不饱和古罗糖醛酸三糖和甘露糖醛酸三糖的结构表征

以双功能褐藻胶裂解酶 (Pseudoalteromonas sp.strain No. 2 72 )分别降解均聚古罗糖醛酸(PG)和均聚甘露糖醛酸 (PM) ,经 Bio- Gel- P6和 POROS- HQ2 0分离得到 2种三糖纯品 ,经 ESI- MS,1 H- NMR,1 3 C- NMR,1 H- 1 H COSY,1 H- 1 3 C HMQC确定其结构为 Δ4,5-古罗糖醛酸 - α(1→ 4 ) - L-古罗糖醛酸 -α(1→ 4 ) - L -古罗糖醛酸 (简写为Δ GG)和Δ4,5-甘露糖醛酸 -β (1→ 4 ) - D-甘露糖醛酸 -β (1→ 4 ) - D-甘露糖醛酸 (ΔMM) ,为进一步从事构效关系研究提供结构信息。     

Influence of Current Width Variation on the Annual Mean Transport of the East Sakhalin Current: A Simple Model

Recent observations suggest that the annual mean southward transport of the East Sakhalin Current (ESC) is significantly larger than the annual mean Sverdrup transport. Motivated by this observational result, transport of a western boundary current has been investigated using a simple numerical model with a western slope. This transport is defined as the instantaneous barotropic transport integrated from the western boundary to the offshore point where the barotropic velocity vanishes. The model, forced by seasonally varying wind stress, exhibits an annual mean of the western boundary current transport that is larger than that of the Sverdrup transport, as observed. The southward transport from October to March in the model nearly equals the instantaneous Sverdrup transport, while the southward transport from April to September decreases slowly. Although the Sverdrup transport in July vanishes, the southward transport in summer nearly maintains the annual mean Sverdrup transport, because the barotropic Rossby wave cannot intrude on the western slope. This summer transport causes the larger annual mean. Although there are some uncertainties in the estimation of the Sverdrup transport in the Sea of Okhotsk, the seasonal variation of the southward transport in the model is qualitatively similar to the observations.     

State Estimation of the North Pacific Ocean by a Four-Dimensional Variational Data Assimilation Experiment

A four-dimensional variational data assimilation system has been applied to an experiment to describe the dynamic state of the North Pacific Ocean. A synthesis of available observational records and a sophisticated ocean general circulation model produces a dynamically consistent dataset, which, in contrast to the nudging approach, provides realistic features of the seasonally-varying ocean circulation with no artificial sources/sinks for temperature and salinity fields. This new dataset enables us to estimate heat and water mass transports in addition to the qualification of water mass formation and movement processes. A sensitivity experiment on our assimilation system reveals that the origin of the North Pacific Intermediate Water can be traced back to the Sea of Okhotsk and the Bering Sea in the subarctic region and to the subtropical Kuroshio region further south. These results demonstrate that our data assimilation system is a very powerful tool for the identification and characterization of ocean variabilities and for our understanding of the dynamic state of ocean circulation. This revised version was published online in July 2006 with corrections to the Cover Date.     

纪伊半岛地区植被净初级生产力的遥感应用研究

在高光谱数据模式分解方法(PDM)的基础上,建立了一种新的植被指数(VIPD)。根据地面植被光合成实验,建立了有效光合成曲线植被净初级生产力(NPP)遥感估算模型,利用2001年各月份的MODIS影像数据,估算得到纪伊半岛地区的各类NPP。研究发现,该地区的温带常绿林NPP年均值与2001年IPCC调查报告和地面实测得到的估算值在误差范围内一致。实验证明,该光合成曲线NPP估算模型能够有效地利用高光谱数据,且能较好地应用于温带植被研究。     

Biogenic Silica Record in Lake Biwa of Central Japan over the Past 145,000 Years

The record of the biogenic silica flux (BSF, g cm⁻²(10³yr)⁻¹) in Lake Biwa reflects changes in diatom productivity in the lake and provides information regarding changes in paleoclimatic conditions. The BSF record of Lake Biwa demonstrates five periods over the past ca. 145,000 yr when the BSF values were significantly greater than 7.5 g cm⁻²(10³yr)⁻¹, and five intervals when they were lower. The data imply that paleoclimatic conditions were warmer and wetter from ca. 123,000 to 115,000, 103,000 to 95,000, 88,000 to 72,000, 57,000 to 32,000 yr B.P., and around ca. 6000 yr B.P. when the BSF values were greater, and relatively dry and cold from ca. 141,000 to 123,000 yr B.P. and during intervals between two of the five warm and wet episodes when the BSF values were lower. Time series of the BSF record can be correlated with the record of biogenic silica content in Lake Baikal and the marine oxygen isotope stages 1 through 6. Furthermore, the BSF values varied with much higher amplitude during the last interglaciation than during the last glaciation, probably implying that the diatom productivity in Lake Biwa was likewise more variable and had a larger range under interglacial conditions than under glacial conditions.     

The first absolute gravity measurements in Indonesia

For the purposes of the calibration of the superconducting gravimeter (SG) in Bandung and the establishment of the absolute gravity (AG) points, we carried out AG measurements for the first time in Indonesia in November 2002. The measurements in Bandung were conducted between November 15th and 20th by means of a FG5 (#210), and 14,520 effective drops were obtained. The gravity value newly determined at the AG point in Bandung is 977976701.2 μgal (1 μgal = 10⁻⁸ ms⁻²) and the scale factor for the SG is −52.22 μgal/V. We also established another AG point in Yogyakarta near Merapi volcano and carried out AG measurements in Yogyakarta between November 22nd and 26th. The gravity value determined for this station is 978203093.5 μgal.     

Multiple Parameter Regularization: Numerical Solutions and Applications to the Determination of Geopotential from Precise Satellite Orbits

Kaula’s rule of thumb has been used in producing geopotential models from space geodetic measurements, including the most recent models from satellite gravity missions CHAMP. Although Xu and Rummel (Manuscr Geod 20 8–20, 1994b) suggested an alternative regularization method by introducing a number of regularization parameters, no numerical tests have ever been conducted. We have compared four methods of regularization for the determination of geopotential from precise orbits of COSMIC satellites through simulations, which include Kaula’s rule of thumb, one parameter regularization and its iterative version, and multiple parameter regularization. The simulation results show that the four methods can indeed produce good gravitational models from the precise orbits of centimetre level. The three regularization methods perform much better than Kaula’s rule of thumb by a factor of 6.4 on average beyond spherical harmonic degree 5 and by a factor of 10.2 for the spherical harmonic degrees from 8 to 14 in terms of degree variations of root mean squared errors. The maximum componentwise improvement in the root mean squared error can be up to a factor of 60. The simplest version of regularization by multiplying a positive scalar with a unit matrix is sufficient to better determine the geopotential model. Although multiple parameter regularization is theoretically attractive and can indeed eliminate unnecessary regularization for some of the harmonic coefficients, we found that it only improved its one parameter version marginally in this COSMIC example in terms of the mean squared error.     

Determination of Bromine and Iodine in Twenty-three Geochemical Reference Materials by ICP-MS

Trace amounts (from nanogram to microgram levels) of bromine and iodine were determined by inductively coupled plasma-mass spectrometry (ICP-MS) in twenty-three geochemical reference materials issued by the GSJ, USGS, IAEA etc. The pyrohydrolysis technique was used to separate bromine and iodine from samples analysed in the form of powder. The accuracy and precision of the experimental values were assessed by the comparative analysis of well established reference materials such as USGS AGV-1, BCR-1 and IGGE GBW07312. The measured values agreed well with reported values within a 10% error range. We also report reliable new data for these elements in these geochemical reference materials.     

Fukuititan nipponensis, A New Titanosauriform Sauropod from the Early Cretaceous Tetori Group of Fukui Prefecture,Japan

<正>A titanosauriform dinosaur:Fukuititan nipponensis gen.et sp.nov.is erected based on the incomplete skeleton.It is characterized by elongated asymmetric tooth crown with a weak or absent labial groove and without lingual concavity;stalk-like epipophysis of cervical vertebra;the transverse width of the proximal end of the humerus approximately 32%of the humerus length;metacarpal longer,approximately 48%of the radius and the distal end of the ischia slightly expanded.It represents the first relatively complete titanosauriform skeleton found from Japan.The discovery of Fukuititan indicates that the diversity and geographical distribution of Titanosauriformes are much higher than the previous thought.     

Current-to-Current Converter for Scientific Underwater Cable Networks

A new current-to-current converter, which is a key device to branch a constant direct current (DC) into two constant DCs, was proposed [K. Asakawa , Proc. OCEANS, pp. 1868-1873, 2003]. It has been verified, through computer simulations and experiments using prototypes, to have good conversion efficiency and stable operation. Because the basic circuit is simple, high reliability is expected. The current-to-current converter is a key device to realize a constant current (CC) power-feeding system for scientific underwater cable networks having mesh topology, which is necessary to enhance robustness against cable breakdowns and to deploy sensors in 2-D and efficiently over a vast research area.