Spatiotemporal changes in cadmium contamination in the Seine estuary (France)

Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd.     

Ingestion of marine debris by loggerhead sea turtles, Caretta caretta, in the Adriatic Sea

We examined the occurrence of marine debris in the gastrointestinal tract of 54 loggerhead sea turtles (Caretta caretta) found stranded or incidentally captured dead by fisheries in the Adriatic Sea, with a curved carapace length of 25.0-79.2 cm. Marine debris was present in 35.2% of turtles and included soft plastic, ropes, Styrofoam and monofilament lines found in 68.4%, 42.1%, 15.8% and 5.3% of loggerheads that have ingested debris, respectively. The dry mass of debris per turtle was low, ranging from <0.01 to 0.71 g, and the ingestion was not significantly affected by sex or body size (all p > 0.05). Marine debris averaged 2.2 ± 8.0% of dry mass of gut content, with a maximum of 35% found in a juvenile turtle that most likely died due to debris ingestion. Considering the relatively high occurrence of debris intake and possible sub-lethal effects of even small quantities of marine debris, this can be an additional factor of concern for loggerheads in the Adriatic Sea.     

Characteristics of sub-daily precipitation extremes in observed data and regional climate model simulations

Theoretical and Applied Climatology - The study compares characteristics of observed sub-daily precipitation extremes in the Czech Republic with those simulated by Hadley Centre Regional Model...     

Biogeochemical behavior of arsenic species in the seine estuary in relation to successive high-amplitude primary production, anoxia, turbidity, and salinity events

Sixty samples were collected in June 1996 at regular intervals within the Seine estuary in France in order to study the arsenic (As) behavior in response to climatic and hydrologic conditions leading to major events in chlorophyll activity, anoxia, turbidity, and salinity. It was determined that arsenate (As5, 15–23 nM) is still the dominant chemical form of dissolved As in the upper, estuary. A concentration of up to 37 nM was observed in the high turbidity zone at the freshwater-seawater interface, presumably a result of pumping and remineralization of plankton particles that develop at salinities >10. The formation of arsenite (As3) was related to two processes: anoxia in the upper estuary and primary production in the superoxygenated, lower estuary. Dimethyl arsenic (DMA) concentrations (0 to 2.2 nM) were not directly correlated with chlorophyll content, but rather with oxygenation rates. Monomethyl arsenic (MMA) concentrations were low. Dissolved organoarsenic concentrations refractory to the formation of volatile hydrides showed high concentrations in the river estuary (1 to 6 nM), and their degradation was probably the cause of DMA and MMA and ultimately of the recycling of dissolved inorganic As. The remineralization of particulate arsenic (AsP) in the high turbidity zone at the freshwater-seawater interface, was apparent once AsP concentrations were normalized with respect to aluminium. This remineralization process, even though it does not exclude the possibility of intra-estuarine As inputs, could account for a major part of the high dissolved total As concentration observed in this specific zone, both in the Seine and other estuaries.     

Holocene palaeohydrological changes in the northern Mediterranean borderlands as reflected by the lake-level record of Lake Ledro,northeastern Italy

A lake-level record of Lake Ledro (northern Italy) spans the entire Holocene with a chronology derived from 51 radiocarbon dates. It is based on a specific sedimentological approach that combines data from five sediment profiles sampled in distinct locations in the littoral zone. On a millennial scale, the lake-level record shows two successive periods from 11,700 to 4500 cal yr BP and from 4500 cal yr BP to the present, characterized by lower and higher average lake levels, respectively. In addition to key seasonal and inter-hemispherical changes in insolation, the major hydrological change around 4500 cal yr BP may be related to a non-linear response of the climate system to orbitally-driven gradual decrease in insolation. The Ledro record questions the notion of an accentuated summer rain regime in the northern Mediterranean borderlands during the boreal insolation maximum. Moreover, the Ledro record highlights that the Holocene was punctuated by successive centennial-scale highstands. Correlations with the Preboreal oscillation and the 8.2 ka event, and comparison with the atmospheric ¹⁴C residual record, suggest that short-lived lake-level fluctuations developed at Ledro in response to (1) final steps of the deglaciation in the North Atlantic area and (2) variations in solar activity.     

Relationships between the North Atlantic Oscillation index and temperatures in Europe in global climate models

The study evaluates relationships between the North Atlantic Oscillation (NAO) index and winter temperatures (including indices of extremes) over Europe in an ensemble of transient simulations of current global climate models (GCMs). We focus on identification of areas in which the NAO index is linked to winter temperatures and temperature extremes in simulations of the recent climate (1961–2000), and evaluate how these relationships change in climate change scenarios for the late 21st century (2071–2100). Most GCMs are able to reproduce main features of the observed links. The NAO index is more important for cold than warm extremes, which is also reproduced by the GCMs. However, all GCMs underestimate the magnitude of the NAO influence on cold extremes when averaged over northern and western Europe. For future scenarios, the links between the NAO and temperatures are mostly analogous to those in the recent climate, except for one GCM (CM3) in which the influence of the NAO on temperature almost disappears over whole Europe. This suggests that future scenarios from this particular GCM should be evaluated with caution. The NAO index is found to represent a useful covariate that explains an important fraction of variability of cold extremes in winter, and its incorporation into extreme value models for daily temperatures (and their possible changes under climate change) may improve performance of these models and reliability of estimates of extremes and their uncertainty.     

Characterization of active fault scarps from LiDAR data: a case study from Central Apennines (Italy)

A high-resolution digital elevation model (DEM, 1 ms spacing) derived from an airborne light detection and ranging (LiDAR) campaign was used in an attempt to characterize the structural and erosive elements of the geometry of the Pettino fault, a seismogenic normal fault in Central Apennines (Italy). Four 90- to 280 m-long fault scarp segments were selected and the surface between the base and the top of the scarps was analyzed through the statistical analysis of the following DEM-derived parameters: altitude, height of the fault scarp, and distance along strike, slope, and aspect. The results identify slopes of up to 40° in faults lower reaches interpreted as fresh faces, 34° up the faces. The Pettino fault maximum long-term slip rate (0.6–1.1 mm/yr) was estimated from the scarp heights, which are up to 12–19 m in the selected four segments, and the age (ca. 18 ka) of the last glacial erosional phase in the area. The combined analysis of the DEM-derived parameters allows us to (a) define aspects of three-dimensional scarp geometry, (b) decipher its geomorphological significance, and (c) estimate the long-term slip rate.     

Climate-change effects on extreme precipitation in central Europe: uncertainties of scenarios based on regional climate models

Observations as well as most climate model simulations are generally in accord with the hypothesis that the hydrologic cycle should intensify and become highly volatile with the greenhouse-gas-induced climate change, although uncertainties of these projections as well as the spatial and seasonal variability of the changes are much larger than for temperature extremes. In this study, we examine scenarios of changes in extreme precipitation events in 24 future climate runs of ten regional climate models, focusing on a specific area of the Czech Republic (central Europe) where complex orography and an interaction of other factors governing the occurrence of heavy precipitation events result in patterns that cannot be captured by global models. The peaks-over-threshold analysis with increasing threshold censoring is applied to estimate multi-year return levels of daily rainfall amounts. Uncertainties in scenarios of changes for the late 21st century related to the inter-model and within-ensemble variability and the use of the SRES-A2 and SRES-B2 greenhouse gas emission scenarios are evaluated. The results show that heavy precipitation events are likely to increase in severity in winter and (with less agreement among models) also in summer. The inter-model and intra-model variability and related uncertainties in the pattern and magnitude of the change is large, but the scenarios tend to agree with precipitation trends recently observed in the area, which may strengthen their credibility. In most scenario runs, the projected change in extreme precipitation in summer is of the opposite sign than a change in mean seasonal totals, the latter pointing towards generally drier conditions in summer. A combination of enhanced heavy precipitation amounts and reduced water infiltration capabilities of a dry soil may severely increase peak river discharges and flood-related risks in this region.