Possible impact of dam reservoirs and river diversions on material fluxes to the Gulf of Thailand

Thai people have always been agricultural-based, although rainwater is not enough to sustain year-round agricultural practice. The first earth-filled dam was built across a valley near Sukhothai over 700 years ago. Now, there are six major multipurposed dam reservoirs, among which the largest is the Sri Nakarind (SN) built across the Kwae Yai River, the main branch of the Mae Klong River in the western part of Thailand. The first multipurposed dam reservoir built on the Chao Phraya (largest) River System is the Bhumibhol Dam on the Ping River. In this paper, the two Mae Klong River Dam Reservoirs and their biology and chemistry are discussed. Also investigated are the historical records of material fluxes to the Gulf of Thailand in down-core sediment profiles and in 40-year bands of coral, Porites lutea, taken from the Upper Gulf of Thailand near Si Chang Island. Sediment cores studied did not show clear decreases in the biogenic silica concentration in the Upper Gulf area after the building of dams. Part of the reasons might be the higher rate of dissolution of silica in tropical waters bioturbation of surface layers or the constant disturbance of the bottom sediment by fishermen using bottom trawls. The record in the coral bands seems to be more promising in reflecting the material flux change due to dam construction. An attempt to detect changes in diatom population with time due to the expected decrease in siliceous material discharge was not possible because there was a change from the use of 70 μm mesh size to 20 μm mesh size resulting in the increase of species and biomass, although the diatom percentage remained above 80% in all estuarine samples.     

Trace metal composition of and accumulation rates of sediments in the Upper Gulf of Thailand

Sediment cores and grab samples were collected in the Upper Gulf of Thailand to determine sedimentation rates and to determine if metal concentrations reflect anthropogenic inputs.Accumulation rates of sediments in the Upper Gulf measured using the ²¹⁰Pb method, appear to vary from ca. 4 to 11 mm yr^?1. Sediment budgets suggest that little of the sediment delivered to the Upper Gulf by the major rivers is ultimately transported to the Lower Gulf. Metal concentrations in Upper Gulf sediments appear to be dominantly controlled by natural inputs.     

A history of metal pollution in the Upper Gulf of Thailand

Sediment cores were taken from the Upper Gulf of Thailand and 5-cm strata were analysed for cadmium, chromium, copper, lead, zinc and aluminium. At the Chao Phrya River mouth area, enriched concentrations of cadmium and lead were observed at the top end of the cores. On applying the sedimentation rates found by the ²¹⁰Pb method, these layers were found to correspond to the past 30 years. No enrichment was found for chromium, copper or zinc.     

Heavy metals and polycyclic hydrocarbon compounds in benthic organisms of the Upper Gulf of Thailand

Concentrations of heavy metals and polycyclic aromatic hydrocarbons (PAHs) were measured in bivalves collected in the Upper Gulf of Thailand. PAHs detected included acenaphthene, acenaphthylene, benzo[a]pyrene, fluoranthene, methylphenanthrene, phenanthrene and triphenylene. Benzo[a]pyrene was detected in all species at concentrations varying from 1.0 to 8.2 ng·g^?1. Concentrations of cadmium, cobalt, copper, lead and nickel were significantly lower in bivalves from the Gulf than in green mussels collected from the mouth of the Chao Phraya River. No correlation was found between metal concentrations in animals and sediment, with the exception of copper. Copper concentrations in polychaetes and clams appeared to correlate with the copper:iron ratio of sediments. High rates of degradation were observed when radiolabelled chlorobenzene, phenanthrene and chrysene were added to water and sediment of the Chao Phraya River. Rates were lower in the waters and sediment of the Gulf of Thailand. The calculated half-lives of chlorobenzene in the Gulf of Thailand and the Chao Phraya River were about 130 and 68 days, respectively.