Organic carbon content in surface sediments—defining regional provinces

Approaches to quantify the organic carbon accumulation on a global scale generally do not consider the small-scale variability of sedimentary and oceanographic boundary conditions along continental margins. In this study, we present a new approach to regionalize the total organic carbon (TOC) content in surface sediments (<5 cm sediment depth). It is based on a compilation of more than 5500 single measurements from various sources. Global TOC distribution was determined by the application of a combined qualitative and quantitative-geostatistical method. Overall, 33 benthic TOC-based provinces were defined and used to process the global distribution pattern of the TOC content in surface sediments in a 1°×1° grid resolution. Regional dependencies of data points within each single province are expressed by modeled semi-variograms. Measured and estimated TOC values show good correlation, emphasizing the reasonable applicability of the method. The accumulation of organic carbon in marine surface sediments is a key parameter in the control of mineralization processes and the material exchange between the sediment and the ocean water. Our approach will help to improve global budgets of nutrient and carbon cycles.     

Coupling of benthic oxygen uptake and silica release: implications for estimating biogenic particle fluxes to the seafloor

A new approach to predict biogenic particle fluxes to the seafloor is presented, which is based on diffusive oxygen uptake and, in particular, opal fluxes to the seafloor. For this purpose, we used a recently published empirical equation coupling benthic silica to oxygen fluxes, and showing a clear negative correlation between Si and O₂ fluxes. Dissolution of biogenic silica mediated by aerobic microbial activity has been inferred at 24 sites along the African and South American continental margins. Based on the assumption that these findings hold essentially for the entire Southern Atlantic Ocean, we applied the silica to oxygen flux ratio to a basin-wide grid of diffusive oxygen uptake extracted from the literature. Assuming that the silica release across the sediment-water interface equals the particulate flux of biogenic opal to the seafloor, we estimated minimum opal rain rates. We combined these calculations with published relationships between aerobic organic carbon mineralization and dissolution rates of calcite above the hydrographical lysocline, thereby assessing the calcite rain rate and particulate organic carbon flux to the seafloor. The addition of the buried fraction completes our budget of biogenic particulate rain fluxes. The combination of such empirical equations provides a powerful and convenient tool which greatly facilitates future investigations of biogenic particle fluxes to the seafloor.     

Last glacial geomorphologic records in Mt Chelmos,North Peloponnesus,Greece

This study deals with the analysis of the glacial processes that have affected the relief of Mt Chelmos in northern Peloponnesus, Greece during middle and Late Pleistocene. The goal was to compile a combined geomorphological-geological map of the study area which would enable the chronological stratification of the glacial landforms cropping up on Mt. Chelmos. Chronological stratification was further aided by optically stimulated luminescence (OSL) dating. The map served as the basis upon which the reconstruction and discussion on the phases of the Middle-Late Quaternary paleoclimatic history of Mt. Chelmos have been made. A sophisticated semiautomated method was first used to analyze the Digital Elevation Model (DEM), combined with Aster, Quickbird and ALOS imagery in order to identify glacial and periglacial, as well as karstic features. Then, these features along with other nonrecognizable features from the remote-sensing images were documented in the field. In this way, several glacial landforms were identified, such as moraines and cirques, indicating extended glaciation phases during the middle and Late Pleistocene. Additionally, a ground moraine located at an altitude of 1900-2050 m, within the Spanolakos glacial valley, was dated using the OSL-dating method. The resulting ages indicate a phase of glacier advance/stabilization during MIS-5b (89-86 ka), which is in consistence with pollenrecord evidence from Greece and the Mediterranean.     

Ecological impacts of air pollution from road transport on local vegetation

Motor vehicles emit a cocktail of pollutants and are a major contributor to ground-level air pollution, but little is known regarding the ecological impacts of air pollution from roads on the surrounding vegetation. Data are presented on vegetation at three sites adjacent to two major motorways in the UK, comprising two woodland sites and one blanket bog site. Surveys of oak and beech tree health (at the woodland sites) and species composition (at the blanket bog site) were undertaken along transects away from the motorway.