Thermal and energy factors of metal concentration in igneous plutons: an application to metallogenic analysis and exploration

The concentration of metals in intrusive systems is influenced by energy conditions and is associated with maxima of thermal and energy fields. Other factors controlling ore location inside plutons are the regimes of crystallization and of heat flow, and physical-chemical peculiarities of a melt. Ore formation in endocontacts and exocontacts of plutons occurs as a result of fluid filtration in the zones of thermal fracturing. Numerical modelling of thermal processes and the analysis of their influence on metal behaviour give clues that help to forecast promising sites. An example of how genetic models and general regularities can be applied to metallogenic analysis is given.     

Changes in the macrobenthic communities of the Gudauta Oyster Bank

Twenty-nine benthic invertebrate species were registered for the Gudauta Bank in the depth range of 8–32 m in 1990. The shallow-water biocenose was defined for the depths of less than 10 m, the biocenoses of Anadara inaequivalvis and A. inaequivalvis-Upogebia pusilla occupied the depths of 10–30 m; and the biocenosis of Pitar rudis was found for the depths of more than 30 m. The highest biodiversity and abundance of benthos was registered for the Anadara biocenoses, while the lowest, for the shallow-water ones. It was found that significant changes in the benthic communities took place in the forty years after the predator gastropod Rapana venosa was introduced into the Black Sea. The oysters became extinct on Gudauta Bank, and the species composition of the benthic community has been significantly depleted. Alien species of Anadara and Rapana became the most abundant by biomass, comprising more than 80% of the total biomass of the benthos. The population density of Rapana constituted 12 ind./m² and was the highest ever registered for the studied areas of the Black Sea. Insufficient nutrition preconditioned the small size of the mollusks.     

Batisite,Na2BaTi2(Si4O12)O2, from Inagli massif,Aldan, Russia: crystal-structure refinement and high-temperature X-ray diffraction study

Mineralogy and Petrology - The crystal structure of batisite, Na2BaTi2 (Si4O12)O2, from the Inagli massif (Aldan, Yakutia, Russia) was refined to R 1 = 0.032 for 1449 unique...     

Evolution of chemical composition of pyrochlore group minerals from phoscorites and carbonatites of the Khibina alkaline massif

Phoscorites and carbonatites of the Khibina alkaline massif, Russia contain three minerals of the pyrochlore group. They are, in order of crystallization: uranpyrochlore and pyrochlore in the phoscorites, and pyrochlore and bariopyrochlore in late calcite carbonatites. Early calcite carbonatites also contain uranpyrochlore and pyrochlore, but they are xenocrysts derived from the phoscorites. Alteration of the pyrochlore group minerals led to increasing U, Ti and water contents and decreasing Na, Ca, Nb and F contents. Crystallization of zoned uranpyrochlore to pyrochlore crystals in the phoscorites is explained by the experiments of Ryabchikov and Hamilton (1993, 1994) on the interaction of carbonate-phosphate melts with mantle peridotites.     

Comparison of Synchrotron Radiation X-Ray Fluorescence with Conventional Techniques for the Analysis of Sedimentary Samples

A comparison is made of elemental analyses of sediment samples (lake bottom sediments and sediments from the petroliferous Bazhenovka Formation) by five competitive methods (synchrotron radiation X-ray fluorescence (SR-XRF), INAA, ICP-MS, AAS and traditional XRF). The object of this study was to identify the most suitable analytical techniques for applications in sedimentary geochemistry. Advantages and shortcomings of the five techniques were considered with respect to applications related to studies of palaeo-climate changes recorded in sedimentary cores from Lake Baikal and the geochemical stratigraphy of the Bazhenovka Formation, which is rich in organic material. We have concluded that SR-XRF was the best technique for producing extensive analytical data series, from the point of view of its speed, ease of application, cost, non-destructive nature and sensitivity, which allowed for the simultaneous determination of more than twenty elements of geochemical interest in small samples of sediments. An additional benefit of the method was demonstrated when used for the independent certification of geological reference materials. International reference samples BIL-1 and SDO-1 were certified by means of this method without use of reference materials. Analyses were based on the physics of the theory of energy transport.     

Effect of the seasonal thermocline on the spatial/temporal structure of internal waves

Mathematical modelling techniques are applied to study the influence of the seasonal pycnocline on the propagation and attenuation of internal waves in an ocean with a main pycnocline. This paper discusses the peculiarities of dispersive dependences, group velocities, and of the velocity field's amplitudinal characteristics induced by the seasonal pycnocline. Short-period motions have been observed to concentrate within the latter, and the conditions causing a modification of the environment's waveguide properties for non-stationary wave packets, associated with the existence of two pycnoclines, have been identified.Translated by Vladimir A. Puchkin.     

High-Temperature Behavior of the CuMo3O10⋅H2O Compound

Geology of Ore Deposits - CuMo3O10⋅H2O crystals have been obtained by hydrothermal synthesis as a result of reaction between (NH4)6Mo2O24⋅4H2O and Cu(CH3COO)2 at 220°C for 7 days....     

Formation of geochemical fields of concentration in the thermal gradient fields of intrusive bodies

The concentration of metals and ores in thermal fields of intrusive bodies can be analyzed by numerical simulation (modelling) of the heat-mass transfer process. A knowledge of the dynamics and the movement of the temperature and crystallization fronts, as well as an understanding of the characteristics of the thermal gradients, heat flows, energy, and thermal stresses which result in the formation of fracture zones, are necessary for an estimation of the spacial and temporal aspects of the mass balance calculations and the ore concentration processes. The application of the method is illustrated by observing the changes in the rare earth element concentration in a vein-type apatite orebody in limestone which has been intruded by a post-ore dike. The method has potential value in exploring for hidden mineralization.     

Corundum-bearing metasomatic rocks in the Central Pamirs

The Muzkol metamorphic complex in the Central Pamirs contains widespread occurrences of corundum mineralization, sometimes with gem-quality corundum. These occurrences are spatially related to zones of metasomatic alterations in calcite and dolomite marbles and crystalline schists. The calcite marbles contain corundum together with muscovite, scapolite, and biotite; the dolomite marbles contain corundum in association with biotite; and the schists bear this mineral coexisting with biotite and chlorite. All these rocks additionally contain tourmaline, apatite, rutile, and pyrite. The biotite is typically highly aluminous (up to 1.9 f.u. Al), and the scapolite is rich in the marialite end member (60–75 mol %). The crystallization parameters of corundum were estimated using mineral assemblages at T = 600–650°C, P = 4–6 kbar, X _{CO 2} = 0.2–0.5 at elevated alkalinity of the fluid. The Sr concentration in the calcite and dolomite marbles is low (345–460 and 62–110 ppm, respectively), as is typical of recrystallized sedimentary carbonates. The variations in the ⁸⁷Sr/⁸⁶Sr ratio in the calcite and dolomite marbles (0.70852–0.70999 and 0.70902–0.71021, respectively) were controlled by the introduction of radiogenic ⁸⁷Sr during the metasomatic transformations of the rocks. The isotopic-geochemical characteristics obtained for the rocks and the results of numerical simulations of the fluid-rock interactions indicate that the corundum-bearing metasomatic rocks developed after originally sedimentary Phanerozoic carbonate rocks, with the desilication of the terrigenous material contained in them. This process was a manifestation of regional alkaline metasomatism during the closing stages of Alpine metamorphism. In the course of transformations in the carbonate reservoir, the juvenile fluid flow became undersaturated with respect to silica, which was a necessary prerequisite for the formation of corundum.