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1.
A survey of the 4(04)-3(03) and 1(01)-0(00) transitions of HOCO+ has been made toward several molecular clouds. The HOCO+ molecule was not observed in any sources except Sgr B2 and Sgr A. The 5(05)-4(04) and 4(14)-3(13) transitions were also detected toward Sgr B2. The results indicate that gas phase CO2 is not a major carbon reservoir in typical molecular clouds. In Sgr B2, the HOCO+ antenna temperature exhibits a peak approximately 2' north of the Sgr B2 central position (Sgr B2[M]) and the 4(04)-3(03) line emission is extended over a approximately 10' x 10' region. The column density of HOCO+ at the northern peak in Sgr B2 is approximately 3 x 10(14) cm-2, and the fractional abundance relative to H2 > or = 3 x 10(-10), which is about 2 orders of magnitude greater than recent predictions of quiescent cloud ion-molecule chemistry. 相似文献
2.
Irvine WM Friberg P Hjalmarson A Ishikawa S Kaifu N Kawaguchi K Madden SC Matthews HE Ohishi M Saito S Suzuki H Thaddeus P Turner BE Yamamoto S Ziurys LM 《The Astrophysical journal》1988,334(2):L107-L111
We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H. 相似文献
3.
We have used observations of the rare isotopes of HCN and HNC to determine the relative abundance of these two chemical isomers along the central ridge of the Orion molecular cloud. The abundance ratio [HCN]/[HNC] decreases by more than an order of magnitude from the relatively warm plateau and hot core sources toward the KL nebula to the colder, more quiescent clouds to the north and south. Even in the cooler regions, however, the ratio is an order of magnitude larger than that found in previous investigations of cold dark clouds. We determine the kinetic temperature in the regions we have studied from new observations of methylacetylene (CH3CCH), together with other recent estimates of the gas temperature near KL. The results suggest that the warmer portions of the cloud are dominated by different chemical pathways than those in the general interstellar cloud material. 相似文献
4.
本文介绍了海水中砷标准物质的研制过程,其中包括溶液的配制、均匀性和稳定性检验,标样的分析方法。并对标准物质的定值数据进行统计处理,两种浓度的定值结果分别为:1.00μg/cm3±0.04μg/cm3和51.0μg/dm3±2.6μg/dm3。两种浓度砷标准物质的稳定期均为一年 相似文献
5.
根据2000年6月10~14日在浙江省西沪港采集的海水样品,利用AA-800石墨炉原子吸收分光光度技术和阳极溶出伏安法测定样品中重金属铜的含量,获得铜在海水中受不同的有机配体控制.不同粒级的铜表观配位容量表明西沪港海水过孔径1.00μm微孔膜的(ACuCC)较高,为144.4nmol/dm3;过0.40和0.20μm滤膜的(ACuCC)分别为103.0和102nmol/dm3;铜的有机配体条件稳定常数的对数值在7.25~9.14之间.铜的总量为21.72nmol/dm3.铜全部为稳定溶解态,其中pH2酸溶态占95.0%,强有机结合态占5.0%.溶解态铜中有机结合态占过滤海水中总铜的61.6%. 相似文献
6.
本文介绍了以海水为基体的痕量金属(Cu、Pb、Cd、Cr、Zn)标准物质的制备、均匀性和稳定性,经试验,在一年零三个月时间内各元素的浓度值为Cu5.0±0.4、Pb10.0±0.6、Cd1.00±0.06、Cr5.0±0.4、Zn70±3μg/kg。 相似文献
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9.
Ohishi M Ishikawa SI Amano T Oka H Irvine WM Dickens JE Ziurys LM Apponi AJ 《The Astrophysical journal》1996,471(1):L61-L64
A new interstellar molecular ion, H2COH+ (protonated formaldehyde), has been detected toward Sgr B2, Orion KL, W51, and possibly in NGC 7538 and DR21(OH). Six transitions were detected in Sgr B2(M). The 1(1,0)-1(0,1) transition was detected in all sources listed above. Searches were also made toward the cold, dark clouds TMC-1 and L134N, Orion (3N, 1E), and a red giant, IRC + 10216, without success. The excitation temperatures of H2COH+ are calculated to be 60-110 K, and the column densities are on the order of 10(12)-10(14) cm-2 in Sgr B2, Orion KL, and W51. The fractional abundance of H2COH+ is on the order of 10(-11) to 10-(9), and the ratio of H2COH+ to H2CO is in the range 0.001-0.5 in these objects. The values in Orion KL seem to be consistent with the "early time" values of recent model calculations by Lee, Bettens, & Herbst, but they appear to be higher than the model values in Sgr B2 and W51 even if we take the large uncertainties of column densities of H2CO into account. We suggest production routes starting from CH3OH may play an important role in the formation of H2COH+. 相似文献
10.
We report the first detection of interstellar nitrogen sulfide (NS) in cold dark clouds. Several components of the 2 pi 1/2, J = 3/2 --> 1/2 and J = 5/2 --> 3/2 transitions were observed in TMC-1 and L134N. The inferred column density for TMC-1 is NNS approximately 8 x 10(12)cm-2 toward the NH3 peak in that cloud, and in L134N is NNS approximately 3 x 10(12)cm-2 toward the position of peak NH3 emission. These values correspond to fractional abundances relative to molecular hydrogen of fNS approximately 8 x 10(-10) for TMC-1, and fNS approximately 6 x 10(-10) for L134N. The NS emission is extended along the TMC-1 ridge and is also extended in L134N. The measured abundances are significantly higher than those predicted by some recent gas phase ion-molecule models. 相似文献