Scanning electron microscopy,cathodoluminescence, and Raman spectroscopy of experimentally shock‐metamorphosed quartzite

Abstract— We studied unshocked and experimentally (at 12, 25, and 28 GPa, with 25, 100, 450, and 750°C pre‐shock temperatures) shock‐metamorphosed Hospital Hill quartzite from South Africa using cathodoluminescence (CL) images and spectroscopy and Raman spectroscopy to document systematic pressure or temperature‐related effects that could be used in shock barometry. In general, CL images of all samples show CL‐bright luminescent patchy areas and bands in otherwise nonluminescent quartz, as well as CL‐dark irregular fractures. Fluid inclusions appear dominant in CL images of the 25 GPa sample shocked at 750°C and of the 28 GPa sample shocked at 450°C. Only the optical image of our 28 GPa sample shocked at 25°C exhibits distinct planar deformation features (PDFs). Cathodoluminescence spectra of unshocked and experimentally shocked samples show broad bands in the near‐ultraviolet range and the visible light range at all shock stages, indicating the presence of defect centers on, e.g., SiO₄ groups. No systematic change in the appearance of the CL images was obvious, but the CL spectra do show changes between the shock stages. The Raman spectra are characteristic for quartz in the unshocked and 12 GPa samples. In the 25 and 28 GPa samples, broad bands indicate the presence of glassy SiO₂, while high‐pressure polymorphs are not detected. Apparently, some of the CL and Raman spectral properties can be used in shock barometry.     

Exposure history of the Torino meteorite

Abstract— We determined He, Ne, Ar, ¹⁰Be, ²⁶Al, ³⁶Cl, and ¹⁴C concentrations, as well as cosmic-ray track densities and halogen concentrations in different specimens of the H6 chondrite Torino, in order to constrain its exposure history to cosmic radiation. The Torino meteoroid had a radius of ～20 cm and travelled in interplanetary space for 2.5–10 Ma. Earlier, Torino was part of a larger body. The smallest possible precursor had a radius of 55 cm and a journey through space longer than ～65 Ma. If the first-stage exposure took place in a body with a radius of >3 m or in the parent asteroid, then it lasted nearly 300 Ma. The example of Torino shows that it is easy to underestimate first-stage exposure ages when constructing two-stage histories.     

Paleoenvironment and sea-level change in the early Cretaceous Barents Sea—implications from near-shore marine sapropels

The late Volgian (early "Boreal" Berriasian) sapropels of the Hekkingen Formation of the central Barents Sea show total organic carbon (TOC) contents from 3 to 36 wt%. The relationship between TOC content and sedimentation rate (SR), and the high Mo/Al ratios indicate deposition under oxygen-free bottom-water conditions, and suggest that preservation under anoxic conditions has largely contributed to the high accumulation of organic carbon. Hydrogen index values obtained from Rock-Eval pyrolysis are exceptionally high, and the organic matter is characterized by well-preserved type II kerogen. However, the occurrence of spores, freshwater algae, coal fragments, and charred land-plant remains strongly suggests proximity to land. Short-term oscillations, probably reflecting Milankovitch-type cyclicity, are superimposed on the long-term trend of constantly changing depositional conditions during most of the late Volgian. Progressively smaller amounts of terrestrial organic matter and larger amounts of marine organic matter upwards in the core section may have been caused by a continuous sea-level rise.     

Chalk shore platform erosion in the vicinity of sea defence structures and the impact of construction methods

Erosion of the intertidal chalk platform in the vicinity of groynes and seawalls is evident to the naked eye along many stretches of the engineered coastline of southeast England, leading to undermining and eventually failure of these structures. However, quantification of the magnitude and spatial extent of the erosion has been difficult to date because of a lack of data about the past elevation of the platform. The application of softcopy photogrammetry makes it possible to recreate past platform elevations from historic air photographs and to compare these with elevations from modern air photographs. Coastal sea defence structures have been installed along the chalk coast east of Brighton at various dates over the past 70 years. During this period, the construction methods have changed from predominantly manual labour to a reliance on heavy machines. The analysis of erosion patterns around structures built since the 1970s using heavy machinery show that surface lowering is 4 to 25 times greater in the vicinity of these structures than across the platform as a whole. In contrast, there is no similar pattern of increased erosion around structures built using predominantly manual labour in the 1930s. A four fold increase in average surface lowering is found also along a vehicle trackway that crosses the mid platform. Depressions developed by enhanced lowering in the front of seawalls generate their own dynamic of increased erosion by trapping pebbles and cobbles that enhance the abrasion of the chalk through bedload transport under standing waves in front of the walls.     

Observations of the Labrador Sea eddy field

This paper is an observational study of small-scale coherent eddies in the Labrador Sea, a region of dense water formation thought to be of considerable importance to the North Atlantic overturning circulation. Numerical studies of deep convection emphasize coherent eddies as a mechanism for the lateral transport of heat, yet their small size has hindered observational progress. A large part of this paper is therefore devoted to developing new methods for identifying and describing coherent eddies in two observational platforms, current meter moorings and satellite altimetry. Details of the current and water mass structure of individual eddy events, as they are swept past by an advecting flow, can then be extracted from the mooring data. A transition is seen during mid-1997, with long-lived boundary current eddies dominating the central Labrador Sea year-round after this time, and convectively formed eddies similar to those seen in deep convection modeling studies apparent prior to this time. The TOPEX / Poseidon altimeter covers the Labrador Sea with a loose “net” of observations, through which coherent eddies can seem to appear and disappear. By concentrating on locating and describing anomalous events in individual altimeter tracks, a portrait of the spatial and temporal variability of the underlying eddy field can be constructed. The altimeter results reveal an annual “pulsation” of energy and of coherent eddies originating during the late fall at a particular location in the boundary current, pinpointing the time and place of the boundary current-type eddy formation. The interannual variability seen at the mooring is reproduced, but the mooring site is found to be within a localized region of greatly enhanced eddy activity. Notably lacking in both the annual cycle and interannual variability is a clear relationship between the eddies or eddy energy and the intensity of wintertime cooling. These eddy observations, as well as hydrographic evidence, suggest an active role for boundary current dynamics in shaping the energetics and water mass properties of the interior region.     

Remote spectroscopic identification of carbonaceous chondrite mineralogies: Applications to Ceres and Pallas

High-resolution spectroscopic observations of asteroids Ceres and Pallas have been obtained in the 1.0- to 2.6-μm region. Combined with previous spectralmeasurements at other wavelengths, this work presents the broadband spectral reflectances of these asteroids over the 0.4 to 3.6-um region. This extended coverage permits new analyses of the surface mineralogies of these objects. Using laboratory comparison spectra of meteorites and mixtures of terrestrial minerals, the surfaces of Ceres and Pallas are consistent with mixtures of opaques and hydrated silicates, such as are found in types C1 and C2 meteorites. This research emphasizes the importance of the 3-um spectral region for studying by remote methods the relationship of carbonaceous chondrite mineralogies to asteroid surfaces.     

Upper limits to trace constituents in Jupiter's atmosphere from an analysis of its 5-μm spectrum

A high-resolution (0.6 cm^?1) spectrum of Jupiter at 5 μm recorded at the Kuiper Airborne Observatory is used to determine upper limits to the column density of 19 molecules. The upper limits to the mixing ratios of SiH₄, H₂S, HCN, and simple hydrocarbons are discussed with respect to current models of Jupiter's atmosphere. These upper limits are compared to expectations based upon the solar abundance of the elements. This analysis permits upper limit measurements (SiH₄), or actual detections (GeH₄), of molecules with mixing ratios with hydrogen as low as 10^?9. In future observations at 5 μm the sensitivity of remote spectroscopic analyses should permit the study of constituents with mixing ratios as low as 10^?10, which would include the hydrides of such elements as Sn and As as well as numerous organic molecules.     

Exposure ages from relict lateral moraines overridden by the Fennoscandian ice sheet

Lateral moraines constructed along west to east sloping outlet glaciers from mountain centred, pre-last glacial maximum (LGM) ice fields of limited extent remain largely preserved in the northern Swedish landscape despite overriding by continental ice sheets, most recently during the last glacial. From field evidence, including geomorphological relationships and a detailed weathering profile including a buried soil, we have identified seven such lateral moraines that were overridden by the expansion and growth of the Fennoscandian ice sheet. Cosmogenic ¹⁰Be and ²⁶Al exposure ages of 19 boulders from the crests of these moraines, combined with the field evidence, are correlated to episodes of moraine stabilisation, Pleistocene surface weathering, and glacial overriding. The last deglaciation event dominates the exposure ages, with ¹⁰Be and ²⁶Al data derived from 15 moraine boulders indicating regional deglaciation 9600 ± 200 yr ago. This is the most robust numerical age for the final deglaciation of the Fennoscandian ice sheet. The older apparent exposure ages of the remaining boulders (14,600-26,400 yr) can be explained by cosmogenic nuclide inheritance from previous exposure of the moraine crests during the last glacial cycle. Their potential exposure history, based on local glacial chronologies, indicates that the current moraine morphologies formed at the latest during marine oxygen isotope stage 5. Although numerous deglaciation ages were obtained, this study demonstrates that numerical ages need to be treated with caution and assessed in light of the geomorphological evidence indicating moraines are not necessarily formed by the event that dominates the cosmogenic nuclide data.     

Streams in the Harz National Parks (Germany) — a hydrochemical and hydrobiological evaluation

Between 1995 and 2001, 16 measuring points at small and medium sized brooks in the Harz National Parks were sampled. The samples have been evaluated by means of hydrochemistry and macroinvertebrate biology. Although nearly all streams are largely uncontaminated by oxygen-consuming substances, they are settled only by a small number of macroinvertebrate species. There is a clear correlation between this number and pH. The reduction in species number with decrease of pH is mainly caused by the absence of most Ephemeroptera, some Coleoptera and Trichoptera. Comparing biological evaluation of acidity with physico-chemical measurements, a unacceptable underestimation was found. The reason could be that different sensitivities to acidification between regional populations seem to exist.

Despite of the low species number, there is a very specific macroinvertebrate fauna that emphasizes the conservation value of the Harz National Parks.