Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

     

High-Resolution Records of the Holocene Paleoenvironmental Variation Reflected by Carbonate and Its Isotopic Compositions in Bosten Lake and Response to Glacial Activities

Abstract: The Early Holocene paleoclimate in Bosten Lake on the northern margin of the Tarim Basin, southern Xinjiang, is reconstructed through an analysis of a 953 cm long core (BSTC2000) taken from Bosten Lake. Multiple proxies of this core, including the mineral components of carbonate, carbonate content, stable isotopic compositions of carbonate, Ca/Sr, TOC and C/N and C/S of organic matter, are used to reconstruct the climatic change since 8500 a B.P. The chronology model is made by nine AMS 14C ages of leaves, seeds and organic matter contained in two parallel cores. The climate was cold and wet during 8500 to 8100 a B.P. Temperature increased from 8100 to 6400 a B.P., the climate was warm and humid, and the lake expanded. The lake level was highest during this stage. Then from 6400 to 5100 a B.P., the climate became cold and the lake level decreased slightly. During the late mid-Holocene, the climate was hot and dry from 5100 to 3100 a B.P., but there was a short cold period during 4400 to 3800 a B.P. At this temporal interval, a mass of ice and snow melting water supplied the lake at the early time and made the lake level rise. The second highest lake level stage occurred during 5200 to 3800 a B.P. The climate was cool and wet during 3100 to 2200 a B.P., when the lake expanded with decreasing evaporation. The lake had the last short-term high level during 3100 to 2800 a B.P. After this short high lake level period, the lake shrank because of the long-term lower temperature and reduced water supply. From 2200 to 1200 a B.P., the climate was hot and dry, and the lake shrank greatly. Although the temperature decreased somewhat from 1200 a B.P. to the present, the climate was warm and dry. The lake level began to rise a little again, but it did not reach the river bed altitude of the Konqi River, an outflow river of the Bosten Lake.     

Compatibility of NAPLs and Other Organic Compounds with Materials Used in Well Construction, Sampling, and Remediation

Structural integrity of well construction, sampling, and remediation materials may be compromised at many hazardous sites by nonaqueous phase liquids (NAPLs) and their dissolved constituents. A literature review of compatibility theory and qualitative field experiences are provided regarding the degradation and corrosion of materials in contact with NAPLs and organic compounds. A chemical compatibility table, compiled from several sources of compatibility testing results, is presented for 73 chemicals and 28 commonly used materials. Field experiences illustrate the compatibility problems of some of the common wastes and materials found at hazardous waste sites.     

Quartz latite rheoignimbrite flows of the Etendeka Formation,north-western Namibia

The Etendeka Formation of north-western Namibia consists of a sequence of interbedded quartz latites and tholeiitic basalts and forms part of the Karoo Igneous Province in southern Africa. The age of the Etendeka Formation is approximately 130–135 Ma. The quartz latites make up a significant proportion of the stratigraphic succession (<25% of the total stratigraphic thickness) and form as much as 60% of the outcrop area in the southern Etendeka. Apart from some systematic differences between pitchstones and devitrified quartz latite, largely explained by alteration processes, individual quartz latite units exhibit remarkably uniform compositions with no significant vertical or lateral variation. Geochemistry can be used as a primary criterion for the correlation of major quartz latite units over much of the southern Etendeka area enabling the reconstruction of the Etendeka Formation stratigraphy in this region. Individual quartz latite units occur as voluminous (400–2600 km³), widespread (up to 8800 km²), sheet-like deposits typically between 40 and 300 m thick. Each unit consists of basal, main and upper zones. The main zone generally constitutes over 70% of the thickness of the unit and typically consists of texturally featureless devitrified quartz latite. In contrast the basal and upper zones of the flow are characterised by flow banding, pitchstone lenses and breccia, with rare occurrences of pyroclastic textures. The quartz latites are sparsely porphyritic (<10% phenocrysts) with glassy or devitrified groundmass textures. The phenocrysts consist of plagioclase, pyroxene, titanomagnetite and rare ilmenite. Pyroxene geothermometry indicates high (1000–1100°C) temperatures of crystallisation which, coupled with the absence or primary hydrous phases, indicates that the quartz latites were relatively hot, H₂O-undersaturated magmas. The quartz latites display features common to both rhyolite lavas and ignimbrites and are clearly the products of an unusual eruption style. The local preservation of pyroclastic textures and the broad areal extent of these units lead to the conclusion that the quartz latites are high-temperature rheomorphic ignimbrites (i.e. rheoignimbrites). A combination of high eruption temperature and relatively low viscosity helps to explain the often completely welded and homogeneous textures observed in most quartz latite outcrops in the Etendeka area.     

An Analysis of Spatial and Temporal Dimension of Drought Vulnerability in Turkey Using the Standardized Precipitation Index

Drought has become a recurrent phenomenon in Turkey in the last few decades. Significant drought conditions were observed during years of late 1980s and the trend continued in the late 1990s. The countrys agricultural sector and water resources have been under severe constraints from the recurrent droughts. In this study, spatial and temporal dimensions of meteorological droughts in Turkey have been investigated from vulnerability concept. The Standardized Precipitation Index (SPI) method was used to detail geographical variations in the drought vulnerability based on frequency and severity of drought events at multiple time steps. Critical (threshold) rainfall values were derived for each station at multiple-time steps in varying drought categories to determine least amount of rainfall required to avoid from drought initiation. The study found that drought vulnerability portrays a very diverse but consistent picture with varying time steps. At regional scale, south-eastern and eastern Anatolia are characterized with moderate droughts at shorter time steps, while the occurrence of severe droughts at shorter time steps is observed at non-coastal parts of the country. A similar picture was observed with very severe droughts. The critical (threshold) values exhibited rising numbers during the growing season at 3-month step in the South-eastern Anatolia, which might have significant consequences considering presence of large irrigation projects under-development in the region. In general, rainfall amounts required for non-drought conditions decrease from the coastal parts toward the interiors with increasing time steps.