Liquid bridge contribution to shear behavior of unsaturated soil: modeling and application to a micromechanics model

Acta Geotechnica - Liquid bridges in unsaturated soils attach to grain contacts and contribute to strengthening microscopic bonding forces, which leads to macroscopic high strength and stiffness...     

Mechanisms of iron oxide transformations in hydrothermal systems

Coexistence of magnetite and hematite in hydrothermal systems has often been used to constrain the redox potential of fluids, assuming that the redox equilibrium is attained among all minerals and aqueous species. However, as temperature decreases, disequilibrium mineral assemblages may occur due to the slow kinetics of reaction involving the minerals and fluids. In this study, we conducted a series of experiments in which hematite or magnetite was reacted with an acidic solution under H₂-rich hydrothermal conditions (T = 100-250 °C, ) to investigate the kinetics of redox and non-redox transformations between hematite and magnetite, and the mechanisms of iron oxide transformation under hydrothermal conditions. The formation of euhedral crystals of hematite in 150 and 200 °C experiments, in which magnetite was used as the starting material, indicates that non-redox transformation of magnetite to hematite occurred within 24 h. The chemical composition of the experimental solutions was controlled by the non-redox transformation between magnetite and hematite throughout the experiments. While solution compositions were controlled by the non-redox transformation in the first 3 days in a 250 °C experiment, reductive dissolution of magnetite became important after 5 days and affected the solution chemistry. At 100 °C, the presence of maghemite was indicated in the first 7 days. Based on these results, equilibrium constants of non-redox transformation between magnetite and hematite and those of non-redox transformation between magnetite and maghemite were calculated. Our results suggest that the redox transformation of hematite to magnetite occurs in the following steps: (1) reductive dissolution of hematite to and (2) non-redox transformation of hematite and to magnetite.     

Magma source transition of lunar mare volcanism at 2.3 Ga

Mare basalts provide insights into the composition and thermal history of the lunar mantle. The ages of mare basalts suggest a first peak of magma activity at 3.2–3.8 Ga and a second peak at ~2 Ga. In this study, we reassess the correlation between the titanium contents and the eruption ages of mare basalt units using the compositional and chronological data updated by SELENE (Kaguya). Using morphological and geological criteria, we calculated the titanium content of 261 mare units across a representative area of each mare unit. In the Procellarum KREEP Terrane, where the latest eruptions are located, an increase in the mean titanium content is observed during the Eratosthenian period, as reported by previous studies. We found that the increase in the mean titanium content occurred within a relatively short period near approximately 2.3 Ga, suggesting that the magma source of the mare basalts changed at this particular age. Moreover, the high‐titanium basaltic eruptions are correlated with a second peak in volcanic activity near ~2 Ga. The high‐titanium basaltic eruptions occurring during the last volcanic activity period can be explained by the three possible scenarios (1) the ilmenite‐bearing cumulate rich layer in the core‐mantle boundary formed after the mantle overturn, (2) the basaltic material layers beneath the lunar crust formed through upwelling magmas, and (3) ilmenite‐bearing cumulate blocks remained in the upper mantle after the mantle overturn.     

A basic study on the application of LRFD in “the technical standard for port and harbour facilities in Japan”: a case of gravity type quay wall in a persistent design situation

ABSTRACT

The Partial Factor Method (PFM) based on the Level 1 reliability design method was introduced in 2007 to the Technical Standards for Port and Harbour Facilities (TSPHF-2007) in Japan. After nearly 10 years of practical use of TSPHF-2007, the design standard has been revised based on requests from the practitioners who recommend the transition from the PFM to the Load Resistance Factor Design (LRFD). In this paper, we discuss the setting method of the target failure probability to determine the partial factors based on code calibration. Furthermore, we examine the impacts of implementing the LRFD concept to the TSPHF by taking the sliding and overturning of a gravity type quay wall as an example to represent port and harbour facilities. We found no practical difference in caisson width derived using the LRFD and the PFM, whereas the degree of matching of the target failure probability was somewhat more precise for the PFM. This finding indicates that the LRFD is a more reasonable design method than the PFM in terms of the simplicity of the performance function itself and the ease of engineering interpretation during the design procedure.     

The use of a water mass curtain to control fish behavior for marine ranching

A practical method is described of initiating a water mass curtain (a jet flow of water partitioning another body of water) to be used to control fish movements, along with its theoretical analysis. In this paper, equations to evaluate the change of density and upward flow rates in a water curtain due to entrainment are presented, and the accuracy of the equations is verified experimentally. The discontinuity of the density on the boundary between jet and ambient fluid was assumed in the analysis, since our experiments showed that the instantaneous density distribution was discontinuous. The equations are much simpler than the conventional formulae deduced by assuming a Gaussian curve, and are amenable to practical usage. The control efficiency of the water curtain is very good for young red sea bream.     

Geochemical characteristics of ores and surface waters for environmental risk assessment in the Pinpet iron deposit,southern Shan State,Myanmar

Mining operations in the Pinpet Fe deposit, which is the second‐largest Fe deposit in Myanmar, are currently suspended, in part because of possible contamination of heavy metals and hazardous elements (e.g., Fe, As, Cu, Zn, and U) into the surrounding aquatic environment and associated public concern. However, a scientific investigation of the source and degree of contamination in streams near the deposit has not yet been conducted. Therefore, we quantified heavy‐metal and hazardous‐element concentrations of stream waters and sediments in stream beds, and measured the speciation and concentration of these metals in deposit Fe ores using the sequential extraction method, to better understand the influence of mining activities on the surrounding environment. Geochemical results for Nan‐tank‐pauk stream and its tributaries indicate that the chemical compositions of their waters are controlled by carbonate bedrock and that no detectable contamination has occurred as a result of mining activity or hematite and limonite ore beneficiation processes in either the wet or dry seasons. All measured heavy‐metal and hazardous‐element concentrations were below the World Health Organization standards for drinking water and the proposed national drinking water quality standards in Myanmar. Bulk chemical compositions of stream‐bed and tailings dam sediments show that As, Zn, and Cu concentrations are similar to those in uncontaminated sediments. Results of bulk mineralogical and chemical analyses of ore samples reveal that some limonite ore samples contain substantial amounts of As (up to 2 wt%). However, sequential extraction results indicate that most (>90%) of the As in these As‐rich ores is hosted in insoluble fractions (e.g., crystalline Fe hydroxides and clays). Therefore, arsenic is unlikely to be released into the aquatic environment by interacting with water during ore beneficiation processes should the mine resume operations.