Neural network assessment of groundwater contamination of US Mid-continent

Artificial neural networks (ANNs) were applied to data taken from 1,302 domestic and rural hydraulic wells in the Mid-continent of the USA including Illinois, Iowa, and other 12 States to predict the contamination of the groundwater with pesticides. Preliminary hydrogeological and geostatistical analyses were carried out to assess groundwater vulnerability and data variability and weight, where data attributes were pre-processed and grouped into three main categories: hydrologic, human interaction, and climatic groups. ANNs are computer parallel-based systems that are characterized by their topologies, transfer functions, and learning algorithms. The backpropagation network (BP-NN) learning algorithm, used here, involves incremental adjustment of a set of parameters to minimize the error between the desired output and the actual output. Sensitivity analysis of the main BP-NN attributes was conducted to improve the BP-NN performance. Results of several trials demonstrated that the BP-NN have predicted the contaminated wells within each minor group in high precision. Sensitivity analysis revealed that BP-NN topologies and transfer functions were the main factors that affected its performance. It is evident that BP-NN is a powerful tool to predict the groundwater contamination over a wide area with limited data availability, which can provide an alternative cheap and effective tool to assess groundwater contamination worldwide.     

Distribution of diagenetic alterations within depositional facies and sequence stratigraphic framework of fluvial sandstones: Evidence from the Petrohan Terrigenous Group,Lower Triassic,NW Bulgaria

Sequence stratigraphy of fluvial deposits is a controversial topic because changes in relative sea level will eventually have indirect impact on the spatial and temporal distribution of depositional facies. Changes in the relative sea level may influence the accommodation space in fluvial plains, and hence have impact on types of fluvial system, frequency of avulsion, and style of vertical and lateral accretion. This study aims to investigate whether depositional facies and changes in the fluvial system of the Lower Triassic Petrohan Terrigenous Group sandstones (NW Bulgaria) in response to changes in the relative sea level have an impact on the spatial and temporal distribution of diagenetic alterations.     

Diagenetic alterations related to marine transgression and regression in fluvial and shallow marine sandstones of the Triassic Buntsandstein and Keuper sequence,the Paris Basin,France

The distribution of diagenetic alterations in Triassic fluvio-deltaic, quartzarenitic to sublitharenitic, lowstand systems tract (LST) sandstones of the Grès á Voltzia Formation, anastomosing fluvial, quartzarenitic transgressive systems tract (TST) sandstones of the Grès á Roseaux Formation, and shallow marine, quartzarenitic to sublitharenitic, TST sandstones of the Grès Coquiller Formation, the Paris Basin (France), can be linked to transgression and regression events, and thus to the sequence stratigraphic context. Near-surface eogenetic alterations, which display a fairly systematic link to the depositional facies and sequence stratigraphic framework, include: (i) cementation by meteoric water calcite (δ¹⁸O=−8.9‰ and δ¹³C=−9.1‰) in the fluvio-deltaic, LST sandstones, (ii) cementation by mixed marine–meteoric calcite (δ¹⁸O=−5.3‰ to −2.6‰ and δ¹³C=−3.9‰ to −1.3‰) and dolomite (δ¹⁸O=−4.6‰ to −2.6‰ and δ¹³C=−2.9‰ to −2.3‰) in the foreshore, TST sandstones and below parasequence boundaries (PB), and transgressive surface (TS), and in the shoreface, TST sandstones below maximum flooding surfaces (MFS), being facilitated by the presence of carbonate bioclasts, (iii) dissolution of detrital silicates and precipitation of K-feldspar overgrowths and kaolinite, particularly in the fluvio-deltaic, LST sandstones owing to effective meteoric water circulation, and (vi) formation of autochthonous glauconite, which is increases in abundance towards the top of the fluvio-deltaic, LST sandstones, and along TS, and in the shoreface, TST sandstones, by alteration of micas owing to the flux of seawaters into the sandstones during transgression, whereas parautochthonous glauconite is restricted to the TS sandstones owing to marine reworking. Mesogenetic alterations, which include cementation by quartz overgrowths and illite, display fairly systematic link to fluvio-deltaic, LST sandstones. This study has revealed that linking of diagenesis to transgression and regression events enables a better understanding of the parameters that control the spatial and temporal distribution of diagenetic alterations in sandstones and of their impact on reservoir quality evolution.     

Hydrothermal alteration of plagioclase in granitic rocks from Proterozoic basement of SE Sweden

Petrographic examinations and electron microprobe analyses of Proterozoic granitic rocks, SE Sweden aimed to characterize and unravel the mechanisms and conditions of plagioclase alterations. These alterations include saussuritization, albitization and replacement of plagioclase by K‐feldspar. The hydrothermal alterations, which are inferred to have occurred at ca. 250–400°C, resulted in concomitant formation of Al‐rich titanite, epidote, calcite, pumpellyite, prehnite and iron oxides. Replacement of plagioclase by K‐feldspar occurs in red‐stained zones, which have developed close to thin fractures owing to the precipitation of tiny Fe‐oxide pigment particles within the altered plagioclase, whereas saussuritized plagioclase has less systematic spatial relationships to these fractures. Albitization of plagioclase occurred in rocks that are poor in biotite compared to rocks that suffered extensive saussuritization. The chemical and textural characterization of various types of plagioclase alterations allows elucidation of the granitic hydrothermal systems. Features of feldspar alteration in the granitic rocks are similar to those encountered in feldspathic sandstones and should hence be considered in studies on diagenetic changes of siliciclastic successions during basin evolution. Copyright © 2009 John Wiley & Sons, Ltd.