Pb and other ore metals in modern seafloor tectonic environments: Evidence from melt inclusions

Many modern seafloor tectonic environments are host to hydrothermal systems and associated polymetallic sulfide deposits. Metal transport and precipitation are controlled by magmatic processes such as pre-eruptive degassing and the hydrothermal cycle. The original availability of Pb and other ore metals in a given setting is dependent on concentrations in the original magmatic source or additional enrichment processes. We have examined the Pb budget of melt inclusions from nine modern seafloor settings representing back-arcs, mid-ocean ridges and seamounts. Melt inclusions provide information on the characteristics of parental magmas, including insights into metal budgets. Trace element data in melt inclusions hosted in plagioclase, olivine and pyroxene were obtained by laser-ablation inductively-coupled mass-spectrometry.Results from back-arcs emphasize the impact of slab-subduction and dehydration processes on the chemical characteristics of generated magmas. Volatile- and fluid-mobile element-rich melt inclusions at Manus basin and Okinawa trough reflect a robust contribution of elements from the subducting slab as evidenced by relatively low Ce/Pb ratios. At Bransfield strait, on the other hand, melt inclusions are volatile poor, and fluid-mobile element ratios are similar to mid-ocean ridge values indicating little or no contribution from the slab. High Cu concentrations at Manus basin and Okinawa trough can be explained by fluxing of ferric iron from the subducting slab benefiting the production of sulfate over sulfide.Metal budgets for seamounts located on and nearby the axis of mid-ocean ridge segments appear to be independent of any input of mantle plume material. Results from the southern Explorer ridge (strong lower mantle influence, transitional- and enriched-MORBs), Pito and Axial seamounts (moderate lower mantle influence, transitional-MORBs) and a Foundation near-ridge seamount (little to no mantle influence, normal-MORB) show that, despite similar tectonic environments and varying contributions of mantle plume material, Cu, Zn and Pb values do not vary significantly between the enriched and non-enriched magma components of a given setting.     

An investigation of upper mantle heterogeneity beneath the Archaean and Proterozoic crust of western Canada from Lithoprobe controlled-source seismic experiments

Observations of upper mantle reflectivity at numerous locations around the world have been linked to the presence of a heterogeneous distribution of rock types within a broad layer of the upper mantle. This phenomenon is observed in wide-angle reflection data from Lithoprobe's Alberta Basement Transect [the SAREX and Deep Probe experiments of 1995] and Trans-Hudson Orogen Transect [the THoRE experiment of 1993]. SAREX and Deep Probe image the Archaean lithosphere of the Hearne and Wyoming Provinces, whereas THoRE images the Archaean and Proterozoic lithosphere of the Trans-Hudson Orogen and neighbouring areas.Finite-difference synthetic seismograms are used to constrain the position and physical properties of the reflective layer. SAREX/Deep Probe modelling uses a 2-D visco-elastic finite-difference routine; THoRE modelling uses a pseudospectral algorithm. In both cases, the upper mantle is parameterized in terms of two media. One medium is the background matrix; the other is statistically distributed within the first as a series of elliptical bodies. Such a scheme is suitable for modelling: (1) variations in lithology (e.g., a peridotite matrix with eclogite lenses) or (2) variations in rheology (e.g., lenses of increased strain within a less strained background).The synthetic seismograms show that the properties of heterogeneities in the upper mantle do not change significantly between the two Lithoprobe transects. Beneath the Trans-Hudson Orogen in Saskatchewan, the layer is best modelled to lie at depths between 80 and 150 km. Based on observations from perpendicular profiles, anisotropy of the heterogeneities is inferred. Beneath the Precambrian domains of Alberta, 400 km to the west, upper mantle heterogeneities are modelled to occur between depths of 90 and 140 km. In both cases the heterogeneous bodies within the model have cross-sectional lengths of tens of kilometers, vertical thicknesses less than 1 km, and velocity contrasts from the background of − 0.3 to − 0.4 km/s. Based on consistency with complementary data and other results, the heterogeneous layer is inferred to be part of the continental lithosphere and may have formed through lateral flow or deformation within the upper mantle.     

Interpretation of subhorizontal crustal reflections by metamorphic and rheologic effects in the eastern part of the Pannonian Basin

The geologic origin of subhorizontal reflections, often observed in crustal seismic sections, was investigated by establishing metamorphic facies and strength of rocks in depth, and correlating these properties to seismic reflection sections from eastern Hungary. Estimation of the depths of metamorphic mineral stability zones utilized the principles developed by Fyfe et al. and known geothermal data of the area. The strength versus depth profile was derived by relating local seismic P -wave interval velocities to Meissner et al. 's activation energy. The results show that the series of subhorizontal reflections, observed in the Pannonian Basin, are a consequence of combined metamorphic and rheologic changes in depths. The synthesis of the integrated data set suggests that the retrograde alteration of the pre-Tertiary basement above the percolation threshold was made possible by the softening effect of shear zones and their water-conducting capacity. The subhorizontal reflections of highest energy, of the consolidated crust below the percolation threshold, originate in the depths of greenschist, amphibolite and granulite metamorphic mineral facies, which were formed in geothermal and pressure conditions similar to those existing today. These results imply the overprint of earlier (Variscan) metamorphic sequences of the crust by more recent retrograde metamorphic processes.     

Low-frequency 3-D seismic survey of upper crustal magmatic intrusions in the northeastern Pannonian basin of Hungary

A specially designed 700-km² grid survey, deploying 1000 regularly distributed low-frequency seismic recording systems, successfully investigated one of the most complex geologic environments of the Pannonian basin. The wide-angle signals penetrated through over 1000 m of multi-phase igneous lithology and recognized, for the first time, the underlying enigmatic Permian to Early Triassic basement rocks. Tomographic inversion of the first arrival grid data resulted in determination of an accurate three-dimensional (3-D) velocity field, to a depth of 4 km. The anomalous changes of the spatial velocity data outline the regional extent of the Late Miocene magmatic intrusions, which are covered by over 2000 m of Mid-Miocene to Pleistocene clastics. Complex relationship was found between the surface potential data and the intrusive bodies. This multi-faceted geophysical data analysis established a functional technique for mapping a subsurface with intricate acoustic and structural complexity.     

New seismic images of the crust in the central Trans-Hudson Orogen of Saskatchewan

A reprocessing program to enhance the correlation between the surface geology and the seismic data has been completed for seismic line 9 (eastern 100 km) and line 10 in the central region of the Trans-Hudson Orogen of Saskatchewan, Canada. The new seismic images through lateral continuity of reflectivity provide sufficient detail to resolve the discrepancy between the low-dipping, layer-parallel and dextral-reverse nature of the Sturgeon-Weir shear zone (line 9) observed in the field and its steeply dipping (apparent) normal displacement character interpreted on the basis of the initial processing. Furthermore, the new interpretation provides a strong confirmation of the role of Pelican Thrust as a major detachment zone — the main `sole thrust' — along which juvenile allochthons have been carried across the Archaean microcontinental block. The images are also refined enough to suggest: (a) a boundary within the Pelican Thrust between its internal and external suites; (b) a possible boundary separating a lower (older?) Archaean basement from its upper (younger?) counterpart; and (c) sub-Moho events (M2) which reveal possible involvement of the upper mantle in the collisional tectonic process in addition to the well defined Moho (M1) which probably represents the youngest of the post-collisional detachments.     

Reflection experiment on a floating ice platform

Summary. Preliminary analysis of a multifold seismic survey on a floating ice platform, northwest of Axel Heiberg Island, along the Canadian portion of the continental margin of the Arctic Ocean revealed a structurally complex basement at a depth beyond 4000 m. The basement is covered with high velocity (5000 m/sec) rock types. The results conform to the anticipated geologic model for regions of passive margins.     

Seismic Signature of the Haughton Structure

Abstract— The western flank of the Haughton impact structure was imaged with a reflection profile generating 9.8 km of subsurface information. Ten reflecting horizons were recognized and have been correlated via a sonic log with the Paleozoic limestone/dolomite rock sequences. The seismic section is dominated by a dense and complex compound fault system with variable attitudes. These steeply dipping faults penetrated the sedimentary rocks but showed no recognizable extension into the crystalline basement. According to the seismically recognized fracture zones of the western margin, the structure is significantly larger than previously estimated. Reconstruction of the crater on the basis of the seismic information and existing scaling relationships reveals a structure with an apparent diameter of 23.9 km, and an excavated cavity of 10.3 km width and 1.97 km depth. The estimated diameters of the transient crater and the central uplift are 12 km and 11 km respectively. The morphologically distinct ring zones do not have seismically recognizable subsurface signatures. The underlying crystalline basement rocks did not exhibit seismically mappable impact-related zones of disturbance. In the central interior region, coherent reflection signals are virtually absent. Valuable information for this area was provided by a 10.26 km long refraction profile that indicated nearly uniform velocities (～5000 m/s) to a considerable depth. Major lateral variations in the velocity field across the structure were not detected.     

Analysis of small-scale heterogeneity in clastic rocks by using computerized X-ray tomography (CT)

The aim of this study is to recognize the basic clastic rock types on the basis of Hounsfield Units (HUs) by using statistical methods (hypothesis tests, distribution fitting, and confidence intervals). How does this recognition depend on depositional history of samples tested? Does the numerical pattern of HUs obtained from small-scale analyzing of some particular sedimentary structures coincide to the textural expectations of those sedimentary structures? Are the HU values provided by the CT measurements capable of evidencing micro-cycles belonging to a particular depositional history?For testing the numerical recognition, we analyze macroscopically homogeneous argillaceous marl, siltstone and fine sandstone samples with similar depositional background, age, and degree of diagenesis. The preliminary research shows that the Hounsfield Units can identify different sedimentary rocks considerably well. There are significant differences among the confidence intervals belonging to the different rock types. However, there also have been some slight overlaps among them.For analyzing the effects of the depositional processes in case of a particular rock type, samples from channel sandstone, distributary mouth-bar, massive (structureless) sandstone from a delta-fed turbidity fan, and channel sandstone with traction carpet origin from a delta-fed turbidity fan (all coming from Pannonian basin filling series) are used. The results prove again the significant differences in the terms of both confidence intervals and distribution-types; however, some overlapping also occurs.