Future changes of the atmospheric composition and the impact of climate change

The development of the future atmospheric chemical composition is investigated with respect to NO _y and O₃ by means of the off‐line coupled dynamic‐chemical general circulation model ECHAM3/CHEM. Two time slice experiments have been performed for the years 1992 and 2015, which include changes in sea surface temperatures, greenhouse gas concentrations, emissions of CFCs, NO _x and other species, i.e., the 2015 simulation accounts for changes in chemically relevant emissions and for a climate change and its impact on air chemistry. The 2015 simulation clearly shows a global increase in ozone except for large areas of the lower stratosphere, where no significant changes or even decreases in the ozone concentration are found. For a better understanding of the importance of (A) emissions like NO _x and CFCs, (B) future changes of air temperature and water vapour concentration, and (C) other dynamical parameters, like precipitation and changes in the circulation, diabatic circulation, stratosphere‐troposphere‐exchange, the simulation of the future atmosphere has been performed stepwise. This method requires a climate‐chemistry model without interactive coupling of chemical species. Model results show that the direct effect of emissions (A) plays a major rôle for the composition of the future atmosphere, but they also clearly show that climate change (B and C) has a significant impact and strongly reduces the NO _y and ozone concentration in the lower stratosphere.     

Soft-bedded subglacial meltwater channel from the Welzow-Süd opencast lignite mine, Lower Lusatia, eastern Germany

An excellent section in the Welzow-Süd open-cast lignite mine in Lower Lusatia, eastern Germany, provided a rare opportunity to study a small (5 m deep), buried subglacial meltwater channel of Saalian age. The channel is steep-sided and distinctly U-shaped. It is separated from undeformed outwash deposits in which it is incised by a sharp erosional contact and it is filled with meltwater sand and till. The till was possibly squeezed into the channel from the adjacent ice/bed interface. Directly beneath the channel, there is a partly truncated diapir of clayey silt, evidencing sediment intrusion into the channel from below. During channel formation, the pressure gradient was oriented from the surrounding sediments into the channel, so that the channel served as a drainage conduit for groundwater from the adjacent subglacial aquifer. The substratum consists largely of sandy aquifers with a total thickness of about 100 m, separated by two aquitards. Channel formation was initiated when hydraulic transmissivity of the bed did not suffice to evacuate all the subglacial meltwater as groundwater flow. As the Welzow-Süd channel belongs to a dense network of subglacial channels in eastern Germany, temporary ice-sheet instability in this region prior to channel formation seems possible.     

Deposit architecture and dynamics of the 2006 block‐and‐ash flows of Merapi Volcano,Java, Indonesia

The internal architecture of the 2006 block‐and‐ash flow deposits of Merapi volcano (Java, Indonesia) was investigated using data collected from 27 stratigraphic sections measured immediately after flow emplacement, and after one and two rainy seasons of erosion. Identification of different depositional units and their longitudinal and lateral facies variations provide detailed information about: (i) the distribution, volumes and sedimentological characteristics of the different units; (ii) flow types and mobility as inferred from associated deposits; and (iii) changes in the dynamics of the different flows and their material during emplacement. Two main types of block‐and‐ash flows (short‐runout to medium‐runout block‐and‐ash flows and long‐runout block‐and‐ash flows) are defined based on flow generation mechanism, flow volume, travel distance, deposit morphology, distribution, lithology and grain‐size distribution. Conceptual models for the transport and depositional mechanisms of these two types of block‐and‐ash flows are presented. Variations in the runout distances observed for short‐runout to medium‐runout block‐and‐ash flows are linked directly to different initial flow volumes, degree of fragmentation and material properties of the moving mass during transport, with the largest and finer grained flows having the greatest mobility. Deposition occurs only over a narrow range of basal inclinations close to the angle of repose for pyroclastic material, indicating that such flows behave in a similar way to granular‐free surface flows on unconfined planes. The flow mechanisms of long‐runout block‐and‐ash flows at Merapi are interpreted to be similar, in many respects, to unsteady, cohesionless grain flows with an inertial flow regime where collisional forces largely overcome frictional forces. Flow unsteadiness causes the main body to be segmented into different pulses that run closer to each other as the flow moves downslope. Deposition occurs stepwise, with rapid aggradation of stacked sub‐units from different parts of the major flow pulses. In such a model, the arrival of each flow pulse front at selected sites in the main river valley controls the generation and development of highly mobile, unconfined pyroclastic flows outside valley regions and their associated overbank deposits.     

Halite cementation and carbonate diagenesis of intra-salt reservoirs from the Late Neoproterozoic to Early Cambrian Ara Group (South Oman Salt Basin)

Late Neoproterozoic to Early Cambrian carbonates of the Ara Group form important intra‐salt ‘stringer’ reservoirs in the South Oman Salt Basin. Differential loading of thick continental clastics above the six carbonate to evaporite cycles of the Ara Group led to the formation of salt diapirs, encasing a predominantly self‐charging hydrocarbon system within partly highly overpressured carbonate bodies (‘stringers’). These carbonates underwent a complex diagenetic evolution, with one stage of halite cementation in a shallow (early) and another in a deep (late) burial environment. Early and late halite cements are defined by their microstructural relationship with solid bitumen. The early phase of halite cementation is post‐dated by solid reservoir bitumen. This phase is most pervasive towards the top of carbonate stringers, where it plugs nearly all available porosity in facies with initially favourable poroperm characteristics. Bromine geochemistry revealed significantly higher bromine contents (up to 280 p.p.m.) in the early halite compared with the late halite (173 p.p.m.). The distribution patterns and the (high) bromine contents of early halite are consistent with precipitation caused by seepage reflux of highly saturated brines during deposition of the overlying rock salt interval. Later in burial history, relatively small quantities of early halite were dissolved locally and re‐precipitated as indicated by inclusions of streaky solid bitumen within the late halite cements. Late halite cement also seals fractures which show evidence for repeated reopening. Initially, these fractures formed during a period of hydrothermal activity and were later reopened by a crack‐seal mechanism caused by high fluid overpressures. Porosity plugging by early halite cements affects the poroperm characteristics of the Ara carbonates much more than the volumetrically less important late halite cement. The formation mechanisms and distribution patterns of halite cementation processes in the South Oman Salt Basin can be generalized to other petroliferous evaporite basins.     

The Gronnedal-Ika Carbonatite-Syenite Complex, South Greenland: Carbonatite Formation by Liquid Immiscibility

The Grønnedal-Ika complex is dominated by layered nephelinesyenites which were intruded by a xenolithic syenite and a centralplug of calcite to calcite–siderite carbonatite. Aegirine–augite,alkali feldspar and nepheline are the major mineral phases inthe syenites, along with rare calcite. Temperatures of 680–910°Cand silica activities of 0·28–0·43 weredetermined for the crystallization of the syenites on the basisof mineral equilibria. Oxygen fugacities, estimated using titanomagnetitecompositions, were between 2 and 5 log units above the fayalite–magnetite–quartzbuffer during the magmatic stage. Chondrite-normalized REE patternsof magmatic calcite in both carbonatites and syenites are characterizedby REE enrichment (La_CN–Yb_CN = 10–70). Calcite fromthe carbonatites has higher Ba (5490 ppm) and lower HREE concentrationsthan calcite from the syenites (54–106 ppm Ba). This isconsistent with the behavior of these elements during separationof immiscible silicate–carbonate liquid pairs. _Nd(T =1·30 Ga) values of clinopyroxenes from the syenites varybetween +1·8 and +2·8, and _Nd(T) values of whole-rockcarbonatites range from +2·4 to +2·8. Calcitefrom the carbonatites has ¹⁸O values of 7·8 to 8·6and ¹³C values of –3·9 to –4·6. ¹⁸Ovalues of clinopyroxene separates from the nepheline syenitesrange between 4·2 and 4·9. The average oxygenisotopic composition of the nepheline syenitic melt was calculatedbased on known rock–water and mineral–water isotopefractionation to be 5·7 ± 0·4. Nd and C–Oisotope compositions are typical for mantle-derived rocks anddo not indicate significant crustal assimilation for eithersyenite or carbonatite magmas. The difference in ¹⁸O betweencalculated syenitic melts and carbonatites, and the overlapin _Nd values between carbonatites and syenites, are consistentwith derivation of the carbonatites from the syenites via liquidimmiscibility. KEY WORDS: alkaline magmatism; carbonatite; Gardar Province; liquid immiscibility; nepheline syenite     

Shell gravel deposits on the Åland Islands, southwestern Finland, with special reference to the molluscan assemblages

Twenty-six shell gravel sites at elevations between 3 and 35 m a.s.l. were found on the Aland Islands. The faunal composition was determined on 14 of these locations and Mytilus edulis and Macoma balthica were found everywhere. Another common species was Hydrobia ulvae , while H. ventrosa , Littorina saxatilis and Cerastoderma glaucum were more sporadic. This species assemblage implies that the salinity of the area was about 10‰ when the animals lived there. The deposits on the N-NE hilltops generally have southerly to westerly aspects, while those of the south-central hilltops are easterly. On the basis of a 14 C-dated stratified deposit it is suggested that each deposit was formed during a relatively short period of time. As a hilltop emerged from the sea, glacial debris was flushed down. Shell-bearing molluscs colonized the bare rock surface and were flushed down and formed the shell gravel deposit as the shoreline displacement continued. At a later stage, as the more concave part of the hilltop was subject to wave action, erosion was weaker and the shell gravel deposit was covered by beach sand. Since the hills may be of different elevation, it is concluded that trying to date ancient shorelines from shell gravel deposits is not justified, as each deposit originates from the hill with which it is associated.