Potential map of gas hydrate formation in Caspian Sea based on physicochemical stability evaluation of methane hydrate

Preliminary studies of Caspian Sea have shown the possibility of gas hydrate accumulations, because of suitable physicochemical conditions, existence of clayey deposits, and high concentrations of organic matter. Studies have indicated that gas hydrates are mainly composed of methane. Therefore, based on physicochemical equations for methane hydrate stability in different pressure, temperature, and salinity, this study was designed to calculate the potential of gas hydrate formation in the Caspian Sea basin. For this, data of more than 600 locations were analyzed and in each location, upper and lower limits of methane hydrate formation zone were calculated. Then, the zoning maps of upper and lower limits were prepared which can be useful for exploring the gas hydrate as an energy source or predicting gas hydrate hazards. According to the calculations and maps, methane hydrate formation in Caspian Sea, theoretically, can take place from near the seabed to 4000 and 2500 m beneath the sea surface when low and high geothermal gradient are supposed, respectively. By comparing the results with gas hydrate zones revealed in geophysical profiles, it has been shown that, in Caspian Sea, gas hydrates probably accumulate near the lower limit when a high geothermal gradient is assumed.     

Characterization of natural hydrocarbon seepage in the South Caspian Sea off Iran using satellite SAR and geological data

Abstract

Two groups of oil slicks have been repeatedly detected in the Southern Caspian Sea, off Cape Sefidrud and close to the Iranian coast of the sea on the synthetic aperture radar (SAR) images acquired by the Sentinel-1A and Sentinel-1B satellites in April–June 2018. Analysis of the SAR images together with bathymetry, geological and geophysical data in geographic information system showed that these manifestations (oil slicks) visible on the sea surface have natural origin, related to the bottom seepage phenomenon and are associated with existing hydrocarbon system. Oil slicks are concentrated over the continental slope and related to local geological formations of the sedimentary cover having oil deposits related to paleo-delta of Sefidrud River. Our evidence shows that two seeps in this area are active and repeating. It is concluded that the SAR is an excellent tool for monitoring of seepage phenomenon. Moreover, results indicate that the use of remote methods to identify offshore natural oil seeps related to existing active petroleum system can be considered as a well-accepted approach to support oil and gas exploration in frontier areas such as the South Caspian Basin.