In situ strength measurements on natural upper-mantle minerals

Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with the residual pressure of fluid inclusions in mantle xenoliths.     

Early Miocene rotational process in the eastern part of south-west Japan inferred from paleomagnetic studies

Abstract This paper provides untilted paleomagnetic data obtained from the early Miocene strata around the Kanazawa‐Iozen area, in the eastern part of south‐west Japan. A thick pile of volcaniclastics and marine transgressive sediments underlie the area; they were deposited in the early stage of the Japan Sea opening event. Progressive thermal demagnetization tests isolated stable primary magnetic vectors from eight sites in the upper part of the Iozen Formation. Overall, the tilt‐corrected mean direction of this unit is D = 36.4°, I = 51.6° and α₉₅ = 12.1. Together with a published paleomagnetic and chronological database, the present results suggest that clockwise rotation of south‐west Japan, linked to the back‐arc opening, commenced in the early Miocene and accelerated at the same time as rapid subsidence along the Japan Sea coast. Post‐opening, differential rotation within the eastern part of south‐west Japan is assumed, based on selected paleomagnetic data from the latest Early Miocene.     

Development and installation of bedload monitoring systems with submerged load cells

Bedload governs riverbed channel variations and morphology, it is necessary to determine bedload discharge through an arbitrary cross section in a mountain river. A new system with submerged load cells has been developed to directly measure bedload discharge. The system consists of: (1) an iron box which is 1 m long, 0.5 m wide and 0.1 m in depth, (2) two submerged load cells 0.7 m apart, (3) a pressure sensor and, (4) an electromagnetic velocity meter. This system has been designed to exclude the effect of the hydraulic pressure of water on direct measurements of bedload particle weight. Initial tests in a laboratory were conducted to examine the accuracy of measurements with the system under aerial conditions. The system has been installed in the supercritical flume in Ashi-arai-dani River of the Hodaka Sedimentation Observatory of the Disaster Prevention Research Institute (DPRI) of Kyoto University to obtain bedload discharge under natural conditions. Flume tests were conducted in this channel by artificial supply of uniform sediment particles of several grain sizes. The average velocity of the sediment particles near the bed was estimated using cross-correlation functions for weight waves obtained by the two load cells. Bedload discharge calculations were based on time integration of the product of sediment velocity and sediment weight obtained by the two load cells. This study clarifies the reasons why bedload measurements are difficult, and provides some solutions using the monitoring systems with submerged load cells through the field measurements. Additionally, the applicability of bedload measurement with the submerged load cells is explained based on experimental artificial sediment supply data.     

Cyclic strength and deformation of crushable carbonate sand

Cyclic triaxial tests have been carried out on a skeletal carbonate sand from the west coast of Eire. Results are presented for undrained cyclic shear tests on samples with 80% of relative density consolidated under both isotropic and anisotropic conditions. Failure was defined as a 5% double amplitude cyclic strain and a 5% peak axial strain for stress-reversal and non-reversal stress conditions, respectively. Using this definition the cyclic strength for isotropically consolidated samples was affected by the confining pressure although the angular platey nature of the sand resulted in higher cyclic strengths than for a comparable silica sand. For anisotropically consolidated samples the cyclic strength increased with increasing initial static shear stress while on the other hand the cyclic strength normalised in the usual way with respect to the initial confining pressure decreased as this pressure increased.     

Dislocation microstructures in naturally deformed silicate garnets

Dislocation microstructures of naturally deformed silicate garnets and olivines in garnet-peridotites and silicate garnets in eclogites from four localities have been observed with a transmission electron microscope (TEM) to clarify the dislocation characteristics of silicate garnets. We have obtained the following results: (1) dislocation densities of garnets in all the garnet-peridotites (ρ = 10⁵−10⁷ cm⁻²) are always nearly an order of magnitude lower than those of co-existing olivines; (2) dislocation densities of garnets in eclogites (ρ = 10⁵−10⁸ cm⁻²) which are embedded in garnet-peridotites are almost an order of magnitude higher than those of garnets in the surrounding garnet-peridotites; (3) the dominant Burgers vector, b, of mainly edge dislocations in garnet is 100 for specimens with dislocation density ρ = 10⁵−10⁶ cm⁻², while b=1/2111 for specimens with ρ = 10⁷−10⁸ cm⁻². Result (1) indicates that the observed dislocations in garnets were formed by plastic deformation under the same stresses as for co-existing olivines, and that there is a similar relationship between applied stress and dislocation density for garnets as for olivines. Result (2) suggests that the stress concentration occurred around eclogites embedded in garnet-peridotites, and the resulting differential stress in garnets in eclogites was further elevated by the interlocking of neighboring hard garnet grains. Finally, result (3) indicates that the dominant Burgers vector of mainly edge dislocations in garnet changes from 100 to 1/2111 with increasing applied differential stress.     

VIDEO AND PHOTOGRAPHIC SPECTROSCOPY OF 1998 AND 2001 LEONID PERSISTENT TRAINS FROM 300 TO 930 nm

Spectra of persistent meteor trains were observed at wavelength between 300 and 930 nm. Two obtained train spectra during the 1998 and 2001 Leonid meteor showers are reported here. During the 1998 Leonids, one train was detected by a photographic camera with a spectrograph covering 370–640 nm region. On the other hand, during the 2001 Leonids, video observations were carried out using image intensified cameras in ultraviolet (UV), visible and near infrared (near-IR) wavelengths. Temperatures in persistent trains have been measured by atmospheric O₂ A(0,1) band at the wavelength near 864.5 nm. From a video spectrum obtained just 7 s after parent fireball’s flare, a rotational temperature of 250 K at altitude of 88.0±0.5 km was estimated. We can say that the cooling time scale of train strongly depends on the initial mass of its fireball at least for Leonids. Based on cooling constant calculated from our results, we estimated a temperature of ∼ ∼130 K as a final exothermic temperature at early stage of persistent trains.     

Amoeboid olivine aggregates and related objects in carbonaceous chondrites: records of nebular and asteroid processes

Amoeboid olivine aggregates (AOAs) are the most common type of refractory inclusions in CM, CR, CH, CV, CO, and ungrouped carbonaceous chondrites Acfer 094 and Adelaide; only one AOA was found in the CB_b chondrite Hammadah al Hamra 237 and none were observed in the CB_a chondrites Bencubbin, Gujba, and Weatherford. In primitive (unaltered and unmetamorphosed) carbonaceous chondrites, AOAs consist of forsterite (Fa_<2), Fe, Ni-metal (5-12 wt% Ni), and Ca, Al-rich inclusions (CAIs) composed of Al-diopside, spinel, anorthite, and very rare melilite. Melilite is typically replaced by a fine-grained mixture of spinel, Al-diopside, and ±anorthite; spinel is replaced by anorthite. About 10% of AOAs contain low-Ca pyroxene replacing forsterite. Forsterite and spinel are always ¹⁶O-rich (δ^17,18O∼−40‰ to −50‰), whereas melilite, anorthite, and diopside could be either similarly ¹⁶O-rich or ¹⁶O-depleted to varying degrees; the latter is common in AOAs from altered and metamorphosed carbonaceous chondrites such as some CVs and COs. Low-Ca pyroxene is either ¹⁶O-rich (δ^17,18O∼−40‰) or ¹⁶O-poor (δ^17,18O∼0‰). Most AOAs in CV chondrites have unfractionated (∼2-10×CI) rare-earth element patterns. AOAs have similar textures, mineralogy and oxygen isotopic compositions to those of forsterite-rich accretionary rims surrounding different types of CAIs (compact and fluffy Type A, Type B, and fine-grained, spinel-rich) in CV and CR chondrites. AOAs in primitive carbonaceous chondrites show no evidence for alteration and thermal metamorphism. Secondary minerals in AOAs from CR, CM, and CO, and CV chondrites are similar to those in chondrules, CAIs, and matrices of their host meteorites and include phyllosilicates, magnetite, carbonates, nepheline, sodalite, grossular, wollastonite, hedenbergite, andradite, and ferrous olivine.Our observations and a thermodynamic analysis suggest that AOAs and forsterite-rich accretionary rims formed in ¹⁶O-rich gaseous reservoirs, probably in the CAI-forming region(s), as aggregates of solar nebular condensates originally composed of forsterite, Fe, Ni-metal, and CAIs. Some of the CAIs were melted prior to aggregation into AOAs and experienced formation of Wark-Lovering rims. Before and possibly after the aggregation, melilite and spinel in CAIs reacted with SiO and Mg of the solar nebula gas enriched in ¹⁶O to form Al-diopside and anorthite. Forsterite in some AOAs reacted with ¹⁶O-enriched SiO gas to form low-Ca pyroxene. Some other AOAs were either reheated in ¹⁶O-poor gaseous reservoirs or coated by ¹⁶O-depleted pyroxene-rich dust and melted to varying degrees, possibly during chondrule formation. The most extensively melted AOAs experienced oxygen isotope exchange with ¹⁶O-poor nebular gas and may have been transformed into magnesian (Type I) chondrules. Secondary mineralization and at least some of the oxygen isotope exchange in AOAs from altered and metamorphosed chondrites must have resulted from alteration in the presence of aqueous solutions after aggregation and lithification of the chondrite parent asteroids.     

Measurement of methane flux over an evergreen coniferous forest canopy using a relaxed eddy accumulation system with tuneable diode laser spectroscopy detection

Very few studies have conducted long-term observations of methane (CH₄) flux over forest canopies. In this study, we continuously measured CH₄ fluxes over an evergreen coniferous (Japanese cypress) forest canopy throughout 1?year, using a micrometeorological relaxed eddy accumulation (REA) system with tuneable diode laser spectroscopy (TDLS) detection. The Japanese cypress forest, which is a common forest type in warm-temperate Asian monsoon regions with a wet summer, switched seasonally between a sink and source of CH₄ probably because of competition by methanogens and methanotrophs, which are both influenced by soil conditions (e.g., soil temperature and soil moisture). At hourly to daily timescales, the CH₄ fluxes were sensitive to rainfall, probably because CH₄ emission increased and/or absorption decreased during and after rainfall. The observed canopy-scale fluxes showed complex behaviours beyond those expected from previous plot-scale measurements and the CH₄ fluxes changed from sink to source and vice versa.     

Biogeochemistry of nitrous oxide in groundwater in a forested ecosystem elucidated by nitrous oxide isotopomer measurements

The biological and physical controls on microbial processes that produce and consume N₂O in soils are highly complex. Isotopomer ratios of N₂O, with abundance of ¹⁴N¹⁵N¹⁶O, ¹⁵N¹⁴N¹⁶O, and ¹⁴N¹⁴N¹⁸O relative to ¹⁴N¹⁴N¹⁶O, are promising for elucidation of N₂O biogeochemistry in an intact ecosystem. Site preference, the nitrogen isotope ratio of the central nitrogen atom minus that of the terminal nitrogen atom, is useful to distinguish between N₂O via hydroxylamine oxidation and N₂O via nitrite reduction.We applied this isotopomer analysis to a groundwater system in a temperate coniferous-forested ecosystem. Results of a previous study at this location showed that the N₂O concentration in groundwater varied greatly according to groundwater chemistry, i.e. NO₃⁻, DOC, and DO, although apportionment of N₂O production to nitrification or denitrification was ambiguous. Our isotopic analysis (δ¹⁵N and δ¹⁸O) of NO₃⁻ and N₂O implies that denitrification is the dominant production process of N₂O, but definitive information is not derived from δ¹⁵N and δ¹⁸O analysis because of large variations in isotopic fractionations during production and consumption of N₂O. However, the N₂O site preference and the difference in δ¹⁵N between NO₃⁻ and N₂O indicate that nitrification contributes to total N₂O production and that most measured N₂O has been subjected to further N₂O reduction to N₂. The implications of N₂O biogeochemistry derived from isotope and isotopomer data differ entirely from those derived from conventional concentration data of DO, NO₃⁻, and N₂O. That difference underscores the need to reconsider our understanding of the N cycle in the oxic-anoxic interface.     

Purely physical separation of a small fraction of the Allende meteorite that is highly enriched in noble gases

Abstract— Fine material that floats during freeze-thaw disaggregation of the Allende meteorite is greatly enriched in noble gases compared to the bulk meteorite. Not only the elemental concentrations, but also most isotopic ratios of the noble gases in this fraction, strongly suggest that this material is very similar to the gas-rich carbonaceous residue isolated from the bulk meteorite by chemical treatment. The only significant difference in noble gas signature between our separated fraction and the chemical residues is that the ¹²⁹Xe/¹³²Xe ratio in the former is significantly lower than that in the latter, which suggests readsorption of ¹²⁹Xe released from the dissolved minerals during the chemical treatment. This is the first time that a gas-rich residue of a meteorite has been separated by a purely physical method alone. We also show that noble gases in phase Q and presolar diamond may be separable physically, although both are closely associated.