Oxygen isotopic compositions of Allende Type C CAIs: Evidence for isotopic exchange during nebular melting and asteroidal metamorphism

In situ oxygen isotopic measurements of primary and secondary minerals in Type C CAIs from the Allende CV3 chondrite reveal that the pattern of relative enrichments and depletions of ¹⁶O in the primary minerals within each individual CAI are similar to the patterns observed in Types A and B CAIs from the same meteorite. Spinel is consistently the most ¹⁶O-rich (Δ¹⁷O = −25‰ to −15‰), followed by Al,Ti-dioside (Δ¹⁷O = −20‰ to −5‰) and anorthite (Δ¹⁷O = −15‰ to 0‰). Melilite is the most ¹⁶O-depleted primary mineral (Δ¹⁷O = −5‰ to −3‰). We conclude that the original melting event that formed Type C CAIs occurred in a ¹⁶O-rich (Δ¹⁷O  −20‰) nebular gas and they subsequently experienced oxygen isotopic exchange in a ¹⁶O-poor reservoir. At least three of these (ABC, TS26F1 and 93) experienced remelting at the time and place where chondrules were forming, trapping and partially assimilating ¹⁶O-poor chondrule fragments. The observation that the pyroxene is ¹⁶O-rich relative to the feldspar, even though the feldspar preceded it in the igneous crystallization sequence, disproves the class of CAI isotopic exchange models in which partial melting of a ¹⁶O-rich solid in a ¹⁶O-poor gas is followed by slow crystallization in that gas. For the typical (not associated with chondrule materials) Type C CAIs as well for as the Types A and B CAIs, the exchange that produced internal isotopic heterogeneity within each CAI must have occurred largely in the solid state. The secondary phases grossular, monticellite and forsterite commonly have similar oxygen isotopic compositions to the melilite and anorthite they replace, but in one case (CAI 160) grossular is ¹⁶O-enriched (Δ¹⁷O = −10‰ to −6‰) relative to melilite (Δ¹⁷O = −5‰ to −3‰), meaning that the melilite and anorthite must have exchanged its oxygen subsequent to secondary alteration. This isotopic exchange in melilite and anorthite likely occurred on the CV parent asteroid, possibly during fluid-assisted thermal metamorphism.     

Mineralogical characterization of a unique material having heavy oxygen isotope anomaly in matrix of the primitive carbonaceous chondrite Acfer 094

We report the mineral compositions and micro-texture of the isotopically anomalous (δ^17,18O_SMOW ∼ +180‰) Fe-S-Ni-O material recently discovered in matrix of the primitive carbonaceous chondrite Acfer 094 [Sakamoto N., Seto Y., Itoh S., Kuramoto K., Fujino K., Nagashima K., Krot A. N. and Yurimoto H. (2007) Oxygen isotope evidence for remnants of the early solar system primordial water. Science317, 231-233]. Synchrotron radiation X-ray diffraction and transmission electron microscopy studies indicate that this material consists of the symplectitically intergrown magnetite (Fe₃O₄) and pentlandite (Fe_5.7Ni_3.3S₈) with magnetite/pentlandite volume ratio of ∼2.3. Magnetite forms column-shaped grains (10-30 nm in diameter and 100-200 nm in length); pentlandite occurs as worm-shaped grains or aggregates of grains 100-300 nm in size between magnetite crystals. Although both the X-ray diffraction and electron energy loss spectra support identification of iron oxide as magnetite, the electron diffraction patterns show that magnetite has a weak 3-fold superstructure, possibly due to ordering of vacancies. We infer that the isotopically anomalous symplectite formed by sulfurization and oxidization of metal grains either in the solar nebula or on an icy planetesimal. The intersite cation distribution of pentlandite suggests that timescale of oxidation was no longer than 1000 years.     

Cycladophora davisiana (Radiolaria) in the Okhotsk Sea: A key for reconstructing glacial ocean conditions

Cycladophora davisiana, a radiolarian species dwelling at mesopelagic depths, is known as a representative glacial fauna due to its unique distribution during glacial periods. In the present ocean, abundant production of C. davisiana is only observed in the Okhotsk Sea, indicating an adaptation of C. davisiana for seasonal sea-ice covered conditions. We found pronounced abundant production of C. davisiana during the early to middle Holocene in the Okhotsk Sea, suggesting more favorable conditions for C. davisiana than the present Okhotsk Sea. In order to clarify the reason, oceanographic conditions during the Holocene were reconstructed based on biomarkers, lithogenic grains including ice-rafted debris (IRD), biogenic opal, and total organic carbon (TOC) in two sediment cores from the Okhotsk Sea. These indicators suggest that the pronounced C. davisiana production may be attributed to: 1) a supply to mesopelagic depths under intensified stratification of fine organic particles derived from coccolithophorids, bacteria, and detrital materials; and 2) cold, well-ventilated intermediate water formation.     

Manganese and iron distributions off central California influenced by upwelling and shelf width

In July 2002, a combination of underway mapping and discrete profiles revealed significant along-shore variability in the concentrations of manganese and iron in the vicinity of Monterey Bay, California. Both metals had lower concentrations in surface waters south of Monterey Bay, where the shelf is about 2.5 km wide, than north of Monterey Bay, where the shelf is about 10 km wide. During non-upwelling conditions over the northern broad shelf, dissolvable iron concentrations measured underway in surface waters reached 3.5 nmol L⁻¹ and dissolved manganese reached 25 nmol L⁻¹. In contrast, during non-upwelling conditions over the southern narrow shelf, dissolvable iron concentrations in surface waters were less than 1 nmol L⁻¹ and dissolved manganese concentrations were less than 5 nmol L⁻¹. A pair of vertical profiles at 1000 m water depth collected during an upwelling event showed dissolved manganese concentrations of 10 decreasing to 2 nmol L⁻¹, and dissolvable iron concentrations of 12–20 nmol L⁻¹ in the upper 100 m in the north, compared to 3.5–2 nmol L⁻¹ Mn and 0.6 nmol L⁻¹ Fe in the upper 100 m in the south, suggesting the effect of shelf width influences the chemistry of waters beyond the shelf.These observations are consistent with current understanding of the mechanism of iron supply to coastal upwelling systems: Iron from shelf sediments, predominantly associated with particles greater than 20 μm, is brought to the surface during upwelling conditions. We hypothesize that manganese oxides are brought to the surface with upwelling and are then reduced to dissolved manganese, perhaps by photoreduction, following a lag after upwelling.Greater phytoplankton biomass, primary productivity, and nutrient drawdown were observed over the broad shelf, consistent with the greater supply of iron. Incubation experiments conducted 20 km offshore in both regions, during a period of wind relaxation, confirm the potential of these sites to become limited by iron. There was no additional growth response when copper, manganese or cobalt was added in addition to iron. The growth response of surface water incubated with bottom sediment (4 nmol L⁻¹ dissolvable Fe) was slightly greater than in control incubations, but less than in the presence of 4 nmol L⁻¹ dissolved iron. This may indicate that dissolvable iron is not as bioavailable as dissolved iron, although the influence of additional inhibitory elements in the sediment cannot be ruled out.     

Reconstruction of sea surface dimethylsulfide in the North Pacific during 1970s to 2000s

We proposed an empirical equation of sea surface dimethylsulfide (DMS, nM) using sea surface temperature (SST, K), sea surface nitrate (SSN, μM) and latitude (L, °N) to reconstruct the sea surface flux of DMS over the North Pacific between 25°N and 55°N: ln DMS = 0.06346 · SST − 0.1210 · SSN − 14.11 · cos(L) − 6.278 (R² = 0.63, p < 0.0001). Applying our algorithm to climatological hydrographic data in the North Pacific, we reconstructed the climatological distributions of DMS and its flux between 25 °N and 55 °N. DMS generally increased eastward and northward, and DMS in the northeastern region became to 2–5 times as large as that in the southwestern region. DMS in the later half of the year was 2–4 times as large as that in the first half of the year. Moreover, applying our algorithm to hydrographic time series datasets in the western North Pacific from 1971 to 2000, we found that DMS in the last three decades has shown linear increasing trends of 0.03 ± 0.01 nM year^− 1 in the subpolar region, and 0.01 ± 0.001 nM year^− 1 in the subtropical region, indicating that the annual flux of DMS from sea to air has increased by 1.9–4.8 μmol m^− 2 year^− 1. The linear increase was consistent with the annual rate of increase of 1% of the climatological averaged flux in the western North Pacific in the last three decades.     

Universal birefringent filter with a new double passband mode

This article describes the universal birefringent filter (UBF) which will be mounted at Taiwan. The UBF permits observations of solar images, vector magnetic fields and/or line-of-sight velocity fields in any Fraunhofer line in the wavelength region from 4000 to 7000 with half width from 0.05 to 0.14 . We have tested it at ten Fraunhofer lines under a spectral telescope in Huairou Station of Beijing Astronomical Observatory and obtained the passband profiles. The principles of magnetic field and velocity field measurement with the UBF are also described.     

PDC钻头切削齿破岩载荷规律的分析

对PDC钻头冠部形状及不同的布齿密度和切削齿在不同的磨损状态下对PDC钻头切削齿受力的影响进行了分析；用相邻的3个切削齿之间的关系(不同的切削齿与切削齿之间的径向距离和切削齿之间的高度差)来分析PDC钻头冠部形状和切削齿布齿密度对切削齿受力的影响，以及将切削齿的磨损状态简化成与切削齿在钻头上装配方向垂直的平面来分析切削齿磨损状态对切削齿受力的影响。     

叶尔羌河冰川阻塞性洪水发生的气象因素

2002年8月12日，叶尔羌河再次发生因高原冰川阻塞形成的洪水。本文对叶尔羌河历次高原冰川阻塞性洪水的成因以及与气象的关系做了较详尽的分析，并提出了从气象角度预报该类型洪水的方法和利用卫星遥感技术对冰川阻塞湖进行监测的建议，期望对叶尔羌河今后的防洪工作有一些指导意义。     

Exploring the spatial and temporal dynamics of land use in Xizhuang watershed of Yunnan, southwest China

Over the last two decades, China has introduced a series of agricultural and forestland use reforms, aiming to feed the largest population in the world and maintain ecological services locally and nationally. This paper studies the impacts of local government-driven reforestation on land use and land cover change, as well as its further impacts on livelihoods of upland farmers in Xizhuang watershed. An analysis of aerial photographs and ASTER satellite imagery from 1987 to 2002, respectively, showed that the forest has significantly increased at the expense of decreasing farmland. However, the monoculture reforestation of pine has caused both biophysical and socio-economic consequences. This case study also shows forestry decentralization in China remains incomplete. Land use and land cover change is also a political economic issue. Some of the reforms designed to protect forest resources have had a negative impact on rural livelihoods.     

祁连山林区大气降水特征与森林对降水的截留作用

通过对连山寺大隆林区定位站1975－2000年的降水特征与森林对降水的再分配分析，建立了祁连山大隆林区降水与温度，降水与湿度，林冠截留的关系式。该区多年平均降水量为433.5mm，年变幅在326.4-539.7mm;降水量最大出现在夏季，占全年降水量的65．70％；海拔高度每升高100m，年了量平均递增4．55％，林区温度和湿度均与降水有较好的拟合关系。青海云杉林与祁连圆柏林林冠对大气降水的平均截留率分别为37．5％，31．7％，灌木林的截留率平均高达66．5％。青海云杉林林冠层平均截留率随着降雨量的增大逐渐减小，当降雨量为18.67mm时，林冠截留量达到最大，为14.72mm；青海云杉树干径流量占降水量的0．51％，当降雨量超过12.0mm时，才开始产生树干径流。青海云杉林枯枝落叶层对降雨的截留量随降雨量级增加而增大，截留率则随降雨量减小而增大，枯枝落叶层所具有的截留降雨和调蓄降雨作用使祁连山林区基本不发生地表径流。分析结果表明，祁连山林区对水源涵养和水流出山的时间调控有重要意义。