Pathways of clay mineral transport in the coastal zone of the Brazilian continental shelf from Ceará to the mouth of the Amazon River

The transport pathways of fine sediments (fraction <2 μm) along the Brazilian continental shelf from Ceará to the Amazon River mouth were studied by means of clay mineral analyses. On the continental shelf southeast of the Amazon mouth, fluctuations in clay mineral compositions reflect simple mixing between the suspended load of the North Brazil Current and sediment from several smaller rivers. Previously, clay mineral variations west of the Amazon mouth have been explained by variable settling velocities of different grain-size classes within the <2 μm fraction or by selective coagulation of individual clay mineral groups. By contrast, our experiments with river bank samples show that selective coagulation does not occur in Amazon River sediments. A more appropriate explanation for observed variations in clay mineral composition off the Amazon mouth seems to be, similarly to that for the shelf between Ceará and the Amazon mouth, a mixing of Amazon sediments with suspended material of the North Brazil Current. This interpretation is supported by data on clay mineral composition east and south of the Amazon mouth, showing more affinity to sediments of the North Brazil Current than to the suspended load of the Amazon River. Additionally, relatively low sedimentation rates and low concentrations of fine-grained sediments on the shelf suggest that high riverine input by the Amazon River does not overprint the sediments of the North Brazil Current in this region. The strong North Brazil Current shunts the Amazon suspended load in a north-westerly direction along the north-eastern coast of South America. Hence, stronger sedimentation of Amazon sediments would occur only west of the river mouth.     

Chemical and environmental compatibility of red mud liners for hazardous waste containment

Red mud residue from alumina production has been proposed as an alternative liner material. The chemical and environmental compatibility of red mud upon exposure to representative organic (methanol, heptane, TCE, and acetic acid) and inorganic liquids (CaCl₂ and seawater) was studied. Chemical compatibility assays comprised Atterberg limits and sedimentation and hydraulic conductivity tests for red mud interacted with the chemical liquids, whereas the environmental compatibility was assessed through the leaching of metals from red mud as permeated with the liquids. Methanol greatly reduced the plasticity at concentrations ≥80 % by volume, but it did not increase the hydraulic conductivity of compacted red mud. High concentrations (≥60 % v/v) of acetic acid reduced the plasticity and enhanced the sedimentation of red mud. Conversely, acetic acid concentrations ≤40 % caused dispersion, but damaged the hydraulic properties and structure of red mud. The percolation of a pH 2 acetic acid solution did not adversely affect the hydraulic performance of the red mud liner. Neither diluted heptane nor TCE affected the red mud. However, pure organics suppressed the plasticity and induced aggregation of red mud, suggesting a great detrimental effect on red mud liners. The red mud exhibited great resistance to attack by inorganic salt solutions. Some concerning leaching of metals (primarily Al and Cr) occurred as water, acetic acid, and CaCl₂ solutions percolated through red mud, but effluent metals concentration quickly dropped to permissible levels. In general, red mud exhibited a high resistance against chemical attack; nevertheless, exposure to low-dielectric-constant organic chemicals should be avoided.     

Nutrient dynamics in Mediterranean temporary streams: A case study in Pardiela catchment (Degebe River, Portugal)

Most of the streams in the Mediterranean region are temporary, following predictable seasonal of flooding and drying, with a transition from lotic conditions to shallow lentic conditions. The goal of our study was to assess the nitrogen and phosphorus dynamics in channel-bed processes of temporary streams between floods. Results show that, during winter, temperatures ranged between 9.5 and 11.2 °C and oxygen concentration ranged from 8.0 to 9.5 mg L⁻¹, whereas, during summer, temperatures varied between 21.2 and 26.8 °C and oxygen between 1.2 and 5.3 mg L⁻¹, with oxygen depletion in the pools during the night. The nitrate concentrations were far more abundant during winter (February), while ammonium concentration increased after stream fragmentation into pools (especially in July when oxygen depletion conditions favoured ammonification). Results on sediment profiles showed that the most active sediment layers for NH₄-N are the top 2–3 cm, corresponding to the sediment depositional sites of the stream. Phosphate concentrations had larger variability, yet concentrations decreased from winter to spring and increased again in summer, when the shallow water pools were formed. Sediment profiles at the sediment depositional sites showed that PO₄-P was more dynamic in the first 6 cm.

In Mediterranean temporary streams, nutrient dynamics vary seasonally, as the system transits from lotic conditions to shallow lentic conditions, evidencing the regeneration of nutrients from organic and inorganic matter during the flow cessation period.     

Momentum- and Heat-Flux Parametrization at Dome C,Antarctica: A Sensitivity Study

An extensive meteorological observational dataset at Dome C, East Antarctic Plateau, enabled estimation of the sensitivity of surface momentum and sensible heat fluxes to aerodynamic roughness length and atmospheric stability in this region. Our study reveals that (1) because of the preferential orientation of snow micro-reliefs (sastrugi), the aerodynamic roughness length \(z_{0}\) varies by more than two orders of magnitude depending on the wind direction; consequently, estimating the turbulent fluxes with a realistic but constant \(z_{0}\) of 1 mm leads to a mean friction velocity bias of \(24\,\%\) in near-neutral conditions; (2) the dependence of the ratio of the roughness length for heat \(z_{0t}\) to \(z_{0}\) on the roughness Reynolds number is shown to be in reasonable agreement with previous models; (3) the wide range of atmospheric stability at Dome C makes the flux very sensitive to the choice of the stability functions; stability function models presumed to be suitable for stable conditions were evaluated and shown to generally underestimate the dimensionless vertical temperature gradient; as these models differ increasingly with increases in the stability parameter z / L, heat flux and friction velocity relative differences reached \(100\,\%\) when \(z/L > 1\); (4) the shallowness of the stable boundary layer is responsible for significant sensitivity to the height of the observed temperature and wind data used to estimate the fluxes. Consistent flux results were obtained with atmospheric measurements at heights up to 2 m. Our sensitivity study revealed the need to include a dynamical parametrization of roughness length over Antarctica in climate models and to develop new parametrizations of the surface fluxes in very stable conditions, accounting, for instance, for the divergence in both radiative and turbulent fluxes in the first few metres of the boundary layer.     

Aeolian dune migration along the Ceará coast, north-eastern Brazil

Aeolian dune dimensions and migration rates are analysed along the Ceará coast, north-east Brazil. Dunes that are currently mobile along the Ceará coast are composed of barchans and sand sheets. The results show that barchans maintain an equilibrium form, which can be characterized by values of dimensionless shape parameters H/W and W/L , where H is the dune height, W is the wing-to-wing width and L is the dune length. Dunes are highly mobile, with average migration rates of 17·5 m year⁻¹ for barchans and 10 m year⁻¹ for sand sheets. The calculated migration rates were found to depend strongly on dune dimensions for both barchans and sand sheets, i.e. the larger the dune is, the lower the migration rate will be. This size dependence was associated with the existence of a representative common transport rate along the dune fields, which induces a different dune migration rate dependent on dune size. Finally, from the observed dune evolution, an aggregated scale aeolian sediment transport was inferred. This bulk transport rate, of the order of 90–100 m³ m⁻¹ year⁻¹, is only valid for a timescale of years to decades, which is the timescale used in dune evolution analysis.     

Effects of sampling effort on the estimation of spatial gradients in a tropical reservoir impacted by an oil refinery

We investigated the effects of increase in sampling effort (30-1043 sampling points) on the accuracy of assessment of the spatial patterns of surface-water quality in a eutrophic tropical reservoir. The investigation was carried out during the dry season, when previous investigations showed that the spatial heterogeneity is more stable. A multi-parameter Yellow Springs Instruments probe coupled to a TechGeo D-GPS was used. This system is equipped to measure and store in a continuous recording mode, several physical and chemical parameters linked to geographical coordinates obtained with a precision of less than 1 m. We used different geostatistical approaches to determine the optimal number of sampling points required to reflect the real spatial patterns of water quality in the system. This approach was tested in a small tropical reservoir (Ibirité) that receives effluents from an oil refinery (the state-owned REGAP oil refinery, PETROBRAS) located near the city of Belo Horizonte. The study showed not only that the spatial patterns of water quality are significantly affected by sampling effort but also it was demonstrated that the establishment of an adequate sampling program is a critical point for the precise identification of source points of pollution. The results of this investigation enabled us to demonstrate the potential uses and limits of this method for rapid assessment of the water quality of lakes and reservoirs that receive external inputs of water contaminants or nutrients.     

Effect of the addition of granitic powder to an acidic soil from Galicia (NW Spain) in comparison with lime

The impact of diffuse pollution, agricultural land use and climate change on the long-term response of subsurface–surface water quality is not well understood, but is a prerequisite for evaluation of water management options. The goal of this study is to model geochemical evolution of water chemistry from the infiltration through soil into the unsaturated zone, transport through bedrocks and granular aquifers to a river in order to identify zones of steep concentration gradients and high dynamics under transient flow conditions. A numerical model was constructed comprising a 2-D 1,500 m × 150 m vertical cross-section of typical sedimentary rock formations, a glacio-fluvial quaternary gravel aquifer in the valley and soil layers. The model coupled saturated/un-saturated flow and reactive transport under steady state and transient conditions. Geochemical interactions, include intra-aqueous kinetic reactions of oxygen with dissolved organic matter, as well as kinetics of carbonate dissolution/precipitation. This model section was chosen to provide insight in to the principal processes and time scales affecting water chemistry along different flow paths. The numerical simulator MIN3P was used, a finite volume program for variably saturated subsurface flow and multi-component reactive transport. The results show that subsurface water residence times range from approximately 2 to 2,000 years. Different zones are to be expected with respect to the development of mineral equilibria; namely, purely atmospherically influenced, as well as open and closed system carbonate dissolution. Short-term responses to daily averaged changes in precipitation, however, are only visible to some extent in the shallower and near-river parts of flow system and solute loads. This can most likely be explained by directional changes in flow paths, indicating that equilibrium geochemical condition predominate at the hillslope scale, i.e. water quality depends on transport pathways rather than on kinetic effects. The extent of reducing conditions is controlled by the presence of organic-rich layers (i.e. peat deposits), the dissolution kinetics of aquifer organic matter and the subsequent mixing with oxygenated water by hydrodynamic dispersion.     

Retrograde resonance in the planar three-body problem

We continue the investigation of the dynamics of retrograde resonances initiated in Morais and Giuppone (Mon Notices R Astron Soc 424:52–64, doi:10.1111/j.1365-2966.2012.21151.x, 2012). After deriving a procedure to deduce the retrograde resonance terms from the standard expansion of the three-dimensional disturbing function, we concentrate on the planar problem and construct surfaces of section that explore phase-space in the vicinity of the main retrograde resonances (2/ $-$ 1, 1/ $-$ 1 and 1/ $-$ 2). In the case of the 1/ $-$ 1 resonance for which the standard expansion is not adequate to describe the dynamics, we develop a semi-analytic model based on numerical averaging of the unexpanded disturbing function, and show that the predicted libration modes are in agreement with the behavior seen in the surfaces of section.