南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.     

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

载波/多普勒平滑伪距在Android手机中的定位实现

针对Android手机GNSS伪距定位精度较低的问题，利用手机端观测信息，通过载波相位/多普勒平滑伪距改善手机端伪距观测值的质量，从而达到提高定位精度的效果。首先给出了Android手机GNSS原始观测量的获取方法，然后推导了载波相位平滑伪距和多普勒平滑伪距算法模型，并设计合理有效的试验对算法的精度进行评定。试验结果表明：在手机端静态定位中载波相位和多普勒平滑算法均可提高原始伪距的定位精度，且多普勒平滑算法表现更优；在手机端动态定位中多普勒平滑算法可获得比原始伪距更优的定位精度，但是载波相位平滑算法较原始伪距更差；由于硬件的制约手机端周跳和信号失锁严重，占比超过50%，载波相位在手机端的可用性较低；多普勒平滑算法的最优平滑时间常数小于等于10 s，具有实时动态定位的巨大潜力。     

河南东秦岭北麓的推覆构造及煤田分布

在东秦岭山脉的北部山麓,存在一个规模宏大的推覆构造带。该构造带大多为新生界所覆盖,仅豫西断续出露于地表。本文即根据豫西的研究,指出该带的展布、特征、形成时代及产生的地质背景,并对山麓带煤田的类型划分和受构造推覆的隐伏煤田找煤前景等作了简要叙述。     

当前解决土地执法难的思考与对策

长期以来，国土资源管理工作中一直存在土地执法难问题。归纳起来，主要表现在以下几个方面。     

MONITORING THE DIFFUSION OF SUSPENDED SEDIMENTS AND STABILITY OF TIDAL RADIAL SAND RIDGES AREA USING MULTI-SATELLITE REMOTE SENSING DATA

Nine Landsat TM tapes and images and MSS images, 10 NOAA tapes and images and 1 SAR image from 1973 to 1997 were used to analyse the diffusion of suspended sediments and the change of tidal radial sand ridges in the northern part of the Changjiang River delta, the South Yellow Sea. The results showed that the diffusion of suspended sediments was controlled by the tide, net current, and submarine topography in this area. The distribution of suspended sediments had close relationship with thesubmarine topography. The old Huanghe River delta and the Changjiang River comprise the main sediment supply for the formation of radial sand ridges, whose evolution can be divided into three stages since the Huangbe River changed its course and flowed northward into the Bohai Sea.     

玉泉观站外来树种栽植区昆虫种类调查研究

2004年甘肃省天水市秦州区林业局玉泉观站引进了5种外来树种,分别是:美国杏李(Prunus domestica×P. armeniaca)、美国东部黑核桃(Juglans nigra)、四倍体刺槐(Robinia pseudoacacia Linn.)、树莓(Rubus sp.)和无刺大果沙棘(Hippophae rhamnoides)。为了确定有无外来物种入侵,2006年对玉泉观站外来树种栽植区进行昆虫种类调查,采用手工捕捉结合网捕的方法采集昆虫标本,经鉴定分析共有45种昆虫,其中有害虫31种,分属于5目21科;天敌昆虫14种,分属于5目11科,种类最多的是鞘翅目昆虫,分别占害虫总数和天敌昆虫总数的35.5%和35.7%。45种昆虫均为当地种,说明引进外来树种没有造成外来物种入侵。