Geochemical Evidence for Subduction Fluxes, Mantle Melting and Fractional Crystallization Beneath the South Sandwich Island Arc

The volcanoes of the South Sandwich island arc follow threedistinct series: low-K tholeiitic (followed by Zavodovski, Candlemas,Vindication, Montagu and Bristol), tholeiitic (followed by Visokoi,Saunders and Bellinghausen) and calcalkaline (followed by Leskov,Freehand and part of Cook and Thule). Flux calculations indicatethat the percentage contribution of the subduction componentto the mantle source of all three series varies from undetectable(e.g. Zr) through small (e.g. Nd=20%) and moderate (e.g. La,Ce, Sr=50–80%) to dominant (e.g. Pb, K, Ba, Rb, Cs >90%)with little change along the arc. Isotope systematics (Pb, Nd,Sr) show that this subduction component obtains a greater contributionfrom altered oceanic crust than from pelagic sediment. Elementsfor which the subduction contribution is small show that themantle is already depleted relative to N-MORB mantle (equivalentto loss of an 2•5% melt fraction) before melting beneaththe arc. After addition of the subduction component, dynamicmelting of this depleted mantle then causes the variations inK that distinguish the three series. The estimated degree ofpartial melting (20%) is slightly greater than that beneathocean ridges, though geothermometry suggests that the primarymagma temperature (1225C) is similar to that of primary MORB.About half of the melting may be attributed to volatile addition,and half to decompression. Dynamic melting involving three-dimensional,two-phase flow may be needed to explain fully the inter-islandvariations. KEY WORDS: geochemistry; petrology; fluxes; melting; subduction ^*Corresponding author     

Initiation of Subduction Zones as a Consequence of Lateral Compositional Buoyancy Contrast within the Lithosphere: a Petrological Perspective

Tonga and Mariana fore-arc peridotites, inferred to representtheir respective sub-arc mantle lithospheres, are compositionallyhighly depleted (low Fe/Mg) and thus physically buoyant relativeto abyssal peridotites representing normal oceanic lithosphere(high Fe/Mg) formed at ocean ridges. The observation that thedepletion of these fore-arc lithospheres is unrelated to, andpre-dates, the inception of present-day western Pacific subductionzones demonstrates the pre-existence of compositional buoyancycontrast at the sites of these subduction zones. These observationsallow us to suggest that lateral compositional buoyancy contrastwithin the oceanic lithosphere creates the favoured and necessarycondition for subduction initiation. Edges of buoyant oceanicplateaux, for example, mark a compositional buoyancy contrastwithin the oceanic lithosphere. These edges under deviatoriccompression (e.g. ridge push) could develop reverse faults withcombined forces in excess of the oceanic lithosphere strength,allowing the dense normal oceanic lithosphere to sink into theasthenosphere beneath the buoyant overriding oceanic plateaux,i.e. the initiation of subduction zones. We term this conceptthe ‘oceanic plateau model’. This model explainsmany other observations and offers testable hypotheses on importantgeodynamic problems on a global scale. These include (1) theorigin of the 43 Ma bend along the Hawaii–Emperor SeamountChain in the Pacific, (2) mechanisms of ophiolite emplacement,(3) continental accretion, etc. Subduction initiation is notunique to oceanic plateaux, but the plateau model well illustratesthe importance of the compositional buoyancy contrast withinthe lithosphere for subduction initiation. Most portions ofpassive continental margins, such as in the Atlantic where largecompositional buoyancy contrast exists, are the loci of futuresubduction zones. KEY WORDS: subduction initiation; compositional buoyancy contrast; oceanic lithosphere; plate tectonics; mantle plumes; hotspots; oceanic plateaux; passive continental margins; continental accretion; mantle peridotites; ophiolites     

U-series Isotope Data on Lau Basin Glasses: the Role of Subduction-related Fluids during Melt Generation in Back-arc Basins

New thermal ionization mass spectrometry U-series disequilibriumdata are presented for 24 basaltic to dacitic glasses from activespreading centres in the back-arc Lau Basin (SW Pacific), togetherwith additional inductively coupled plasma mass spectrometrytrace element analyses and Sr–Nd–Pb isotope data.Valu Fa Ridge samples, adjacent to the arc front, have highU/Th and (²³⁰Th/²³⁸U) <1, implying a recent (<<350ka) addition of a U-rich slab-derived fluid. The Valu Fa datacan be combined with existing ²³⁰Th–²³⁸U data for theCentral Tonga arc to infer a fluid addition event at     

Chemical Variations in the Palisade Sill

Walker (1940) considered that the chemical data of the differentiatedPalisade sill could not be treated in variation diagrams becauseof the narrow range of SiO² weight per cent. The present workexamines the same data using a recent graphical technique whichis not subject to such limitations. The results show that thechemical variation is almost exactly that required by crystalfractionation of olivine and pyroxene from a single, relativelyhomogeneous, parent magma. Most other hypotheses of differentationare either unnecessary or not in accordance with the chemicaldata. Generally, the results confirm Walker's earlier conclusionswhich were based mainly on petrography ansd field relations.     

Mantle Preconditioning by Melt Extraction during Flow: Theory and Petrogenetic Implications

Mantle preconditioning may be defined as the extraction of smallmelt fractions from mantle asthenosphere during its flow tothe site of magma generation. Equations may be written for mantlepreconditioning, assuming that the mantle comprises enriched‘plums’ in a depleted matrix. The equations takeinto account variations in mass fraction of plums, the relativerate of melting of plums and matrix, the temperature and pressureof melt extraction, the mass fraction of melt extracted, theextent of chemical exchange between plums and matrix, and theefficiency of melt extraction. Monitoring mineralogical changesand variations in partition coefficients along the inferredP–T–t path of the mantle asthenosphere allows theequations to be correctly applied to the conditions under whichmelt extraction takes place. Numerical experiments demonstratethe influence of petrogenetic variables on the shape of meltextraction trajectories and provide new criteria for distinguishingbetween melt extraction and mixing as the cause of regionalgeochemical gradients. Representative examples of arc–back-arcsystems (Scotia), continental break-up (Afar) and plume–ridgeinteraction (Azores) indicate that the compositions of the mantlesources of mid-ocean ridge basalts and island arc basalts maybe determined, at least in part, by the melt extraction historiesof their asthenospheric sources. KEY WORDS: geochemical modelling; mantle flow; isotope ratios; trace elements     

40Ar/ 39Ar and K–Ar geochronological age constraints for the inception and early evolution of the Izu–Bonin – Mariana arc system

K–Ar and ⁴⁰Ar/³⁹Ar dates are presented for locations in the Izu–Bonin – Mariana (IBM) forearc (Ocean Drilling Program (ODP) sites 786 & 782, Chichijima, Deep Sea Drilling Program (DSDP) sites 458 & 459, Saipan), and Palau on the remnant arc of the Kyushu–Palau Ridge. For a number of these locations, the ⁴⁰Ar/³⁹Ar plateau and ³⁶Ar/⁴⁰Ar versus ³⁹Ar/⁴⁰Ar isochrons give older ages than the K–Ar results. The most important results are: (i) at site 786, initial construction of the proto-IBM (now forearc) basement occurred at least by ca 47–45 Ma, consistent with the age of the immediately overlying sediments (middle Eocene nannofossil Zone CP13c); the younger pulse of construction dated at ca 35 Ma by K–Ar could not be confirmed by ⁴⁰Ar/³⁹Ar analysis; (ii) ⁴⁰Ar/³⁹Ar ages for the initial construction of the Mariana portion of the IBM system are as old as those of the Izu–Bonin portion, for example at site 458, initial construction commenced at least by ca 49 Ma and at ca 47 Ma at Saipan (Sankakayuma Formation); and (iii) a combination of K–Ar and ⁴⁰Ar/³⁹Ar ages indicate continued boninite magmatism in the Izu–Bonin forearc (and remnant arc at Palau) until ca 35 Ma. Subduction inception including boninite series rocks along most of the exposed length of the IBM system, clearly preceded by some 5 million years the Middle Eocene (ca 43.5 Ma) change in Pacific plate motion. Boninitic series magmatism persisted at locations now exposed in the forearc for ～ 15 million years after arc inception concurrently with low-K tholeiitic series eruptions from a subaerial arc system, established at ≥ 40 Ma, on the Kyushu–Palau Ridge. For the Mariana portion of the IBM system, reconstruction of the proto-arc places this activity adjacent to the concurrent but orthogonally spreading Central Basin Ridge of the West Philippine Basin. It is possible that a combination of subduction of a young North New Guinea Plate beneath newly created back-arc basin crust may account for some of the features of the Mariana system. It is clear, however, that the understanding of the processes of subduction initiation and early IBM arc development is incomplete.     

Nature of the Source Regions for Post-collisional, Potassic Magmatism in Southern and Northern Tibet from Geochemical Variations and Inverse Trace Element Modelling

Neogene potassic lavas in northern and southern Tibet have differentisotopic (     

Modelling grain‐recycling zoning during metamorphism

Chemical zoning, recorded by grain growth during metamorphism, is a key source of information about P–T–t paths. Interpretation of these data must be carried out using appropriate models and recognizing their inherent assumptions. To assist with defining how zoned minerals form, a set of geometric criteria for three types of chemical zoning developed in minerals (diffusion, growth and grain recycling) is outlined. Re‐equilibration of minerals by lattice diffusion causes zoning if the re‐equilibration is incomplete. Growth of porphyroblasts is commonly considered in pelites, but in metagranitoids, large monophase domains undergo coarsening by recycling of material from one grain to another as grain boundaries migrate driven by surface energy. This type of grain size increase is termed here ‘grain recycling’. Zoning developed during grain recycling due to equilibration of the recycled material with grain‐boundary chemistry is termed ‘grain‐recycling zoning’. Furthermore, short lattice diffusion lengths relative to grain sizes cause metamorphic fractionation because material in the grain cores is not in communication thermodynamically with the rest of the rock. A new model is derived for this sort of grain size increase coupled with metamorphic reactions using Theriak–Domino. An example is given of plagioclase undergoing an increase in anorthite content as epidote breaks down during amphibolite facies metamorphism of a metagranitoid. Agreement between naturally occurring zoning profiles and those derived from modelled P–T–t paths shows that this model can be used to extract metamorphic conditions from rocks which are not accessible using conventional thermobarometry.