Predicting the impact of management and climate scenarios on groundwater nitrate concentration trends in southern Portugal

Hydrogeology Journal - The dynamics related to evolution of nitrate-contaminated groundwater are analyzed with focus on the impact of intrinsic aquifer properties, agricultural activities and...     

Using Traditional Methods and Indigenous Technologies for Coping With Climate Variability

In agrometeorology and management of meteorology related natural resources, many traditional methods and indigenous technologies are still in use or being revived for managing low external inputs sustainable agriculture (LEISA) under conditions of climate variability. This paper starts with the introduction of an “end-to-end” climate information build up and transfer system in agrometeorology, in which the use of such methods and technologies must be seen to operate. It then reviews the options that LEISA farmers have in risk management of agrometeorological and agroclimatological calamities. This is based on the role that the pertinent meteorological/climatological parameters and phenomena play as limiting factors in agricultural production and the expectations on their variability. Subsequently, local case studies are given as examples of preparedness strategies to cope with i). variable water/moisture flows, including mechanical impacts of rain and/or hail, ii). variable temperature and heat flows, including fires, and iii). fitting cropping periods to the varying seasons, everywhere including related phenomena as appropriate. The paper ends with a series of important additional considerations without which the indicated strategies cannot be successful on a larger scale and in the long run.     

Dispersal of natural and anthropogenic lead through submarine canyons at the Portuguese margin

Submarine canyons represent natural conduits for preferential transport of particulate material, including anthropogenic contaminants, from coastal zones directly to the deep sea. To assess related dispersal of natural and anthropogenic lead (Pb), we analyzed Pb concentrations and stable isotope ratios in surface sediments and sediment trap particulate material from the Portuguese margin Nazaré and Setúbal/Lisbon canyons. Geochemical data are integrated with previously obtained data on near-bottom hydrodynamics and processes and pathways of sediment transport. The two canyon systems are located in close geographic proximity to each other, but represent contrasting settings in terms of sediment input and down-canyon sediment transport processes.Concentration–isotope diagrams and three-isotope plots (²⁰⁶Pb/²⁰⁷Pb vs. ²⁰⁸Pb/²⁰⁶Pb) suggest binary mixing between natural and anthropogenic end members. The inferred isotopic signature of pollutant Pb (²⁰⁶Pb/²⁰⁷Pb=1.143 [1.134–1.149, 95% confidence interval]) is most consistent with industrial Pb; ongoing influence from gasoline Pb additives is at most of minor importance. Two proposed natural end members most likely bracket the isotopic signature of natural Pb. Accordingly, binary mixing calculations indicate that on average 20–45% vs. 35–55% of total Pb is derived from anthropogenic sources in the Nazaré and Setúbal–Lisbon canyon systems, respectively. Enhanced anthropogenic influence in the latter area is consistent with its proximity to heavily populated and industrialized areas and with sediment input from the Tagus and Sado rivers, potential major carriers of pollutant particles. In both canyon systems, the anthropogenic component generally decreases with increasing water depth.Isotopic signatures of sediment trap particulate material are generally consistent with surface sediment data at similar water depth, but show large variability in the upper Nazaré canyon and major deviations from surface sediments in the lower canyon. In the lower canyon, Pb isotopic ratios of sediment trap particulate material mostly reflect low pelagic fluxes from the overlying water column, whereas surface sediment signatures are dominated by episodic down-canyon mass transport events. Such gravity flows appear to incorporate older (pre-industrial) material masking the isotopic signature of pollutant Pb. Large variability in the upper canyon reflects continuous sediment resuspension by bottom currents. Stronger average bottom currents are associated with higher ²⁰⁶Pb/²⁰⁷Pb ratios of sediment trap particulate material and hence decreased influence of pollutant Pb. This may reflect preferential resuspension of natural Pb at the canyon floor and/or additional remobilization of older, less-polluted sediment in adjacent areas such as the canyon walls.     

Near-bed particle deposition and resuspension in a cold-water coral mound area at the Southwest Rockall Trough margin,NE Atlantic

Cold-water coral reefs and mounds are observed mainly on slopes and topographic highs, in areas with high current speeds. Previous investigations of the near-bed hydrodynamic regime around cold-water coral mounds at the Southwest Rockall Trough margin have revealed the presence of internal waves with a diurnal tidal frequency. Hitherto only short-term measurements existed on the particle supply to the corals and data are lacking on the seasonal variability. Bottom landers equipped with sensors recording near-bottom current dynamics were deployed at two sites in a mound area on the Southwest Rockall Trough margin, one with a dense coral cover and one without coral cover. At both sites a similar seasonal variation in internal-wave activity was recorded with high activity during winter and summer months and less dynamic conditions in spring and autumn. Increased intensity of internal-wave activity, reflected in higher average near-bottom current speed and amplitude of daily temperature fluctuations, results in higher mass fluxes as recorded in the sediment traps. On the site without coral cover, mass fluxes are two times higher, compared to the site with dense coral cover. During periods of high mass fluxes a predominance of resuspended material was observed at both sites, as indicated by reduced ²¹⁰Pb activity and low organic matter concentrations. The flux of resuspended material largely masked the primary pelagic signal. However, low δ¹⁵N values in early spring and summer marked the arrival of fresh particles on both sites. A dense coral framework, baffling a large amount of particles settling between the coral branches, results in differences in particle flux, chemical composition and freshness of the trapped material. On the long term the presence of a coral framework plays a crucial role in the build-up of cold-water coral mounds.     

Sediment bioavailable organic matter,deposition rates and mixing intensity in the Setúbal–Lisbon canyon and adjacent slope (Western Iberian Margin)

The role of the Setúbal–Lisbon canyon in accumulation and transport of labile organic matter from the coastal sea and ocean surface water towards the deep sea was assessed by investigating the distribution of organic matter of different quality in sedimentary aggregates and surface sediments of the canyon and adjacent slopes. Total hydrolysable amino acids (THAA) and organic carbon (Corg) were measured from aggregates, and contents of Corg, chlorophyll a (chl a), phaeopigments (phaeo), chloroplastic pigment equivalents (CPE) from sediments. As indices of organic matter (OM) quality THAA:Corg, degradation index (DI), chl a:phaeo, chl a:Corg and C:N ratio were determined. Sediment profiles of chl a and the isotope 210 of lead (²¹⁰Pb) were used as tracers in a transport model to estimate deposition rates and background levels of the tracers, and sediment mixing rates (Db). Whereas bulk Corg contents of canyon and slope sediments were practically similar at all depths, higher contents of THAA, chl a and CPE, as well as higher THAA:Corg, DI and chl a:Corg, in aggregates and sediments from the upper reaches of the canyon indicate that labile organic matter accumulates in the upper canyon. This is confirmed by higher chl a and ²¹⁰Pb deposition and Db calculated from the model. Hence, the Setúbal–Lisbon canyon, specially the upper region, acts as a natural trap of organic matter that is transported to the region via lateral transport and vertical settling from primary productivity. Organic matter might be further transported in downward canyon direction via rebound processes. The chl a and ²¹⁰Pb profiles reveal active sediment mixing by physical processes and/or animal reworking.     

Sustainable groundwater development in the coastal Tra Vinh province in Vietnam under saltwater intrusion and climate change

Three-dimensional transient groundwater flow and saltwater transport models were constructed to assess the impacts of groundwater abstraction and climate change on the coastal aquifer of Tra Vinh province (Vietnam). The groundwater flow model was calibrated with groundwater levels (2007–2016) measured in 13 observation wells. The saltwater transport model was compared with the spatial distribution of total dissolved solids. Model performance was evaluated by comparing observed and simulated groundwater levels. The projected rainfalls from two climate models (MIROC5 and CRISO Mk3.6) were subsequently used to simulate possible effects of climate changes. The simulation revealed that groundwater is currently depleted due to overabstraction. Towards the future, groundwater storage will continue to be depleted with the current abstraction regime, further worsening in the north due to saltwater intrusion from inland trapped saltwater and on the coast due to seawater intrusion. Notwithstanding, the impact from climate change may be limited, with the computed groundwater recharge from the two climate models revealing no significant change from 2017 to 2066. Three feasible mitigation scenarios were analyzed: (1) reduced groundwater abstraction by 25, 35 and 50%, (2) increased groundwater recharge by 1.5 and 2 times in the sand dunes through managed aquifer recharge (reduced abstraction will stop groundwater-level decline, while increased recharge will restore depleted storage), and (3) combining 50% abstraction reduction and 1.5 times recharge increase in sand dune areas. The results show that combined interventions of reducing abstraction and increasing recharge are necessary for sustainable groundwater resources development in Tra Vinh province.

     

Recent sediment transport and accumulation on the NW Iberian margin

Five transects across the NW Iberian margin were studied in the framework of the EU-funded Ocean Margin EXchange II (OMEX II) project, to determine and establish recent sediment and organic carbon transport and accumulation processes and fluxes.On the Galician shelf and shelf edge, resuspension of sediments resulting in well-developed bottom nepheloid layers was observed at all stations, but transport of suspended sediment appears largely confined to the shelf. On the continental slope, only very dilute bottom nepheloid layers were present, and intermediate nepheloid layers were only occasionally seen. This suggests that cross-slope transfer of particles is limited by the prevailing northerly directed shelf and slope currents.Optical backscatter and ADCP current measurements by the BOBO lander, deployed at 2152 m depth on the Galician slope, indicated that particles in the bottom boundary layer were kept in suspension by tidal currents with highest speeds between 15–25 cm s⁻¹. Net currents during the recording period August 6th–September 10th 1998, were initially directed along-slope toward the NNW, but later turned off-slope toward the SW.The separation of the water masses on the slope from the sediment-laden shelf water by the along-slope current regime is reflected in the recent sedimentary deposits of the Galician shelf and slope. Apart from compositional differences, shelf deposits differ from those on the slope by their higher flux of excess ²¹⁰Pb (0.57–5.37 dpm cm⁻²y⁻¹ versus 0.11–3.00 dpm cm⁻²y⁻¹), a much higher sediment accumulation rate (315.6–2295.9 g m⁻²y⁻¹ versus 10.9–124.7 g m⁻²y⁻¹) and organic carbon burial rate (1.01–34.30 g m⁻²y⁻¹ versus 0.01–0.69 g m⁻²y⁻¹).In contrast to the observations on the Galician margin, pronounced nepheloid layers occurred in the Nazaré Canyon, which extended to considerably greater water depths. This indicates that significantly greater transport of fine-grained particles in both the INL and the BNL was occurring within the canyon, as reflected in the exceptionally high ²¹⁰Pb excess flux (up to 34.09 dpm cm⁻²y⁻¹), mass accumulation rates (maximum 9623.1 g m⁻²y⁻¹) and carbon burial fluxes (up to 180.91 g m⁻²y⁻¹) in the sediment. However, radioisotope fluxes in the lower canyon were only slightly higher than at comparable depths on the Galician margin. This suggests that transport and rapid accumulation is focused on the upper and middle part of the canyon, from where it is episodically released to the deep sea. Compared to the Galician margin, the Nazaré Canyon may be considered as an important organic carbon depocenter on short time-scales, and a major conduit for particulate matter transport to the deep sea on >100 y time-scales.     

Influence of aquifer properties and the spatial and temporal distribution of recharge and abstraction on sustainable yields in semi‐arid regions

This paper aims to contribute to understanding the importance of four factors on the determination of sustainable yields: (i) aquifer properties; (ii) temporal distribution of recharge; (iii) temporal distribution of groundwater pumping; and (iv) spatial distribution of pumping wells. It is important to comprehend how the present‐day and future vulnerability of groundwater systems to pumping activities depend on these critical factors and what the risks are of considering sustainable yield as a fixed percentage of mean annual recharge (MAR). A numerical model of the Querença–Silves aquifer in Portugal is used to develop hypothetical scenarios with which these factors are studied. Results demonstrate the aquifer properties, particularly the storage coefficient, have an important role in determining the resilience of an aquifer and therefore to which degree it is dependent on the spatial and temporal distribution of abstraction and recharge, as well as the occurrence of extreme events. Sustainable yields are determined for the developed scenarios based on specific criteria rather than a fraction of MAR. Under simplified current recharge and abstraction conditions, the sustainable yield was determined at approximately 73% of MAR or 76 million m³. When considering a concentration of rainfall in time, as predicted by climate scenarios for the region, sustainable yield could drop to ca 70% of MAR. However, a more even distribution of pumping volumes throughout the year could increase this value. The location of the pumping wells is seen to affect the distribution of hydraulic heads in the aquifer, albeit without significant changes in sustainable yield. Copyright © 2011 John Wiley & Sons, Ltd.     

Evaluation of an intrinsic and a specific vulnerability assessment method in comparison with groundwater salinisation and nitrate contamination levels in two agricultural regions in the south of Portugal

The applicability of two vulnerability assessment methods in evaluating the impact of agricultural activities on groundwater quality, is tested in two areas in the south of Portugal with modest results. Intensive citri- and horticulture require large amounts of fertiliser and water supplied by irrigation, which induces groundwater salinisation and contamination by nitrates. The degree of contamination varies highly within and between the study areas and is related to hydrogeological factors as well as intensity of agricultural practices. Vulnerability mapping is performed with the intrinsic DRASTIC method and the specific Susceptibility Index (SI), which is an adaptation of DRASTIC. These methods can constitute useful groundwater management tools, for instance when designating new Nitrate Vulnerable Zones as defined in the European Directive 91/676/EEC. However, in the case of DRASTIC, little correspondence exists between the most vulnerable and the most contaminated areas. This is mainly a result of underestimating the dilution capacity and overemphasising the attenuating potential of the unsaturated zone and aquifer, as both chloride and nitrate prove to be very stable contaminants. By including a parameter for land use, SI manages to produce more reliable results, although in many areas the vulnerability is overestimated.

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Resumen Se evalúa la aplicabilidad de dos métodos de estimación de vulnerabilidad en evaluar el impacto de actividades agrícolas en la calidad del agua subterránea para dos áreas en el sur de Portugal obteniendo resultados modestos. La horticultura y citricultura intensiva requiere grandes cantidades de fertilizantes y agua abastecida por riego, lo cual induce salinización de agua subterránea y contaminación por nitratos. El grado de contaminación varía fuertemente dentro y entre las áreas de estudio y se relaciona con factores hidrogeológicos así como con la intensidad de las prácticas agrícolas. El mapeo de vulnerabilidad se lleva a cabo con el método intrínsico DRASTIC y el Índice de Susceptibilidad específica (SI), el cual es una adaptación de DRASTIC. Estos métodos pueden constituir herramientas de manejo de aguas subterráneas útiles, por ejemplo al designar nuevas Zonas Vulnerables por Nitratos del modo que se definen en la Directiva Europea 91/676/EEC. Sin embargo, en el caso de DRASTIC, existen poca correspondencia entre las zonas más vulnerables y las áreas más contaminadas. Esto se debe principalmente a la subestimación de la capacidad de dilución y a al sobre énfasis del potencial de atenuación de la zona no saturada y el acuífero, ya que tanto cloruro como nitrato han probado ser contaminantes muy estables. Al incluir un parámetro del uso de la tierra, SI genera resultados más confiables, aunque en muchas áreas se sobrestima la vulnerabilidad.

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Résumé Lapplication de deux méthodes de calcul de la vulnérabilité permettant dévaluer limpact des activités agricoles sur la qualité des eaux souterraines, est testée dans deux zones du Sud du Portugal, avec des résultats modestes. La citriculture et lhorticulture intensives nécessitent de grandes quantités e fertilisants et deau souterraine pour lirrigation, ce qui induit la salinisation et la contamination des eaux souterraines par les nitrates. Le degré de contamination varie grandement à lintérieur et entre les zones détudes, en fonction des facteurs hydrogéologiques et de lintensité des pratiques agricoles. La cartographie de la vulnérabilité est mise en oeuvre via la méthodologie DRASTIC et lIndex de Susceptibilité (SI) spécifique, qui est une adaptation de la méthode DRASTIC. Ces méthodes êuvent constituer des outils de management des eaux souterraines, par exemple lors de la désignation de nouvelles zones de vulnérabilité aux Nitrates selon la n Directive Européenne 91/676/EEC. Par ailleurs dans le cas de DRASTIC, de petites correspondances existent entre les zones les plus vulnérables et les plus contaminées. Ceci est principalement le résultat dune sous-estimation de la capacité de dilution et de la sur-accentuation du potentiel datténuation de la zone non-saturée de laquifère, car et le chlore et les nitrates sont des contaminants très stables. En incluant un paramètre dutilisation des sols, SI produit des résultats plus réalistes, bien que dans de nombreuses zones la vulnérabilité soit surestimée.