Intercomparison of Stratospheric Chemistry Models under Polar Vortex Conditions

Several stratospheric chemistry modules from box, 2-D or 3-D models, have been intercompared. The intercomparison was focused on the ozone loss and associated reactive species under the conditions found in the cold, wintertime Arctic and Antarctic vortices. Comparisons of both gas phase and heterogeneous chemistry modules show excellent agreement between the models under constrained conditions for photolysis and the microphysics of polar stratospheric clouds. While the mean integral ozone loss ranges from 4–80% for different 30–50 days long air parcel trajectories, the mean scatter of model results around these values is only about ±1.5%. In a case study, where the models employed their standard photolysis and microphysical schemes, the variation around the mean percentage ozone loss increases to about ±7%. This increased scatter of model results is mainly due to the different treatment of the PSC microphysics and heterogeneous chemistry in the models, whereby the most unrealistic assumptions about PSC processes consequently lead to the least representative ozone chemistry. Furthermore, for this case study the model results for the ozone mixing ratios at different altitudes were compared with a measured ozone profile to investigate the extent to which models reproduce the stratospheric ozone losses. It was found that mainly in the height range of strong ozone depletion all models underestimate the ozone loss by about a factor of two. This finding corroborates earlier studies and implies a general deficiency in our understanding of the stratospheric ozone loss chemistry rather than a specific problem related to a particular model simulation.     

湘西北寒武系沉积型镍钼矿成矿物质来源

湘西北寒武系含矿丰富,在寒武系下统牛蹄塘组黑色岩系中赋存有磷矿、石煤、钒矿、铀矿,并有有色金属钼、镍矿及铂族元素矿物聚集。通过分析总结前人成果资料,探究镍钼矿成矿地质环境条件是在低温环境、有微生物参与及强还原环境中同生沉积,对寒武系沉积型镍钼矿成矿物质来源提出了明确的看法,即成矿物质来源于海底喷流-热水。     

配位滴定法同时测定金属离子浓度的研究

将多元校正分析法应用于配位滴定中，以ＥＤＴＡ为滴定剂，玻璃电极为指示电极，饱和甘汞电极为参比电极。依据电位滴定原理，对混合三组分：Ｃｕ￣（２＋）、Ｃｄ￣（２＋）、Ｚｎ￣（２＋）、及Ｃｕ￣（２＋）、ＣＯ￣（２＋）、Ｎｉ￣（２＋）进行测定，各金属离子之间的△ｌｏｇＫ在０．０４～２．３４之间，计算误差一般小于土１０％。     

Features of the Early Palaeozoic Mantle beneath Langao County and Its Formation Mechanism

Phlogopite-amphibole pyroxenite xenoliths contained in an Early Palaeozoic alkali subvolcanic lam-prophyre complex in Langao County, Shaanxi Province, are metasomatized mantle xenoliths, composed mainly of clinopyroxene, amphibole, phlogopite, apatite, pervoskite, ilmenite and sphene with well-developed subsolidus metamorphism-deformation textures, such as "triple points" and "cataclastic boundaries" . Minerological studies indicate that clinopyroxene is rich in SiO2 and MgO and poor in TiO2 and Al2O3, which is notably different from magmatogenic deep-seated megacrysts and phenocrysts formed in the range of mantle pressure. Amphibole and phlogopite have the compositional feature of mantle-derived amphibole and phlogopite. Sm-Nd isotope studies suggest that the metasomatized mantle beneath Langao County is the product of metasomatism of primitive mantle by melt (fluid) derived from the mantle plume, and the mantle metasomatism occurred 650 Ma ago. The process of mantle metasomatism changed from mantle me     

A Method to Determine the Solar Synodic Rotation Rate and the Height of Tracers

The dependence of the measured apparent synodic solar rotation rate on the height of the chosen tracer is studied. A significant error occurs if the rotation rate is determined by tracing the apparent position of an object above the photospheric level projected on the solar disc. The centre-to-limb variation of this error can be used to determine simultaneously the height of the object and the true synodic rotation rate. The apparent (projected) heliographic coordinates are presented as a function of the height of the traced object and the coordinates of its footpoint. The relations obtained provide an explicit expression for the apparent rotation rate as a function of the observed heliographic coordinates of the tracer, enabling an analytic least-squares fit expression to determine simultaneously the real synodic rotation rate and the height of the tracer.     

大型帐篷构造对贵州天星桥喀斯特石林形成演化的控制作用

贵州黄果树天星桥景区下三叠统安顺组白云岩广泛出露,分布有连片水上石林,其发育在下三叠世台地相与深海盆地过渡的台地边缘相带上,这里海水进退频繁,古海岸带暴露面上大型帐蓬构造十分发育.碳酸盐岩古暴露带这种岩性特征,一则导致岩石充满裂隙及孔洞,极有利于大气降水入渗及地下水的赋存和运移;另则导致岩体软弱结构面密布,岩石的力学强...     

Integrated Rhaetian foraminiferal and conodont biostratigraphy from the Slovenian Basin, eastern Southern Alps

Conodonts and re-deposited shallow-water benthic foraminifera co-occur in the Upper Norian-Rhaetian Slatnik Formation of the Slovenian Basin (Southern Alps). The Mt. Kobla and Mt. Slatnik sections were investigated in order to give the first direct correlation between these two groups. The Norian-Rhaetian boundary (NRB) is placed at the First Appearance Datum of the conodont Misikella posthernsteini and is approached with the First Occurrence of the foraminifer Involutina turgida. An association of Trocholina turris with duostominids is a good marker for the Rhaetian. Careful revision of literature combined with our data culminated in reambulation of stratigraphical ranges for several foraminiferal species. The foraminiferal Triassic-Jurassic boundary (TJB) can be defined with the Last Occurrence of Galeanella tollmanni, ??Sigmoilina?? schaeferae or duostominids. The absence of the uppermost Rhaetian Misikella ultima conodont zone and the close coincidence of foraminiferal and conodont TJB could point to the presence of hiati in the upper part of the Slatnik Formation. Consequently, the exact pattern of disappearance of Late Triassic foraminifera at the boundary could not be observed. It is clear, however, that the foraminiferal assemblage was decimated for reef-dwelling foraminifera, duostominids and most of the platform-dwelling foraminifera. Biotic changes at the TJB are best explained as a result of a biocalcification crisis.     

平顶山矿区原生结构煤和构造煤孔渗实验对比

为了研究构造煤孔渗变化特性, 利用平顶山矿区原生结构煤和构造煤, 进行了不同围压、温度、湿度和煤体结构类型等条件下孔隙度及渗透率的实验测定, 对煤层孔渗特性在不同条件下的变化趋势进行了分析.结果表明: 围压、温度、湿度和煤体结构类型4种因素对煤的孔隙度和渗透率均有较大影响, 当温度和围压同时作用时, 围压的作用效果大于温度的作用效果.并用Origin软件对部分实验数据进行了数据拟合, 得出原生结构煤和构造煤的渗透率-孔隙度函数关系.