Influx of Streaming Methane into Anoxic Waters of the Black Sea Basin

Oceanology - Based on long-term data on the spatial distribution and fluxes of streaming (bubbling) methane in the Black Sea, the study considers various types of streaming gas emissions...     

Methane in the Sevastopol coastal area, Black Sea

Concentrations of dissolved methane in seawater and bottom sediments, as well as of methane emanating from gas seeps were measured at 18 stations including several small bays in the Sevastopol coastal area (Black Sea) during 2007–2008. Methane concentrations in surface waters ranged from 10 to 2,970 nmol l^?1, and correlated well with values recorded for sediments. Methane concentrations in the water column were influenced by water depth, as well as by air and water temperatures. In the spring and summer of 2008, in situ CH₄ saturation relative to air was in the range of 970–71,900%. Maximum saturation was in summer. CH₄ fluxes to the atmosphere from the Sevastopol coastal area were estimated to vary from 190 to 1,550 μmol m^?2 day^?1. Gas bubbles escaping from the seepages contained about 57 vol% methane. Radiocarbon dating of the methane revealed an age not exceeding 150 years, implying a biogenic origin.     

Vodyanitskii mud volcano,Sorokin trough,Black Sea: Geological characterization and quantification of gas bubble streams

Vodyanitskii mud volcano is located at a depth of about 2070 m in the Sorokin Trough, Black sea. It is a 500-m wide and 20-m high cone surrounded by a depression, which is typical of many mud volcanoes in the Black Sea. 75 kHz sidescan sonar show different generations of mud flows that include mud breccia, authigenic carbonates, and gas hydrates that were sampled by gravity coring. The fluids that flow through or erupt with the mud are enriched in chloride (up to ∼650 mmol L⁻¹ at ∼150-cm sediment depth) suggesting a deep source, which is similar to the fluids of the close-by Dvurechenskii mud volcano. Direct observation with the remotely operated vehicle Quest revealed gas bubbles emanating at two distinct sites at the crest of the mud volcano, which confirms earlier observations of bubble-induced hydroacoustic anomalies in echosounder records. The sediments at the main bubble emission site show a thermal anomaly with temperatures at ∼60 cm sediment depth that were 0.9 °C warmer than the bottom water. Chemical and isotopic analyses of the emanated gas revealed that it consisted primarily of methane (99.8%) and was of microbial origin (δD-CH₄ = −170.8‰ (SMOW), δ¹³C-CH₄ = −61.0‰ (V-PDB), δ¹³C-C₂H₆ = −44.0‰ (V-PDB)). The gas flux was estimated using the video observations of the ROV. Assuming that the flux is constant with time, about 0.9 ± 0.5 × 10⁶ mol of methane is released every year. This value is of the same order-of-magnitude as reported fluxes of dissolved methane released with pore water at other mud volcanoes. This suggests that bubble emanation is a significant pathway transporting methane from the sediments into the water column.     

The Dnepr Canyon: evidence for a continuous submarine channel link between the outer shelf and the deep-sea basin of the northwestern Black Sea

Multibeam bathymetric surveys and single-beam profiles were collected in 2003–2010 from aboard the Ukrainian RV Professor Vodyanitskiy (cruises PV-58 and PV-60, 2003 and 2004), and the German RV Meteor (cruise M-72, legs 1 and 4, 2007) and RV Maria S. Merian (cruise MSM-15, leg 2, 2010) along the continental margin of the NW Black Sea. Integrating published, reprocessed and novel data has revealed the existence of a major continuous channel extending from the Dnepr paleo-delta into greater water depths. It is more than 90 km long, 1.1 km wide and up to 125 m deep. On the upper slope (120–960 m water depth), a number of smaller channels merge into the large, Y-shaped Dnepr Canyon, which then continues obliquely downslope via this submarine channel to at least 1,815 m water depth off the Crimean continental margin, NW Black Sea. The channel could be an important, hitherto unknown link between the shallow oxic and deep anoxic environments of the Black Sea, along which sediment and organic matter could be funneled into the deep-sea basin. This would have far-reaching implications for investigations dealing with marine geology and biology, climate change, as well as oil and natural gas exploitation. The unusual alignment of the channel along the margin of the basin, as well as the location and mode of channel termination in deeper waters deserve future research.     

Cartographic generalization of radioecological conditions in the South Urals

Considered are the structure and contents of the Atlas of the East Ural and Karachai Radioactive Traces being the first cartographic generalization of current radioecological conditions in the South Urals.     

Mud volcanoes and gas hydrates in the Black Sea: new data from Dvurechenskii and Odessa mud volcanoes

Meteor cruise M52/1 documented the presence of gas hydrates in sediments from mud volcanoes in the Sorokin Trough of the Black Sea. In a mud flow on the Odessa mud volcano, a carbonate crust currently forms in association with anaerobic methane oxidation. Dvurechenskii mud volcano (DMV), a flat-topped mud pie-type structure, appeared to be very active. Pore water in sediments of DMV is enriched in several constituents, such as ammonium and chloride, which seem to originate at depth. High sediment temperatures of up to 16.5 °C in close contact to the ambient bottom water of 9 °C also suggest strong advective transport of material from greater depth. Steep temperature gradients indicate a high fluid and/or mud flux within DMV, which is confirmed by the shape of the pore water profiles. Active fluid expulsion sites are evidenced by direct seafloor observation, and a potential flux of methane from the sediment to the bottom water is indicated by water-column methane measurements.     

Acid-base characteristics of Russian snow cover

The results of pH measurement results are summarized for 1994–2004. These were obtained from the snow pollution and acidity monitoring network in the Russian Federation. A map of acid-base characteristics is compiled for the Russian territory. The zones of the most frequent cases of snow acidification are singled out. Dependence of pH values on the concentration of acid-forming anions neutralizing cation acids is established based on the ion balance analysis.