Phase Relations and Melting of Anhydrous K-bearing Eclogite from 1200 to 1600{degrees}C and 3 to 5 GPa

To investigate eclogite melting under mantle conditions, wehave performed a series of piston-cylinder experiments usinga homogeneous synthetic starting material (GA2) that is representativeof altered mid-ocean ridge basalt. Experiments were conductedat pressures of 3·0, 4·0 and 5·0 GPa andover a temperature range of 1200–1600°C. The subsolidusmineralogy of GA2 consists of garnet and clinopyroxene withminor quartz–coesite, rutile and feldspar. Solidus temperaturesare located at 1230°C at 3·0 GPa and 1300°C at5·0 GPa, giving a steep solidus slope of 30–40°C/GPa.Melting intervals are in excess of 200°C and increase withpressure up to 5·0 GPa. At 3·0 GPa feldspar, rutileand quartz are residual phases up to 40°C above the solidus,whereas at higher pressures feldspar and rutile are rapidlymelted out above the solidus. Garnet and clinopyroxene are theonly residual phases once melt fractions exceed 20% and garnetis the sole liquidus phase over the investigated pressure range.With increasing melt fraction garnet and clinopyroxene becomeprogressively more Mg-rich, whereas coexisting melts vary fromK-rich dacites at low degrees of melting to basaltic andesitesat high melt fractions. Increasing pressure tends to increasethe jadeite and Ca-eskolaite components in clinopyroxene andenhance the modal proportion of garnet at low melt fractions,which effects a marked reduction in the Al₂O₃ and Na₂O contentof the melt with pressure. In contrast, the TiO₂ and K₂O contentsof the low-degree melts increase with increasing pressure; thusNa₂O and K₂O behave in a contrasted manner as a function ofpressure. Altered oceanic basalt is an important component ofcrust returned to the mantle via plate subduction, so GA2 maybe representative of one of many different mafic lithologiespresent in the upper mantle. During upwelling of heterogeneousmantle domains, these mafic rock-types may undergo extensivemelting at great depths, because of their low solidus temperaturescompared with mantle peridotite. Melt batches may be highlyvariable in composition depending on the composition and degreeof melting of the source, the depth of melting, and the degreeof magma mixing. Some of the eclogite-derived melts may alsoreact with and refertilize surrounding peridotite, which itselfmay partially melt with further upwelling. Such complex magma-genesisconditions may partly explain the wide spectrum of primitivemagma compositions found within oceanic basalt suites. KEY WORDS: eclogite; experimental petrology; mafic magmatism; mantle melting; oceanic basalts     

Chlorinated hydrocarbons and hatching success in Baltic herring spring spawners

Eggs from 69 females of spring spawning herring from the German Baltic coast (Travemünde, April 1979) were incubated in clean sea water (20‰ S, temperature 8°C) under standard conditions. Sixty-one trials could be used for the evaluation of hatching success. Viable hatch was taken as a measure to evaluate the effects of chlorinated hydrocarbons accumulated in gonads, liver and muscle of parental fish.PCB levels in running ripe females ranged on a wet weight basis between 19 and 241 ng g^?1 (gonad), 20 and 377 ng g^?1 (liver) and 11 and 1820 ng g^?1 (muscle). Concentrations of other chlorinated hydrocarbons (DDD, DDE, γ-HCH, etc.) were in the same range as reported by other authors for Baltic herring (Huschenbeth, 1973, 1977). Viable hatch was significantly affected at ovary DDE concentrations higher than 18 ng g^?1 (wet wt) and PCB concentrations of more than 120 ng g^?1 (wet wt).Results are compared with data obtained during earlier investigations with flounder eggs.     

Climate proxies from Sr/Ca of coccolith calcite: calibrations from continuous culture of Emiliania huxleyi

Continuous culture of the coccolithophorid Emiliania huxleyi reveals that coccolith Sr/Ca ratios depend on temperature and growth rate. At a constant temperature of 18°C, coccolith Sr/Ca ratios increased nearly 15% as growth rate increased from 0.1 to 1.5 divisions per day and calcification rate increased from 1.5 to 50 pg calcite per cell per day. When temperature increased from 7 to 26°C, Sr/Ca ratios increased by more than 25% (i.e., 1%/1°C), although the range in growth and calcification rates was the same as for experiments at constant temperature. The temperature dependence of Sr/Ca ratios in coccoliths is consistent with that observed in planktonic foraminifera and abiogenic calcites, suggesting that it is controlled by thermodynamic processes. However, the positive correlation of coccolith Sr/Ca with temperature contrasts with field studies in the equatorial Pacific, where Sr/Ca ratios are highest at the locus of maximum upwelling and productivity despite depressed temperatures. This paradox may reflect different calcification rate effects between E. huxleyi and the other species dominating assemblages in the equatorial Pacific sediments, which may be resolved by new techniques for separation of monospecific coccolith samples from sediments. Models of crystal growth indicate that kinetic effects on Sr partitioning in calcite due to surface enrichment could explain the Sr/Ca variations observed in constant temperature experiments but not the larger amplitude calcification rate effects observed in equatorial Pacific sediments. Despite the dual influence of temperature and growth rate on coccolith Sr/Ca, coccolith Sr/Ca correlates with “b,” the slope of the dependence of carbon isotope fractionation in biomarkers (ε_p) on CO₂(aq) at a range of growth rates and temperatures. Consequently, using coccolith Sr/Ca in combination with alkenone ε_p may improve paleo-CO₂ determinations.     

Methodology of Environmental Standardization for Natural Waters

Doklady Earth Sciences - This paper discusses sources of significant errors that occur in the course of determination of the primary environmental standard for natural waters: the maximum...     

Nonlinear Effects in the Formation of Water Quality

Doklady Earth Sciences - The indicators of the composition and quality of natural water are random variables. Since the “linear” approach to their assessment and forecast provides no...     

A 1600-year history of the Labrador Current off Nova Scotia

A multicore from Emerald Basin, on the continental margin off Nova Scotia, has a modern ¹⁴C age at the top, and other ¹⁴C dates indicate a linear sedimentation rate of ~30 cm/ka to 1600 calendar years BP. This rate is great enough to record century-to-millennial scale changes in the surface and deep (~250 m) waters in the basin that are influenced by the Labrador Current. We applied five proxies for seawater temperature changes to the sediments of Emerald Basin, including the percent abundance and the oxygen isotope ratio (d ¹⁸O) of the polar planktonic foraminifer N. pachyderma (s.), the unsaturation ratio of alkenones (U ^k' ₃₇) produced by prymnesiophyte phytoplankton, and the d ¹⁸O and Mg/Ca of benthic foraminifera. All five proxies indicate the ocean warmed suddenly sometime in the past 150 years or so. The exact timing of this event is uncertain because ¹⁴C dating is inaccurate in recent centuries, but this abrupt warming probably correlates with widespread evidence for warming in the Arctic in the nineteenth century. Because the Canadian Archipelago is one of the two main sources for the Labrador Current, warming and melting of ice caps in that region may have affected Labrador Current properties. Before this recent warming, sea surface temperature was continually lower by 1–2 °C, and bottom water was colder by about 6 °C in Emerald Basin. These results suggest that there was no Medieval Warm Period in the coastal waters off Nova Scotia. Because there is also no evidence of medieval warming in the Canadian archipelago, it seems likely that coastal waters from Baffin Bay to at least as far south as Nova Scotia were continually cold for ~1500 of the past 1600 years.     

Reconstruction of natural groundwater flow paths in the multiple aquifer system of the northern Negev (Israel), based on lithological and structural evidence

 The Judea Group, a limestone and dolomite karstic aquifer of late Albian–Turonian age, is one of the most important sources of water in Israel. In the western part of the country, the Judea Group aquifer is also known as the Yarkon–Taninim basin. In the northern Negev, the Judea Group is a recipient for fresh water flowing southward from the Hebron Mountains and of brackish paleowater flowing northward from Sinai. Very little is known of the hydraulic properties of this aquifer. In order to outline assumed natural flow paths that existed in this karstic environment prior to groundwater exploitation, use was made of lithological, structural, and paleomorphological features. A detailed hydrogeological conceptual model of the Judea Group aquifer in northern Negev was established by the geological interpretation of high-resolution seismic reflection and by analysis of lithological evidence from boreholes. Isopach, isolith-contour, and isolith-ratio maps were compiled for the main lithological components. Increase in transmissivity values is inversely proportional with the cumulative thickness of argillaceous components. The lithological and hydraulic evidence provides the basis for subdividing the subsurface into distinctive permeability zones for the upper and lower sections of the aquifer; for outlining possible preferential groundwater flow paths for both subaquifers; and for improving understanding of groundwater-salinty variations that result from lithological variability, direction of groundwater flow paths, groundwater flow rates, and the duration of rock/water interactions. In an earlier conceptual model of the basin, the Judea Group aquifer was regarded as a continuous and undisturbed entity. The present study reveals an intricate groundwater flow pattern that is controlled by lithological and structural factors that create zones of preferential flow. This interpretation bears on the overall evaluation of groundwater resources and their management and exploitation. Received, December 1996 · Revised, October 1997, June 1998 · Accepted, July 1998     

Runoff and erosion processes and rates in the Zin valley badlands,northern Negev,Israel

Badland areas are usually regarded as impermeable zones which generate high runoff and are very vulnerable to sheetwash and rainsplash. To test those considerations sprinkling experiments using two rainfall simulators were carried out on slopes of varying aspect in the northern Negev (Israel). For one unit 1·5 m² plots were used with rainfall of natural characteristics at 36 mm/hr intensity and 43–48 minute duration, runoff being recorded and water/sediment samples taken every 5 minutes. The second unit was used on 30–50 m² plots but rainfall energy production was below that of natural rainfall. Results show that due to the high stability and strong flocculation of clay-rich aggregates rainsplash is ineffective in surface sealing so that infiltration capacities remain high despite intense, prolonged rainfall. Aspect differences are reflected in variation of surface properties despite homogenous bed-rock, which cause marked differences in hydrological response. North-facing slopes respond more quickly, more frequently and produce more runoff than south-facing slopes. Non-uniform runoff generation is also seen within plots of one aspect reflecting subtle variations in surface properties. Comparison of rainfall intensity and duration used during the experiments with those prevailing under natural conditions shows that under present day conditions surface flow in the Zin valley badlands must be extremely infrequent and denudation rates very low.     

Holocene rockfalls in the southern Negev Desert,Israel and their relation to Dead Sea fault earthquakes

Rockfall ages in tectonically active regions provide information regarding frequency and magnitude of earthquakes. In the hyper-arid environment of the Dead Sea fault (DSF), southern Israel, rockfalls are most probably triggered by earthquakes. We dated rockfalls along the western margin of the DSF using terrestrial cosmogenic nuclides (TCN). At each rockfall site, samples were collected from simultaneously exposed conjugate boulders and cliff surfaces. Such conjugate samples initially had identical pre-fall (“inherited”) TCN concentrations. After boulder detachment, these surfaces were dosed by different production rates due to differences in post-fall shielding and geometry. However, in our study area, pre-rockfall inheritance and post-rockfall production rates of TCN cannot be evaluated. Therefore, we developed a numerical approach and demonstrated a way to overcome the above-mentioned problems. This approach can be applied in other settings where rockfalls cannot be dated by simple exposure dating. Results suggest rockfall ages between 3.6 ± 0.8 and 4.7 ± 0.7 ka. OSL ages of sediment accumulated behind the boulders range between 0.6 ± 0.1 and 3.4 ± 1.4 ka and support the TCN results. Our ages agree with dated earthquakes determined in paleoseismic studies along the entire length of the DSF and support the observation of intensive earthquake activity around 4–5 ka.