Geophysical and geochemical evidence of Proterozoic collision in the western marginal zone of the Baltic Shield

New continental crust was formed in the Svecofennian domain of the Baltic Shield c. 1.9 Ga ago. Approximately 0.1–0.15 Ga later, new crust accreted to the SW part of the Shield. In this paper an attempt is made, on the basis of gravity measurements and lithogeochemistry, to describe the tectonic processes responsible for the continental growth c. 1.75–1.8 Ga ago. The Transscandinavian Granite Porphyry Belt (TGPB) separates the Svecofennian domain from the polymetamorphic terrain of the SW Swedish gneiss region. Red orthogneisses occurring immediately west of the TGPB are the deformed equivalents of the TGPB type granitoids, while grey orthogneisses, displaying a tonalitic-granodioritic trend and situated further west, were generated in a »volcanic arc« environment. The TGPB granitoids and the red SW Swedish gneisses represent a transition from this volcanic arc type rock to contemporaneous »within-plate« type granites intruded in the Svecofennian crust. The volcanic arc was forced against the Svecofennian crust in which large tensional fracture zones ensued with strike directions normal to the collision front. In such tensional environments the »withinplate« type granites were generated. In the collision zone the crust was down-warped, and huge amounts of granitic melts were generated at the base of the crust. This TGPB Magma rose upwards utilizing the fracture zone between the arc rocks, generated slightly earlier, and the Svecofennian crust. A relatively thin upper part of the TGPB that spread laterally westwards became strongly deformed during the collision (i.e. the red SW Swedish gneisses), while the major deep-reaching TGPB root zone that was not completely solidified yet, acted as a buffer against the foliation front.

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Zusammenfassung Vor 1,9 Milliarden Jahren kam es zur Neubildung von kontinentaler Kruste im svecofennischen Bereich des Baltischen Schildes. Ungefähr 100–150 Millionen Jahre später wurde im Südwesten des Schildes neue Kruste hinzugefügt. In diesem Artikel wird auf der Basis von Gravimetriemessungen und Lithogeochemie der Versuch unternommen die tektomschen Vorgänge, die zu diesem 1,75–1,8 Milliarden Jahre alten Krustenzuwachs führten, zu beschreiben.Der Transskandinavische-Granit-Porphyr-Gürtel (Transscandinavian-Granite-Porphyry-Belt/TGPB) trennt das Svecofennium von der polymetamorphen, im Südwesten Schwedens gelegenen Gneis-Region. Ein direkt westlich des TGPB gelegenes Vorkommen roter Orthogneise entspricht den deformierten TGPB Granitoiden. Graue Orthogneise, die weiter im Westen aufgeschlossen sind, zeigen eine mehr tonalitische bis granodioritische Zusammensetzung und werden auf einen vulkanischen Inselbogen zurückgeführt. Die TGPB Granitoide und die roten südwest-schwedischen Gneise stellen einen Übergang von den Inselbogen-Vulkaniten zu den zeitgleichen »Intra-Platten-Graniten« der svecofennischen Kruste dar. Der Inselbogen kollidierte mit der svecofennischen Kruste, es entstanden großräumige Bruchzonen mit Streichrichtungen senkrecht zur Kollisionsebene. Während des Zustands der hohen Druckspannung des Gebietes intrudierten die »Intra-Platten-Granite«. Innerhalb des Kollisionsbereiches wurde die Kruste nach unten gebogen, und so entstanden an der Basis der Kruste große Mengen granitischen Magmas. Dieses TGPB Magma stieg entlang der Störungszone innerhalb der Inselbogengesteine, die nur wenig älter sind, und der svecofennischen Kruste, auf. Nur ein, von relativ geringer Mächtigkeit, weiter westlich gelegener Teil des TGPB, die roten südwest-schwedischen Gneise, wurde während der Kollision intensiv deformiert. Dagegen war der Hauptanteil der tiefreichenden TGPB Wurzelzone noch nicht vollständig erstarrt und wirkte deshalb wie eine Pufferzone gegen die Schieferungsfront.

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Résumé De la croûte continentale nouvelle s'est formée il y a 1,9 Ga dans le domaine des Svecofennides (Bouclier baltique). Environ 100 à 150 Ma plus tard, de la croûte nouvelle s'est accrétionnée à la bordure sud-ouest du bouclier. Cette note basée sur des mesures de gravité et la lithogéochimie, présente un essai d'analyse des processus tectoniques responsables de cette croissance continentale d'âge 1,75 à 1,8 Ga. Le «Transcandinavian Granite Porphygry Belt» (TGPB) sépare le domaine svécofennien des gneiss polymétamorphiques du sud-ouest de la Suède. Immédiatement à l'ouest de TGPB affleurent des orthogneiss rouges qui représentent l'équivalent déformé de granitoïdes du TGPB, tandis que des orthogneiss gris de tendance tonalitique-granodioritique, situés plus à l'ouest, ont été engendrées dans un environnement d'arc volcanique. Les granitoïdes du TGPB et les gneiss rouges du sud-ouest de la Suède représentent une transition entre ces produits d'arc volcanique et les granites intra-plaque de même âge intrudés dans la croûte svécofennienne. L'arc volcanique a été accrétionné à la croûte svécofennienne avec production dans celleci de grandes fractures d'extension perpendiculaires au front de collision. C'est dans ce domaine en extension que les granites intra-plaque se sont mis en place. Dans la zone de collision, la croûte s'est incurvée vers le bas et de grandes quantités de liquides granitiques ont été engendrées à la base de la croûte. Ces magmas TGPB sont montés à la faveur de la zone fracturée entre les roches de l'arc engendrée un peu plus tôt, et la croûte svécofennienne. Seule une fraction supérieure relativement mince du TGPB, développée vers l'ouest, a subi une déformation importante au cours de la collision, pour former les gneiss rouges du sud-ouest de la Suède; par contre, la partie principale de la racine profonde du TGPB, qui n'était pas encore entièrement solidifiée, a joné le role tampon en avant du front de foliation.

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Migration of lignosulfonates in a karstic-fractured-porous aquifer: History and prognosis for a Zn-Pb mine,Pomorzany, southern Poland

Lignosulfonate lyes, which had been deposited by a paper factory for about 50 years into Quaternary sediments and accumulated in a quasistagnant depression, became mobile when a depression cone caused by mine activity in a deeper aquifer reached the erosion window close to the disposal site. Their transport parameters in the karstic-fractured-porous carbonate aquifer are shown to be mainly governed by diffusion between the mobile water in karstic channels and fractures and the stagnant water in matrix, although the hydraulic conductivity is shown to depend mainly on the karstic system. The main transport velocity is, with a sufficient accuracy, related to the hydraulic conductivity by a simple model in which matrix porosity is the governing rock parameter. The dispersivity, although also governed by matrix diffusion, depends strongly on several parameters that are difficult to determine.     

Transport of three herbicides in ground water at Twin Lake test site,Chalk River,Ontario, Canada

A field tracer test performed under natural flow conditions at the Twin Lake test site, Chalk River Laboratories of the Atomic Energy of Canada Ltd. in Chalk River, Ontario, Canada, using tritium and three herbicides (Chlortoluron, Terbuthylazine, and Pendimethalin) was interpreted using the dispersion equation with a combined reaction model. The reaction model couples an instantaneous equilibrium reaction governed by a linear adsorption isotherm with a reversible or irreversible kinetic reaction of the first order, and decay. An improved interpretation method consists of a simultaneous fitting of theoretical concentration and mass-recovery curves to the experimental data, which leads to a more reliable determining of reaction models and improves the accuracy of fitting. Tritium served as the reference tracer to determine the flow velocity, dispersivity, and the recovery of the herbicides. Chlortoluron was slightly delayed by equilibrium exchange with strongly reduced concentration due to an irreversible kinetic reaction and/or decay. Terbuthilazine was slightly delayed by equilibrium exchange, with strongly reduced concentration due to a reversible kinetic reaction with some influence of decay. A strong equilibrium reaction and a strong reversible kinetic reaction without degradation governed the transport of Pendimethalin, reducing considerably its concentration. The results obtained show that simulations based only on Kd and decay constant, especially if these parameters are found in the laboratory, may considerably differ from those performed with reaction parameters determined in properly performed field tests. The dominant reaction types, and the values of parameters found in the study, supply useful information on the transport of the investigated herbicides in sandy aquifers under natural flow conditions.     

Hydraulic parameters and solute velocities in triple-porosity karstic-fissured-porous carbonate aquifers: case studies in southern Poland

 Rock and flow parameters of three karstic-fissured-porous aquifers in the Krakow-Silesian Triassic formations were measured using various methods and compared. Though cavern and fissure porosities are shown to be very low (cavern porosity below 0.5% and fracture porosity below 0.2%), they contribute dominantly to the hydraulic conductivity (from about 1.3×10^–6 to about 11×10^–6 m/s). Matrix porosity (2–11%) is shown to be the main water reservoir for solute transport and the main or significant contributor to the specific yield (<2%). Though the matrix porosity is shown to be much larger than the sum of the cavern and fissure porosities, its contribution to the total hydraulic conductivity is practically negligible (hydraulic conductivity of the matrix is from about 5×10^–11 m/s to about 2×10^–8 m/s). On the other hand, the matrix porosity (for neglected cavern and fissure porosities) when combined with tracer ages (or mean travel times) is shown to yield proper values of the hydraulic conductivity (K) by applying the following formula: K≅(matrix porosity×mean travel distance)/(mean hydraulic gradient×mean tracer age). Confirming earlier findings of the authors, this equation is shown to be of great practical importance because matrix porosity is easily measured in the laboratory on rock samples, whereas cavern and fracture porosities usually remain unmeasurable. Received: 21 February 1997 · Accepted: 13 May 1997     

Groundwater dating with 3H and SF6 in relation to mixing patterns,transport modelling and hydrochemistry

A comprehensive study of a sandy aquifer of deltaic origin in southern Poland included water chemistry, isotopes, dissolved trace gases and transport modelling. Tritium, sulphur hexafluoride (SF₆) and freons (F‐11, F‐12 and F‐113) showed the presence of modern waters in the recharge areas and shallow confined parts of the aquifer. The presence of older Holocene waters farther from the recharge areas was indicated by lack of ³H, SF₆ contents ≤0·02 fmol l⁻¹ and relatively low ¹⁴C values. The discharge from the system is by upward seepage in the valley of a major river. Pre‐Holocene waters of a cooler climate, identified on the basis of δ¹⁸O, δ²H, ¹⁴C, Ne and Ar data, were found in some distant wells. Concentrations of N₂, Ne and Ar determined by gas chromatography were used for calculating the noble gas temperatures, air excess needed for correction of SF₆, and nitrogen content released by denitrification process. The time series of ³H content available for some wells supplied quantitative information on age distributions and the total mean ages of flow through the unsaturated and saturated zones. The derived ³H age distributions turned out to be very wide, with mean values in the range of about 30 to 160 years. For each well with determined ³H age, the SF₆ data showed either a lower age range or the possibility of a lower age as expected due to shorter travel times of SF₆ through the unsaturated zone, which most probably also resulted in different types of age distributions of these tracers. Freons appeared to be of little use for individual age determinations. A quantitative estimation of two‐component mixing from SF₆ ³H relations is not possible unless the travel time of ³H through the unsaturated zone is comparable to that of SF₆. The ratio of integrals of the response function over the age range with tracer and the whole response function yields the ratio of water with tracer to total flow of water. That ratio is a tracer‐dependent function of time. Transport modelling of SF₆ tracer done with MT3D code yielded initially large discrepancies between calculated and measured tracer concentrations. Some discrepancies remained even after calibration of the transport model with SF₆. Simulation of tritium contents with a calibrated transport model yielded reasonable agreement with measured contents in some wells and indicated a need for further investigations, particularly in the eastern part of the aquifer. The existence of distinct hydrochemical zones is consistent with the tracer data; young waters with measurable ³H and SF₆ contents are aerobic and of HCO₃ Ca or HCO₃ SO₄ Ca types. Slightly elevated Na and Cl contents, as well as the highest concentrations of SO₄ and NO₃ within this zone are due to anthropogenic influences. Anaerobic conditions prevail in the far field, under the confining cover, where pre‐bomb era Holocene waters dominate. In that zone, dissolved oxygen, NO₃ and U contents are reduced, and Fe, Mn and NH₄ contents increase. In the third zone, early Holocene and glacial waters occur. They are of HCO₃ Ca Na or HCO₃ Na types, with TDS values higher than 1 g l⁻¹ and Na content higher than 200 mg l⁻¹, due to either small admixtures of ascending or diffusing older water or freshening of marine sediments, a process that is probably occurring till the present time. Copyright © 2005 John Wiley & Sons, Ltd.     

A geometric analysis of surface deformation: Implications for the tectonic evolution of Ganymede

A visual nonalignment of the furrows and the circularity of impact craters are used to study surface deformation on Ganymede. The furrow system is examined to test the hypothesis that lateral motion has taken place between areas of dark terrain. Results show that while lateral motion cannot be ruled out, it may not be required to explain the geometry of the system. Initial nonconcentricity of the furrows or an early period of penetrative deformation shortly after furrow formation could also account for the present configuration. Centers of curvature of the furrows in Galileo and Marius Regiones are numerically determined and it is shown that if lateral movement did occur, it is not possible to determine the amount of displacement. The axial ratios of impact craters in the Uruk Sulcus region which separates Galileo and Marius Regiones are determined and show that large scale shear deformation has not occured in that area since bright terrain was emplaced. Deformation of impact craters within Galileo Regio suggests that Ganymede's lithosphere has behaved rigidly throughout most of the satellite's evolution. The shapes and orientations of impact craters in dark terrain around wedges of bright terrain are used to place an upper limit on the amount of extension associated with bright terrain formation.     

Measurement of the radius of Mercury by radio occultation during the MESSENGER flybys

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft completed three flybys of Mercury in 2008–2009. During the first and third of those flybys, MESSENGER passed behind the planet from the perspective of Earth, occulting the radio-frequency (RF) transmissions. The occultation start and end times, recovered with 0.1 s accuracy or better by fitting edge-diffraction patterns to the RF power history, are used to estimate Mercury's radius at the tangent point of the RF path. To relate the measured radius to the planet shape, we evaluate local topography using images to identify the high-elevation feature that defines the RF path or using altimeter data to quantify surface roughness. Radius measurements are accurate to 150 m, and uncertainty in the average radius of the surrounding terrain, after adjustments are made from the local high at the tangent point of the RF path, is 350 m. The results are consistent with Mercury's equatorial shape as inferred from observations by the Mercury Laser Altimeter and ground-based radar. The three independent estimates of radius from occultation events collectively yield a mean radius for Mercury of 2439.2±0.5 km.     

The transition from complex crater to peak-ring basin on the Moon: New observations from the Lunar Orbiter Laser Altimeter (LOLA) instrument

Impact craters on planetary bodies transition with increasing size from simple, to complex, to peak-ring basins and finally to multi-ring basins. Important to understanding the relationship between complex craters with central peaks and multi-ring basins is the analysis of protobasins (exhibiting a rim crest and interior ring plus a central peak) and peak-ring basins (exhibiting a rim crest and an interior ring). New data have permitted improved portrayal and classification of these transitional features on the Moon. We used new 128 pixel/degree gridded topographic data from the Lunar Orbiter Laser Altimeter (LOLA) instrument onboard the Lunar Reconnaissance Orbiter, combined with image mosaics, to conduct a survey of craters >50 km in diameter on the Moon and to update the existing catalogs of lunar peak-ring basins and protobasins. Our updated catalog includes 17 peak-ring basins (rim-crest diameters range from 207 km to 582 km, geometric mean = 343 km) and 3 protobasins (137-170 km, geometric mean = 157 km). Several basins inferred to be multi-ring basins in prior studies (Apollo, Moscoviense, Grimaldi, Freundlich-Sharonov, Coulomb-Sarton, and Korolev) are now classified as peak-ring basins due to their similarities with lunar peak-ring basin morphologies and absence of definitive topographic ring structures greater than two in number. We also include in our catalog 23 craters exhibiting small ring-like clusters of peaks (50-205 km, geometric mean = 81 km); one (Humboldt) exhibits a rim-crest diameter and an interior morphology that may be uniquely transitional to the process of forming peak rings. A power-law fit to ring diameters (D_ring) and rim-crest diameters (D_r) of peak-ring basins on the Moon [D_ring = 0.14 ± 0.10(D_r)^1.21±0.13] reveals a trend that is very similar to a power-law fit to peak-ring basin diameters on Mercury [D_ring = 0.25 ± 0.14(D_rim)^1.13±0.10] [Baker, D.M.H. et al. [2011]. Planet. Space Sci., in press]. Plots of ring/rim-crest ratios versus rim-crest diameters for peak-ring basins and protobasins on the Moon also reveal a continuous, nonlinear trend that is similar to trends observed for Mercury and Venus and suggest that protobasins and peak-ring basins are parts of a continuum of basin morphologies. The surface density of peak-ring basins on the Moon (4.5 × 10⁻⁷ per km²) is a factor of two less than Mercury (9.9 × 10⁻⁷ per km²), which may be a function of their widely different mean impact velocities (19.4 km/s and 42.5 km/s, respectively) and differences in peak-ring basin onset diameters. New calculations of the onset diameter for peak-ring basins on the Moon and the terrestrial planets re-affirm previous analyses that the Moon has the largest onset diameter for peak-ring basins in the inner Solar System. Comparisons of the predictions of models for the formation of peak-ring basins with the characteristics of the new basin catalog for the Moon suggest that formation and modification of an interior melt cavity and nonlinear scaling of impact melt volume with crater diameter provide important controls on the development of peak rings. In particular, a power-law model of growth of an interior melt cavity with increasing crater diameter is consistent with power-law fits to the peak-ring basin data for the Moon and Mercury. We suggest that the relationship between the depth of melting and depth of the transient cavity offers a plausible control on the onset diameter and subsequent development of peak-ring basins and also multi-ring basins, which is consistent with both planetary gravitational acceleration and mean impact velocity being important in determining the onset of basin morphological forms on the terrestrial planets.     

Catastrophic and dangerous inflows to salt mines in Poland as related to the origin of water determined by isotope methods

 Tritium, ¹⁴C, δ¹³C, δ¹⁸O and δD measurements indicated as early as 1973 the existence of inflows of modern meteoric water to the Wapno salt mine in a Zechstein diapir. In spite of these early warnings, the continuation of improper exploitation led, in 1977, to sudden flooding of the mine followed by catastrophic land subsidence. The lesson learned from that catastrophe, as well as the results of isotope investigations performed in the Inowrocław salt mine, led to the decision to flood the mine artificially in order to avoid a similar land subsidence. The Kłodawa mine was not regarded to be in danger of flooding due to a thick clay cap. In fact, a large number of usually short-lasting water occurrences had the isotopic composition characteristic for evaporated ocean water. However, since 1956 an inflow has existed with δ¹⁸O and δD values close to that of pre-Quaternary saline waters and brines in the Mesozoic formations adjacent to the diapir. Two other inflows have recently occurred with the initial δ¹⁸O and δD values of modern waters. As a consequence, the mine is regarded to be in danger, and the exploitation of salt in the areas of inflows has been stopped. The Wieliczka mine, southern Poland, exploits Miocene salts overthrusted together with the Carpathian flysch from the south. The most dangerous and catastrophic inflows were caused by human errors. Isotope data show the water to be of glacial or Holocene age stored in Tertiary, slightly cemented rocks of low permeability, which neighbor the mine from the north. Owing to specific geology, the mine has survived for a long time, in spite of relatively large and long-lasting inflows. However, its existence is in permanent danger. Received: 7 March 1997 · Accepted: 17 November 1998     

Dawn Mission to Vesta and Ceres

The initial exploration of any planetary object requires a careful mission design guided by our knowledge of that object as gained by terrestrial observers. This process is very evident in the development of the Dawn mission to the minor planets 1 Ceres and 4 Vesta. This mission was designed to verify the basaltic nature of Vesta inferred both from its reflectance spectrum and from the composition of the howardite, eucrite and diogenite meteorites believed to have originated on Vesta. Hubble Space Telescope observations have determined Vesta’s size and shape, which, together with masses inferred from gravitational perturbations, have provided estimates of its density. These investigations have enabled the Dawn team to choose the appropriate instrumentation and to design its orbital operations at Vesta. Until recently Ceres has remained more of an enigma. Adaptive-optics and HST observations now have provided data from which we can begin to confidently plan the mission. These observations reveal a rotationally symmetric body with little surface relief, an ultraviolet bright point that can be used as a control point for determining the pole and anchoring a geographic coordinate system. They also reveal albedo and color variations that provide tantalizing hints of surface processes.