Microboudin structures of piemontite along the Sambagawa metamorphic belt, Japan: implications for lateral variation of differential stress during regional metamorphism

Evidence is presented of a lateral variation in differential stress during metamorphism along a regional metamorphic belt on the basis of the proportion of microboudinaged piemontite grains (p) in a quartz matrix in metacherts. It is proposed that p is a practical indicator of relative differential stress. Analysis of 123 metacherts from the 800 km long Sambagawa metamorphic belt, Japan, reveals that p‐values range from < 0.01 to 0.7 in this region. Most samples from Wakayama in the mid‐belt area have p‐values of 0.4–0.6, whereas those from western Shikoku have p‐values of < 0.1. This difference cannot be explained by variations in metamorphic temperature, and is instead attributed to a regional, lateral variation in differential stress during metamorphism.     

The squeezing potential of rock around tunnels: Theory and prediction with examples taken from Japan

Summary Large deformations of surrounding media around tunnels are often encountered during excavations in rocks with squeezing characteristics. These deformations may sometimes continue for a long period of time. Predictions of deformations of tunnels in such grounds are urgently needed, not because of stability concerns, but also of their sevicability. In the present study, the squeezing phenomenon of rock around tunnels and its mechanism and associated factors are first clarified by carefully studying failures of tunnels, and a survey of tunnels in squeezing rocks in Japan is presented and its results are summarised. Then, a practical method is proposed to predic the squeezing potential and deformation of tunnels in squeezing rock and this method has beeen applied to actual tunnelling projects, where squeezing problems were encountered, to check its applicability and validity. Finally, an extension of this method to the time-dependent behaviour of squeezing rocks is given and an application of this method to an actual tunnel is presented.     

The squeezing potential of rocks around tunnels; Theory and prediction

Summary The deformational behaviour of tunnels, which underwent large deformations, socalled squeezing, have been recently receiving great attention in the field of rock mechanics and tunnelling. Contrary to rockbursting phenomenon in which the deformation of the medium takes place instantaneously, the deformation of the surrounding rock in squeezing phenomenon takes place slowly and gradually when the resulting stress state following the excavation exceeds the strength of the surrounding medium. Although there are some proposals for the definition of squeezing rocks and prediction of their squeezing potential and deformations of tunnels in literature, it is difficult to say that they are concise and appropriate.In the first half of this paper, the squeezing phenomenon of rock about tunnels and its mechanism and associated factors are clarified by studying carefully observed failures in-situ and laboratory model tests. Then, an extensive survey of tunnels in squeezing rocks in Japan is presented and the results of this survey are summarised. In the second half of the paper, a new method is proposed to predict the squeezing potential and deformations of tunnels in squeezing rock. Then, the method is applied to actual tunnelling projects, where squeezing problems have been encountered, to check its validity and applicability. As a concrete example, an application of the method to predict the squeezing potential and deformations of the rock along a 300 m long section of an actual tunnel was made.     

Calibration and validation of the ocean color version-3 product from ADEOS OCTS

We present calibration and validation results of the OCTS’s ocean color version-3 product, which mainly consists of the chlorophyll-a concentration (Chl-a) and the normalized water-leaving radiance (_nL_w). First, OCTS was calibrated for the inter-detector sensitivity difference, offset, and absolute sensitivity using external calibration source. It was also vicariously calibrated using in-situ measurements for water (Chl-a and_nL_w) and atmosphere (optical thickness), which were acquired synchronously with OCTS under cloud-free conditions. Second, the product was validated using selected 17 in-situ Chl-a and 11 in-situ_nL_w measurements. We confirmed that Chl-a was estimated with an accuracy of 68% for Chl-a less than 2 mg/m³, and_nL_w from 94% (band 2) to 128% (band 4). Geometric accuracy was improved to 1.3 km. Stripes were significantly reduced by modifying the detector normalization factor as a function of input radiance.     

MicroRaman spectroscopy of anomalous planar microstructures in quartz from Mt. Oikeyama: Discovery of a probable impact crater in Japan

Abstract– Planar deformation features (PDFs) and planar fractures (PFs) have been found and confirmed by optical microscope observations and microRaman spectroscopy in quartz grains from Mt. Oikeyama (Akaishi Mountains, Central Japan), for which the semicircular topographic feature of the ridge suggests a crater formed by an impact event. According to the optical microscope observations, a low shock pressure (8–10 GPa) is estimated by the occurrence of basal or ω PDFs leading to lack of multiple sets of PDFs. In addition, a new type of planar microstructure was found in several quartz grains. The microRaman characteristics of PDFs in quartz from Mt. Oikeyama show the amorphous state indicating the presence of weak broad bands at 400 and 800 cm^?1 peak positions. These characteristics are indicative of PDFs that are limited to shocked quartz. This indicates an impact origin for distinct planar microstructures in quartz from Mt. Oikeyama.     

Geometric Series-Steady State (GSSS) Model: A New Protocol for Interpreting Compound-Specific Δ14C Data

A model system developed to understand the complicated history of general organic matter in soil using its carbon isotopic data such as ??¹⁴C and ?? ¹³C is described. The system, named the geometric series-steady state (GSSS) model, is mathematically described as when the geometric series reaches a steady state in infinite time. This model assumes that molecules of photosynthetic origin are continuously supplied as well as decaying at constant rates. Consideration of the model leads to the following general remarks: (1) the GSSS model defines the unique undisturbed line on the ??¹⁴C age-abundance plane, along which any molecules supplied exclusively by photosynthesis may fall; (2) the model defines the disturbed regions on the plane: molecules supplied by not only photosynthesis but also biotic/abiotic synthetic reactions may give plots on the disturbed regions; (3) the ?? ¹³C value of a molecule cannot be fractionated by Rayleigh distillation type-fractionation. As an exercise, the GSSS model has been applied to the reported data of several fatty acids of different carbon number from soil. A protocol is presented which applies the GSSS model to the natural system, whose ??¹⁴C value was greatly altered by the bomb effect. By the combination of the GSSS consideration and model simulation using real atmospheric ¹⁴C data during the last half century, the author investigated the behavior of fatty acids within the assumptions of the model. Assuming that fatty acids with carbon number greater than or equal to 26 are undisturbed, the GSSS model concludes that fatty acids in soil with carbon number less than 26 are not directly supplied from leaf litter, but should be synthesized continually from other less labile molecules in the soil. The proportion of synthesized molecules to those supplied originally from leaves is greater for the smaller carbon numbered fatty acids. The GSSS model should be applicable to any system, in which a molecule is regularly supplied from atmospheric CO₂ via photosynthesis.     

Variation of the distribution coefficients of rare earth elements in modern coral-lattices: species and site dependencies

Rare earth element (REE) concentrations in the carbonate lattice of four species of coral have been analyzed and compared with the dissolved REE in ambient seawaters. The corals were from two areas of different salinity, marine (34-34.5) and bay (33-34). The measurement of REE in coral was carried out with inductively coupled plasma mass spectrometry (ICP-MS) after meticulous washing of coral samples, digestion with acetic acid and preconcentration of REE. The concentrations of REE in the two ambient seawaters were quite different, being ten-times higher in the bay area and enriched in light REE. However, the average distribution coefficients (D’s) were almost identical in the two areas. Substantial distribution coefficient differences were observed among the four coral species and the magnitude of inter-species variation in D was also species-dependent. Theoretical calculations imply that pH variation could cause variations in D large enough to account for the small differences between the two areas.     

Inhibiting effects of lanthanum ion on calcite formation from CaCL2-NaHCO3 solutions at 25°C

The influence of La³⁺ on calcite formation was studied using CaCl₂-NaHCO₃ solutions. We adopted a closed system, where the pH change of the solutions was monitored in a closed vessel. The closed system reduces a number of thermodynamic variables of the solution, thus enabling us to calculate the amount of CaCO₃ precipitate only from pH with the assumption of equilibria among dissolved components in solution. After the analytical inspection of the calculation and assumption on which the calculation is based on, it was applied to experiments of the calcite formation in a Teflon vessel. The mole concentration of lanthanum added in the experiments was smaller than 1/3000 of that of calcium ion in the solutions. The addition of lanthanum oxide, chloride, and nitrate caused the difference in the pH change of the solution. The decrease of pH was smaller when lanthanum reagents were added, indicating that the amount of CaCO₃ precipitate decreased. The smallest decrease was observed when lanthanum chloride or nitrate salt was added. The X-ray diffraction study showed that the CaCO₃ precipitated in any solutions were calcite. If an equilibrium is assumed, which is considered to be likely from the pH change, the ion activity product (IAP) calculated in this study increased about 6 times when lanthanum ion, whose concentration is only 1/14 000 mole of calcium ion, was present.     

Intergranular trace elements in mantle xenoliths from Russian Far East: Example for mantle metasomatism by hydrous melt

Based on both major and trace element chemistry, the occurrence of the intergranular component in mantle-derived xenoliths from far eastern Russia has been constrained. Whole-rock trace element measurements of one xenolith show apparent negative anomalies in Ce, Th, and high field strength elements on normalized trace element patterns. The trace element pattern of the whole rock differs from those of constituent minerals, indicating that the anomalies in the whole rock are attributable to the presence of an intergranular component. That assumption was confirmed using in situ analysis of trace elements in the intergranular substance and melt inclusion using laser ablation inductively coupled plasma–mass spectrometry. Both the intergranular component and the melt inclusions have identical trace element patterns, which mean that these materials are a cognate metasomatizing agent. The anomalies are regarded as mantle metasomatism related to an aqueous fluid. Hydrous minerals were observed on the wall of the melt inclusions using micro-Raman spectroscopy, indicating that the melt inclusions contained a large amount of water. Thus, this study reveals a trace element composition of a hydrous metasomatizing agent in the mantle.     

Composition of rare earth elements in settling particles collected in the highly productive North Pacific Ocean and Bering Sea: Implications for siliceous-matter dissolution kinetics and formation of two REE-enriched phases

Settling particles were sampled monthly for 1 year using an automated time-series sediment trap positioned at similar depths at two sites of high diatomaceous productivity in the North Pacific Ocean and Bering Sea. The particles were analyzed for rare earth elements (REEs) by inductively coupled plasma mass spectrometry (ICP-MS) with and without chemical treatment of the bulk samples to isolate siliceous fractions. The REE composition of the bulk samples is explained largely by the contribution of two distinct components: (i) carbonate with a higher REE concentration, a negative Ce anomaly and lighter REE (LREE) enrichment; (ii) opal with a lower REE concentration, a weaker negative Ce anomaly and heavier REE (HREE) enrichment.The siliceous fractions of settling particles are characterized by high Si/Al ratios (30-190), reflecting high diatom productivity at the studied sites. The La/Al ratio of the siliceous fraction is close to that of the upper crust, but the Lu/Al and Lu/La ratios are significantly higher than those of the upper crust or airborne particles, indicating the presence of excess HREEs in the siliceous fraction. Diatoms are believed to be important carriers of HREEs.The Ce anomaly, Eu anomaly, slope of the REE pattern, and ΣREE of the siliceous fraction vary exponentially with decreasing total mass flux. They can be well-reproduced according to the differential dissolution kinetics of elements in the order of Ce < lighter REEs (LREEs) < Eu = heavier REEs (HREEs) < Si from settling particles, where the dissolution rate is critically reduced through particle aggregation. This order is consistent with the vertical distribution of dissolved REEs and Si in oceans. The differential dissolution kinetics leads to HREE enrichment of the original diatoms and REE enrichment of dissolved diatoms. The Lu/Si ratio of the siliceous fraction of settling particles recovered from some of the highest diatom fluxes is identical to that of the two elements dissolved in deep seawater, providing further evidence for the dissolution of siliceous matter in deep water.