广西姑婆山里松花岗岩中闪长质包体的地球化学特征及其成因探讨

广西姑婆山里松花岗岩中广泛发育有大量的闪长质包体，包体的野外地质特征、显微结构、矿物组合及化学组成等特征显示其岩浆快速结晶成因。它们的主量元素在相关图上呈不同程度的直线变异关系。在微量元素方面，包体和寄主花岗岩都富含大离子亲石元素和高场强元素。用锆石饱和温度和角闪石成分估算了包体和寄主花岗岩结晶的温度和压力表明，它们的结晶温度和压力条件相近，分别在793—824℃和（3．5—5．1）×10^8Pa范围内。岩石学和同位素地球化学特征也表明，里松包体和寄主花岗岩基本同时结晶，但壳幔比例和来源有所不同。这些特征总体上说明了里松闪长质包体可能是两种岩浆混合时不完全消化的产物     

A hybrid framework for improving recharge and discharge estimation for a three-dimensional groundwater flow model

We employed the ArcGIS plug-in package PRO-GRADE (Lin et al. 2009), developed for zonation of recharge/discharge (R/D) for modeling two-dimensional aquifer systems, to develop alternative R/D zonations for an existing three-dimensional groundwater flow model of a complex hydrogeologic setting. Our process began by intersecting PRO-GRADE output with the existing model's 4-zone R/D representation to develop a model having 12 R/D zones (R12) and then calibrating the resulting model using PEST. We then revised the R12 zonation using supplementary GIS data to develop a 51-zone R/D zonation (R51). From R51, we developed a series of daughter models having 40, 30, 28, and 18 R/D zones by removing zones from R51 if calibration resulted in little change in the zone's starting R/D rate and/or if the model was insensitive to the zone's R/D rate. For these models (R40N, R30N, R28N, and R18N), we used the ArcGIS Nibble tool to rapidly and consistently reassign model cells within eliminated zones of R51 to the zone of the nearest model cell in a retained zone having the same starting value. R12, R51, R40N, R30N, R28N, and R18N are all more accurate than the original model (R4), although improvements relative to stream discharge targets exceeded improvements relative to head targets. The models also executed with better numerical stability and less mass balance discrepancy than R4. These improvements demonstrate that R/D estimation in a complex shallow three-dimensional steady-state model can be improved with PRO-GRADE estimates of R/D when guided by calibration statistics and supplemental geographic data.     

Microbial community dynamics and biodegradation of polycyclic aromatic hydrocarbons in polluted marine sediments in Hong Kong

Dynamics of microbial community and biodegradation of polycyclic aromatic hydrocarbons (PAHs) in polluted marine sediments, artificially spiked with a mixture of PAHs (fluorene, phenanthrene, fluoranthene and pyrene), were examined for a period of 60 days. Microbial communities were characterised by bacterial counts, ester-linked fatty acid methyl ester (EL-FAME) analysis and denaturing gradient gel electrophoresis (DGGE). A noted reduction in species diversity occurred only in the high PAH level treatment at onset. Both EL-FAME and DGGE demonstrated a marked shift in microbial community, in all the PAH level treatments, afterwards, with increases in the number of fatty acid degraders, the relative abundance of fatty acid biomarkers for gram-negative bacteria and a decrease in species diversity. The shift was also accompanied by the significant decrease in PAH concentrations. By the end of the experiment, diversity indices, based on both approaches, recovered when PAH concentrations declined to their background levels, except in the high PAH level treatment.     

H2Pb2Fe4[（Te，S）O4]9·9H2O：东坪金矿的未定名碲酸盐矿物

东坪金矿是产于正长杂岩内接触带的特大型金矿床。矿石以富碲、少硫化物为特点。主要载金矿物为自然金和金、银碲化物。后包裹于黄铁矿为主的硫化物内,属于氰化法的“难溶金”,在表生条件下的氧化产物种类丰富的含金碲酸盐相中含量与自然金相当。     

冀西北水泉沟正长岩杂岩体成因机制及成岩成矿时代探讨

华北克拉通北缘富碱侵入岩带是我国重要的金矿成矿带,金矿成矿与克拉通边缘深大断裂的活动、富碱侵入岩岩浆活动关系密切。河北张-宣地区与正长岩有关的金矿床产于水泉沟正长岩杂岩体的内外接触带,与水泉沟碱性杂岩体有成因联系。近年来对其及与之有关的金(碲)矿化进行了深入研究,现就岩体成因、岩体形成年龄及金矿化年龄代等问题作一简要探讨。     

碲成矿机制研究新进展

简要总结了碲的丰度、矿物学及其分布,重点论述了“碱质类”金矿床中碲的赋存状态、载金作用、迁移形式及其来源等研究的现状、存在问题和大水沟独立碲矿床对研究元素超常富集的启示,并对超大型矿床成矿机制的研究方向进行了展望。     

东坪金矿矿石碲、金分布及其相关性

用原子吸收，原子荧光法分别系统测定矿石Au,Te含量表明，东坪金矿具有典型的Au-Te元素组合，Te/Au比值平均为0．71，且随矿石Au丰度的加富而增加，它们的相关系数增大，Au,Te含量对数值的统计分布和矿物组合，元素赋存状态的微束分析结果表明，Au,Te均以独立矿物为主要赋存状态，但Aud的矿化表现出多期次特征，而Te主要在硅化－硫化物阶段，二可能具有不同的母源，上述结论对提高金的回收率，碲的综合利用和事矿体的追索提供一定的依据。     

湘南骑田岭岩体菜岭超单元花岗岩侵位年龄和物质来源研究

湘南骑田岭岩体菜岭超单元花岗岩以角闪石黑云母二长花岗岩为主,其全岩Rb-Sr等时线年龄为159±1.2Ma,单颗粒锆石熔融法U-Pb年龄为161±2Ma,Sr同位素初始比值偏低(0.70854),Nd同位素初始比值偏高(-5.4～-5.8),Nd模式年龄偏低(0.94～1.49Ga)。在岩石化学和微量元素方面,属钙碱系列,准铝,富含K、Rb等大离子亲石元素和Th、REE、Nb等高场强元素。常见较多具有岩浆混合特征的微花岗岩类暗色包体。这些同位素、岩石学和微量元素特征,总体上反映了菜岭超单元花岗岩的成岩组成中有明显的地幔物质的参与。该花岗岩可能是在燕山早期华南地壳开始拉张减薄的构造背景下定位的,壳幔相互作用对本区大陆地壳物质的重熔和花岗岩浆的形成和演化起了重要的作用。