Carbonaceous materials in size-segregated atmospheric aerosols from urban and coastal-rural areas at the Western European Coast

A high-volume cascade impactor, equipped with a PM10 inlet, was used to collect size-segregated aerosol samples during the summer of 2004 at two Portuguese locations: a coastal-rural area (Moitinhos) and an urban area (Oporto). Concentrations of airborne particulate matter (PM), total carbon (TC), organic carbon (OC), elemental carbon (EC), and water-soluble organic carbon (WSOC) were determined for the following particle size ranges: < 0.49, 0.49–0.95, 0.95–3.0, and 3.0–10 µm. The total PM mass concentrations at the urban and coastal-rural sites ranged from 22.8 to 79.6 μg m^− 3 and 19.9 to 28.2 μg m^− 3, respectively, and more than 56% of the total aerosol mass was found in the fractions below 3.0 μm. At both locations the highest concentrations of OC and EC were found in the submicrometer size range. The regional variability for the OC and EC concentrations, with the highest concentrations being found in the urban area, was related to the contribution of local primary sources (mostly traffic emissions). It was also verified an enrichment of the small size particles in WSOC, representing on average 37.3(± 12.4)% and 59.7(± 18.0)% of OC in the very fine aerosol at the coastal-rural and urban areas, respectively. The amount of secondary OC calculated by the minimum OC/EC ratio method indicates that secondary organic aerosol formation was important throughout the study at both sites. The obtained results suggest that long-range transport and favourable summer conditions for photochemical oxidation are key factors determining secondary OC formation in the coastal-rural and urban areas. The ultraviolet absorption properties of the chromophoric constituents of the WSOC fractions were also different among the different particle size ranges and also between the two sampling locations, thus suggesting the strong impact of the diverse emission sources into the composition of the size-segregated organic aerosol.     

Assessment of climate change impacts on the hydrology of the Peruvian Amazon–Andes basin

In this article, we propose an investigation of the modifications of the hydrological response of two Peruvian Amazonas–Andes basins in relationship with the modifications of the precipitation and evapotranspiration rates inferred by the IPCC. These two basins integrate around 10% of the total area of the Amazonian basin. These estimations are based on the application of two monthly hydrological models, GR2M and MWB3, and the climatic projections come from BCM2, CSMK3 and MIHR models for A1B and B1 emission scenarios (SCE A1B and SCE B1). Projections are approximated by two simple scenarios (anomalies and horizon) and annual rainfall rates, evapotranspiration rates and discharge were estimated for the 2020s (2008–2040), 2050s (2041–2070) and 2080s (2071–2099). Annual discharge shows increasing trend over Requena basin (Ucayali river), Puerto Inca basin (Pachitea river), Tambo basin (Tambo river) and Mejorada basin (Mantaro river) while discharge shows decreasing trend over the Chazuta basin (Huallaga river), the Maldonadillo basin (Urubamba river) and the Pisac basin (Vilcanota river). Monthly discharge at the outlet of Puerto Inca, Tambo and Mejorada basins shows increasing trends for all seasons. Trends to decrease are estimated in autumn discharge over the Requena basin and spring discharge over Pisac basin as well as summer and autumn discharges over both the Chazuta and the Maldonadillo basins. Copyright © 2011 John Wiley & Sons, Ltd.     

Basin-scale analysis of rainfall and runoff in Peru (1969–2004): Pacific,Titicaca and Amazonas drainages

Abstract

We present a procedure for estimating Q95 low flows in both gauged and ungauged catchments where Q95 is the flow that is exceeded 95% of the time. For each step of the estimation procedure, a number of alternative methods was tested on the Austrian data set by leave-one-out cross-validation, and the method that performed best was used in the final procedure. To maximise the accuracy of the estimates, we combined relevant sources of information including long streamflow records, short streamflow records, and catchment characteristics, according to data availability. Rather than deriving a single low flow estimate for each catchment, we estimated lower and upper confidence limits to allow local information to be incorporated in a practical application of the procedure. The components of the procedure consist of temporal (climate) adjustments for short records; grouping catchments into eight seasonality-based regions; regional regressions of low flows with catchment characteristics; spatial adjustments for exploiting local streamflow data; and uncertainty assessment. The results are maps of lower and upper confidence limits of low flow discharges for 21 000 sub-catchments in Austria.     

Relationship between bedload and suspended sediment in the sand-bed Exu River,in the semi-arid region of Brazil

Abstract

Suspended sediment and bedload discharges in sand-bed rivers shape semi-arid landscapes and impact sediment delivery from these landscapes, but are still incompletely understood. Suspended sediment and bedload fluxes of the intermittent Exu River, Brazil, were sampled by direct measurements. The highest suspended sediment concentration observed was 4847.4 mg L^-1 and this value was possibly associated with the entrainment of sediment that was deposited in the preceding year. The bedload flux was well related to the stream power and the river efficiently transported all available bedload with a mean rate of 0.0047 kg m^-1 s^-1, and the percentage of bedload to suspended sediment varied between 4 and 12.72. The bed sediment of Exu River was prone to entrainment and showed a proclivity for transport. Thus, sand-bed and gravel-bed rivers of arid environments seem to exhibit the same mobility in the absence of armour layer.

Editor D. Koutsoyiannis; Associate editor B. Touaibia

Citation Cantalice, J.R.B., Cunha Filho, M., Stosic, B.D., Piscoya, V.C., Guerra, S.M.S., and Singh, V.P., 2013. Relationship between bedload and suspended sediment in the sand-bed Exu River, in the semi-arid region of Brazil. Hydrological Sciences Journal, 58 (8), 1789–1802.     

Trends in rainfall and temperature in the Peruvian Amazon–Andes basin over the last 40 years (1965–2007)

The hydroclimatology of the Peruvian Amazon–Andes basin (PAB) which surface corresponding to 7% of the Amazon basin is still poorly documented. We propose here an extended and original analysis of the temporal evolution of monthly rainfall, mean temperature (T_mean), maximum temperature (T_max) and minimum temperature (T_min) time series over two PABs (Huallaga and Ucayali) over the last 40 years. This analysis is based on a new and more complete database that includes 77 weather stations over the 1965–2007 period, and we focus our attention on both annual and seasonal meteorological time series. A positive significant trend in mean temperature of 0.09 °C per decade is detected over the region with similar values in the Andes and rainforest when considering average data. However, a high percentage of stations with significant T_mean positive trends are located over the Andes region. Finally, changes in the mean values occurred earlier in T_max (during the 1970s) than in T_min (during the 1980s). In the PAB, there is neither trend nor mean change in rainfall during the 1965–2007 period. However, annual, summer and autumn rainfall in the southern Andes presents an important interannual variability that is associated with the sea surface temperature in the tropical Atlantic Ocean while there are limited relationships between rainfall and El Niño‐Southern Oscillation (ENSO) events. On the contrary, the interannual temperature variability is mainly related to ENSO events. Copyright © 2012 John Wiley & Sons, Ltd.     

Artisanal fishing in Andalusia (and III): “The Day After…”

During the past 5 years researchers from the University of Cádiz have carried out several studies on artisanal fishing in Andalusia, with the object of determining the state of the fleet and safety on board vessels. These studies have been financed largely with help from the European Union. In this third approach to the topic, the census of the fleet is updated and the changes that have taken place are considered from two perspectives: the influence of the policies implemented by the various governmental authorities, and the dynamic of the new commercial scenarios. For this study special emphasis is given to those communities in the SW of the province of Cádiz where the policies associated with the Treaties with the Kingdom of Morocco have had a decisive impact.     

Combined use of aerogammaspectrometry and geochemistry to access sediment sources in a shallow coral site at Armação dos Búzios,Brazil

Coral and reef environments in shallow waters are negatively affected by human activities in several coastal areas worldwide. It has been demonstrated that sediment influx and macronutrient discharges induce decline of coral population structure and diversity. Therefore, efforts to quantify sediment flux, sources and the biological response to sedimentation were conducted by several marine researchers. Herein, we investigated the case study of Armação dos Búzios/Brazil/Western South Atlantic, where coral colonies (mostly Siderastrea stellata) are under stress due to sediment apportionment as a consequence of regional human occupation. Classification of potential sediment source regions was based on a high-resolution aerogammaspectrometry survey for ²³²Th, ²³⁸U and ⁴⁰K in main land near shore, used as primarily tool, in combination with sediment geochemistry. This approach allowed distinguishing three hydrographic basins (Macaé river basin, São João river basin and Una river basin) as potential sources. Hierarchical cluster analysis applied to the set of parameters identified the Macaé River as the most probable sediment contributor to the coralline site.     

Assessment of the exploitable biomass of thread herring(Opisthonema spp.) in northwestern Mexico

In recent years, the small pelagic fishery on the Pacific northwest coast of Mexico has significantly increased fishing pressure on thread herring Opisthonema spp. This fishery is regulated using a precautionary approach(acceptable biological catch(ABC) and minimum catch size). However, due to fishing dynamics, fish aggregation habits and increased fishing mortality, periodic biomass assessments are necessary to estimate ABC and assess the resource status. The Catch-MSY approach was used to analyze historical series of thread herring catches off the western Baja California Sur(BCS, 1981–2018) and the Gulf of California(GC, 1972–2018) to estimate exploitable biomass and target reference points in order to obtain catch quotas. According to the results, in GC,the maximum biomass reached in 1972(at the beginning of fishery) and minimum biomass reached in 2015; the estimated exploitable biomass for 2019 was 42.2×10~4 t; and the maximum sustainable yield(MSY) was 15.4×10~4 t.In the western BCS coast, the maximum biomass was reached in 1981(at the beginning of fishery) and minimum biomass was reached in 2017; the estimated exploitable biomass for 2019 was 3.2×10~4 t; and the MSY was 1.2×10~4 t.Both stocks showed a decrease in biomass over the past years and were currently near to point of full exploitation.The results suggest that the use of the Catch-MSY method is suitable to obtain annual biomass estimates, in order to establish an ABC, to know the current state of the resource, and to avoid overcoming the potential recovery of the stocks.     

Synchronous Scan and Excitation-Emission Matrix Fluorescence Spectroscopy of Water-Soluble Organic Compounds in Atmospheric Aerosols

Three-dimensional excitation–emission matrix (EEM) fluorescence spectra of water-soluble organic compounds (WSOC) from aerosol samples were measured and compared with those reported in the literature for natural dissolved organic matter. The EEM profiles of the WSOC presented three characteristic excitation/emission (_Exc/_Em) peaks: 240/405 nm, 310/405 nm and 280/340 nm. The fluorescence intensities at _Exc/_Em240/405 nm and _Exc/_Em310/405 nm are located at wavelengths shorter than those reported for aquatic humic substances, indicating a smaller content of both aromatic structures and condensed unsaturated bond systems in the WSOC fraction. The EEM profiles of fractions obtained by the isolation procedure of the WSOC by the XAD resins showed that a fractionation has occurred and the XAD-8 eluate is highly representative of the total WSOC of collected aerosol. Synchronous scan spectra were more detailed than conventional fluorescence emission spectra, appearing more suitable for studying multicomponent samples such as the WSOC from atmospheric aerosols.     

Water resources and climate change impact modelling on a daily time scale in the Peruvian Andes

Abstract

Estimating water resources is important for adequate water management in the future, but suitable data are often scarce. We estimated water resources in the Vilcanota basin (Peru) for the 1998–2009 period with the semi-distributed hydrological model PREVAH using: (a) raingauge measurements; (b) satellite rainfall estimates from the TRMM Multi-satellite Precipitation Analysis (TMPA); and (c) ERA-Interim re-analysis data. Multiplicative shift and quantile mapping were applied to post-process the TMPA estimates and ERA-Interim data. This resulted in improved low-flow simulations. High-flow simulations could only be improved with quantile mapping. Furthermore, we adopted temperature and rainfall anomalies obtained from three GCMs for three future periods to make estimations of climate change impacts (Delta-change approach) on water resources. Our results show more total runoff during the rainy season from January to March, and temporary storages indicate that less water will be available in this Andean region, which has an effect on water supply, especially during dry season.

Editor Z.W. Kundzewicz; Associate editor D. Gerten