\,1) plane, mostly along [0 1 0], and pure shear in the (0 1 0) plane due to the decrease of β. From comparison with silicate analogues, the germanate clinopyroxenes are more expansible, while the P2₁/c expands more than the C2/c phase. The evolution of Q ² (calculated as the normalized intensity of b-type reflections) with T in the framework of the Landau theory has been done using a standard expression for a first order phase transition. We observe a jump of Q ₀² = 0.538(2) at T _tr, with T _c of 481(7) K, b/a = −2,290 K, and c/a = 3,192 K, and thus far from being tri-critical point. A closely related composition (LiFe³⁺Si₂O₆) shows an equivalent phase transition at 228 K, which is very close to the tri-critical point and 561 K cooler. This result indicates that a change in the composition of tetrahedral sites can have dramatic effects on the P2₁/c ↔ C2/c displacive phase transition in clinopyroxenes. The major changes observed in the evolution of the crystal structure with T are observed in the M2 polyhedron, with a volume decrease by ca. 13.3%, compared to ca. 1.3% observed in the M1 polyhedron. The tetrahedra behave as rigid units with neither a significant change of volume at T > T _tr (<1‰), nor a change of tilting of the basal plane. No change in coordination is observed at T > T _tr in the M2 polyhedron, which remains sixfold coordinated although a strong deformation of this polyhedron is observed. This deformation is related to a strong change by 51.4° at T _tr of the kinking angle (O3–O3–O3 angle) of the B-chain of tetrahedra, which switches from O-rotated to S-rotated [from 143.3(5)° to 194.7(6)°]. The A-chain is S-rotated at T < T _tr [206.8(5)° at 703 K] and extends by 12° at the transition.     

Canada-France-Hawaii Telescope's “redeye” infrared camera system: Array performance

The Canada-France-Hawaii Telescope (CFHT) has recently commissioned two facility infrared cameras for astronomical observations in the 1.0 to 2.5 micron region. These cameras use NICMOS3 256×256 pixel arrays fabricated from Hg:Cd:Te. We report here on array performance and discuss two unique features of these arrays, namely corner glow and residual images. We have developed techniques for reducing corner glow and a method of clearing residual image charge. We discuss our techniques and their side effects.     

Thermal structure and circulation in the great lakes

Abstract

Large enough to include many oceanic phenomena, the Laurentian Great Lakes are more accurately described as inland seas. With the exception of the shallow Western Basin of Lake Erie, the lakes are thermally stratified in summer, homogeneous in winter, with average temperatures passing through the temperature of maximum density of fresh water (4°C) in both the spring and the fall. The circulation is mainly powered by the wind but is strongly modified by thermal stratification and basin geometry. Effects of the earth's rotation are present in all large‐scale flows. Current speeds are typically 10 cm s^?1; they are too small, with rare exceptions, to present difficulties to navigation but a knowledge of the patterns of water movement is essential for interpreting the behaviour of these valuable lakes as complex ecosystems. This paper will review more than a century of physical study of the Great Lakes.     

Instruments, Detectors and the Future of Astronomy with Large Ground Based Telescopes

Results of a survey of instrumentation and detector systems, either currently deployed or planned for use at telescopes larger than 3.5 m, in ground based observatories world-wide, are presented. This survey revealed a number of instrumentation design trends at optical, near, and mid-infrared wavelengths. Some of the most prominent trends include the development of vastly larger optical detector systems (> 10⁹ pixels) than anything built to date, and the frequent use of mosaics of near-infrared detectors – something that was quite rare only a decade ago in astronomy. Some future science applications for detectors are then explored, in an attempt to build a bridge between current detectors and what will be needed to support the research ambitions of astronomers in the future.     

Analysis of shallow-water experimental acoustic data including acomparison with a broad-band normal-mode-propagation model

Channel temporal variability, resulting from fluctuations in oceanographic parameters, is an important issue for reliable communications in shallow-water-long-range acoustic propagation. As part of an acoustic model validation exercise, audio-band acoustic data and oceanographic data were collected from shallow waters off the West Coast of Scotland. These data have been analyzed for temporal effects. The average impulse response for this channel has been compared with simulations using a fast broad-band normal-mode propagation model. In this paper, we also introduce a novel technique for estimating and removing the bistatic reverberation contribution from the data. As propagation models do not necessarily account for reverberation, it has to be extracted from the signals when comparing measured and modeled transmission loss