A laser-photolysis fragment-fluorescence (LPFF) method for the detection of gaseous nitric acid in ambient air

The development and first tests of a novel method for the direct, sensitive, selective, and fast detection of gaseous nitric acid in air are described. The detection method is based on the laser-photolysis fragment-fluorescence (LPFF) method using 193 nm (ArF) laser light. The photolysis process yielding OH fluorescence has been thoroughly investigated. Up to now, the method has been found to be practically free of interferences. The mixing ratio for nitric acid is measured on-line with a detection limit of about 0.1 ppbv for an accumulation time of the signal of 10–15 min. A number of tests and field measurements were performed to demonstrate the feasibility and limits of the described detection method.     

Measurement of gaseous HNO3 over the Atlantic Ocean

A latitudinal profile (30° W, from 30° N to 30° S) of mixing ratios of nitric acid and particulate nitrate was determined on the Atlantic Ocean during the Polarstern cruise ANT VII/1 from Bremerhaven, Germany, to Rio Grande, Brazil. The detection of HNO₃ was performed simultaneously by laser-photolysis fragment-fluorescence (LPFF) and by nylon filter packs. The detection limit was about 30 pptv for a signal accumulation time of 1 h for LPFF and about 5 pptv for the filters at a collection time of 4 h. In general, the mixing ratios of HNO₃ in the Northern Hemisphere were found to be significantly higher than those in the Southern Hemisphere. The Atlantic background concentrations frequently varied between 80 pptv and the detection limit. Larger deviations from this trend were found for the more northern latitudes and for episodes like crossings of exhaust plumes from ships or from continental pollutions sources.     

Anatomy of a subaqueous ice-contact fan and delta complex, Middle Pleistocene, North-west Germany

This paper presents a detailed analysis of the high‐resolution facies architecture of the Middle Pleistocene Porta subaqueous ice‐contact fan and delta complex, deposited on the northern margin of glacial Lake Weser (North‐west Germany). A total of 10 sand and gravel pits and more than 100 wells were examined to document the complex facies architecture. The field study was supplemented with a ground‐penetrating radar survey and a shear‐wave seismic survey. All collected sedimentological and geophysical data were integrated into a high‐resolution three‐dimensional geological model for reconstructing the spatial distribution of facies associations. The Porta subaqueous fan and delta complex consist of three fan bodies deposited on a flat lake‐bottom surface at the margin of a retreating ice lobe. The northernmost fan complex is up to 55 m thick, 6·2 km wide and 6·5 km long. The incipient fan deposition is characterized by high‐energy flows of a plane‐wall jet. Very coarse‐grained, highly scoured jet‐efflux deposits with an elongate plan shape indicate a high Froude number, probably >5. These jet‐efflux sediments are deposited in front of a large ～3·2 km long, up to 1·2 km wide, and up to 25 m deep flute‐like scour, indicating the most proximal erosion and bypass area of the jet that widens and deepens with distance downstream to the region of maximum turbulence (approximately five times the conduit diameter). Evidence for subsequent flow splitting is given by the presence of two marginal gravel fan lobes, deposited in front of 1·3 to 2·5 km long flute‐like scours, that are 0·8 to 1 km wide and 7 to 20 m deep. In response to continued aggradation, small jets developed at the periphery of these bar‐like deposits and filled in the low areas adjacent to the original superelevated regions, locally raising the depositional surface and characterized by large‐scale trough cross‐stratified sand and pebbly sand. The incision of an up to 1·2 km wide and up to 35 m deep channel into the evolving fan is attributed to a catastrophic drainage event, probably related to a lake outburst and lake‐level fall in the range of 40 to 60 m. At the mouth of this channel, highly scoured jet‐efflux deposits formed under hydraulic‐jump conditions during flow expansion. Subsequently, Gilbert‐type deltas formed on the truncated fan margin, recording a second lake‐level drop in the range of 30 to 40 m. These catastrophic lake‐level falls were probably caused by rapid ice‐lobe retreat controlled by the convex‐up bottom topography of the ice valley.     

Rural Development and Social Exclusion: A case study of sustainability and distributive issues in Brazil

Rural modernisation based on the concept of the Green Revolution has changed the social and ecological landscape in Brazil, particularly since the late 1960s. The expansion of extensive cattle ranching and mechanised agriculture have been major driving forces in this transformation process. In the Midwest, one of the last frontier regions in Brazil, extensive savanna land has recently been cleared for cash-crop production and pastureland. After the displacement of indigenous people during early confrontations with Portuguese explorers in the eighteenth century, we are now witnessing the dispossession of traditional small-scale farmers who had settled in the region two centuries ago. Rural communities have remained marginalised and powerless in the face of pressure and impact from recent development of agribusiness and cattle ranching. The agricultural activity of the smallholders is subsistence-oriented with little market integration, and their production system (shifting cultivation) is based on local knowledge, which seems to be well adapted to the savanna environment. The system is no longer sustainable. Due to capitalist expansion and prevailing conditions of unsecured land tenure, lack of access to basic assets, and high population pressure on scarce resources, the peasants have had to intensify production. This research focuses on the consequences of recent social, economic and environmental change in traditional rural communities.     

Evidence of iceberg-ploughing in a subaqueous ice-contact fan, glacial Lake Rinteln, NW Germany

The Coppenbrügge subaqueous ice‐contact fan complex of early Saalian age is about 10 km long and up to 10 km wide and is composed of offset‐stacked fan clinothems that are transgressive‐regressive sequences formed during an overall lake level rise. The individual fan bodies consist of coarse gravel in the ice‐proximal part, passing distally into sandy facies and showing large‐scale foreset bedding. The iceberg scour recognized in an open‐pit outcrop is up to 1.5m deep, up to 2m wide and cut in undisturbed mid‐fan deposits. The scour‐fill can be traced laterally for about 15m and consists of sheared sand and, in the frontal zone, of downbent overlying strata surrounded by a zone of deformed sediments. The deformed sediment produced by the iceberg keel's shearing of the trough walls is a sand mass containing angular soft‐sediment clasts that show internal folds and fractures. The basal surface of the deformed sediment is a nearly horizontal shear plane, steepening up laterally as a discrete thrust and showing a flat‐ramp‐flat geometry. The scour was formed by the iceberg keel's ploughing the substrate and pushing the sediment sideways and frontally, forming a ridge of deformed sediments at the trough end. This ridge was concurrently eroded by an accompanying meltwater underflow which apparently developed a horseshoe system of scouring vortices around the grounded iceberg. The current's scour was filled with massive, non‐stratified sand deposited rapidly from turbulent suspension. The iceberg eventually broke up and its keel part was buried. As these ice fragments gradually melted, the space was closed by normal faulting and downbending of overlying strata. The collapsing scour‐fill became partly liquified, and the resulting water‐escape structures cut the normal faults and the overlying deposits. Though produced chiefly by tangential shear strain, iceberg‐ploughing features are readily distinguishable from other glaciotectonic deformations. They can serve as a diagnostic criterion for glaciolacustrine or glaciomarine environments and the distinguishing of ice‐contact subaqueous fans from ice‐contact deltas in the stratigraphic record.     

Effects of the Herbicide Metazachlor on Phytoplankton and Periphyton Communities in Outdoor Mesocosms

The effects of the chloroacetanilide herbicide metazachlor have been investigated in outdoor artificial mesocosms. Decreasing phytoplankton densities were caused by the application, however, the communities recovered after 30 to 35 days. Periphyton growth was found to be affected not only by the herbicide application but by the presence of species with different ability to grow on artificial substrates. Zooplankton diversity was small due to low density of ingestible algae species. Oxygen saturation was found to be correlated with the dosage levels of the herbicide in the second half of the study.     

Assessment by microsatellite analysis of genetic diversity and population structure of Enhalus acoroides from the coast of Khanh Hoa Province, Vietnam

Seagrass beds degraded significantly since the last century on both, global and local scale. The seagrass species Enhalus acoroides (Linnaeus f.) Royle is a common species found in almost all marine ecosystems including bays, lagoons and around offshore islands in tropical regions of the West Pacific. It was shown that genetic diversity is an essential indicator of the conditions of ecosystems. In the present study, microsatellite markers were used to assess the genetic diversity and population structure of six distinct seagrass beds along the coast of the Khanh Hoa Province, Vietnam. The results indicate that the genetic diversity of the populations in the open sea is higher than in the lagoon. Seagrass beds occurring in disturbed sites show reduced genetic diversity. The fixing index value (F_ST) depicts a relatively high genetic structure among populations. Structure analysis clusters the populations into open sea and lagoon populations and cluster analysis and AMOVA indicate a significant difference between the two groups. There are low but non-significant positive correlations between geographic and genetic distances. The different habitats of the open sea and the lagoon are probably responsible for forming two groups.