The influence of mussel beds on nutrients in the Western Wadden Sea and Eastern Scheldt estuaries

The uptake and release of materials by intertidal mussel beds were directly measured in two cultivated Dutch estuaries. Generally, chlorophylla, seston, and particulate organic carbon were taken up, while ammonium, orthophosphate, and silicate were released. The observed rates were higher than values computed from organismic observations and similar to those observed for intertidal oyster reefs in South Carolina. Specific estuarine material turnover rates varied from 1 week to 38 weeks when calculated with mussel bed fluxes. The fastest turnover rates were for chlorophylla and ammonium. These results support the idea that dense assemblages of bivalves are major components in the recycling of nutrients in estuaries.     

Assessment of sandstone deterioration at Ta Keo temple (Angkor): first results and future prospects

A first application of geomorphological methods to the assessment of sandstone deterioration at Angkor is presented. Damage diagnosis was carried out on the first eastern tier of the central pyramid of the 1,000 year-old Ta Keo temple. Methods combine field observations and measurements at 230 sampling points, high-resolution lasergrammetry and stereophotogrammetry on a 2-m² test zone, and SEM observations. The first results indicate that decay operates through a synergistic combination of weathering phenomena dominated by scaling and solution, and exhibits a high spatial variability. Percentages of deteriorated surfaces vary from 17.6 to 93.8%, and average stone recession values from 0.00 to 2.71 cm (minimum) and 0.34 to 5.49 cm (maximum). On the test-zone, stereophotogrammetry and 3D-mapping of the present and reconstructed initial states using lasergrammetry indicate that erosion scars up to 6 cm deep have formed since 1963. On the whole, the amount of deteriorated surfaces more than tripled between 1963 and 2008. The degree of implication of salts in stone decay remains unclear for most efflorescences are composed of calcite (CaCO3), with secondary importance of barite (BaSO4) and gypsum (CaSO₄·2H₂O). Future prospects aim to evaluate the impact on stone decay of the clearing out of the temple from the forest in the 1920s.     

Prolonged Magmatic and Tectonic Development of the Caribbean Igneous Province Revealed by a Diving Submersible Survey

Using the diving submersible survey NAUTICA we investigated the central part of the Caribbean large igneous province (CLIP) to observe and sample internal portions of this proposed oceanic plateau. Most of the samples are gabbroic and doleritic rocks; basalts are scarce. Radiometric dating by ⁴⁰Ar/³⁹Ar incremental heating experiments indicate that the intrusive rocks are Campanian in age (81–75 Ma). In some places these intrusive rocks underlie older Santonian (85–83 Ma) extrusive basaltic rocks, suggesting that the Campanian rocks represent a sill injection and an underplating episode. Results of the diving program supplemented by information from ODP and DSDP drilling sites document a 20 m.y. period (94–75 Ma) of igneous activity in the submerged portion of the Caribbean large igneous province (CLIP). In the northern part of the Beata Ridge late Campanian and/or post Campanian uplift is documented by prominent Maastrichtian (71–65 Ma) erosion and the establishment of a Paleocene-middle Eocene (65–49 Ma) carbonate platform. During and after the uplift an extensional period is indicated by seismic images and the subsidence (3 km depth) of the carbonate platform. Paleocene ages (55–56 Ma) determined on some volcanic samples are attributed to localised decompression mantle melting that accompanied the extension. We document a prolonged period of magmatic and tectonic events that do not fit with the current models of short-lived plateau formation during mantle plume initiation but shares many similarities with the constructional histories of other oceanic large igneous provinces.     

Solar noise storms coordinated observations: May 16–24, 1981

We present the main results obtained from the coordinated observations of solar radio noise storms organized by C.E.S.R.A. in May 1981. They concern the structure and polarization of radio sources, and the relation with the photospheric magnetic field. A model of coronal magnetic field, accounting for the observations, is briefly discussed.     

Evidence of large scale diverging paths in the solar corona for type III bursts exciters

On 1 July 1971, about ten groups of type III bursts were observed with high time resolution (10^?1 sec) with the 169 MHz Nançay radioheliograph. Each group consists of two or several bursts, appearing successively from E to W in all cases, with very short delays. The analysis of successive E-W profiles allowed us to show that, for each event:

1. the delay between maximum times of the sources was in the range 0.3–0.8 s and that their time profiles were very similar.
2. the mutual distance between sources was ～1.5 × 10⁵ km.

Explanations by simultaneous emission at the fundamental and harmonic of the local plasma frequency, or by reflexion of electromagnetic radiations at boundary at a dense region are shown to be inconsistent with the observations. We suggest that distinct exciters are simultaneously accelerated at low levels in very close regions and propagate upward along very widely diverging magnetic field lines. This divergence could be related to the existence of large scale magnetic connexions in the corona as revealed by XUV observations. We stress the point that this kind of structure in type III bursts groups, visible only with high time resolution, may have led in the past to erroneous conclusions concerning diameter and decay time of type III bursts because of both spatial and temporal overlapping.     

Characterization of a major refractory component of marine dissolved organic matter

Refractory carboxyl-rich alicyclic molecules (CRAM) are characterized in marine dissolved organic matter (DOM) using nuclear magnetic resonance spectroscopy and ultrahigh resolution mass spectrometry. CRAM are distributed throughout the water column and are the most abundant components of deep ocean DOM ever characterized. CRAM are comprised of a complex mixture of carboxylated and fused alicyclic structures with a carboxyl-C:aliphatic-C ratio of 1:2 to 1:7. CRAM are expected to constitute a strong ligand for metal binding, and multiple coordination across cations could promote aggregation and marine gel formation thereby affecting CRAM reactivity and the bioavailability of nutrients and trace metals. It appears CRAM are ultimately derived from biomolecules with structural similarities to sterols and hopanoids. The occurrence of CRAM in freshwater and terrestrial environments seems likely, considering the global distribution of biomolecules and the similarities of biogeochemical processes among environments.     

Probability Density Functions as Botanical-Climatological Transfer Functions for Climate Reconstruction

We present a new procedure, the pdf method (pdf=probability density function), for reconstructing Quaternary climate utilizing botanical data. The procedure includes the advantages of the indicator species method by considering the fossil and modern presence and absence of taxa rather than their frequencies, thus avoiding the need for modern analog plant communities. Overcoming the problematic use of absolute limits to describe climate response ranges is the main progress of the pdf method in comparison to the indicator species method. This advantage results from estimating probability density functions (pdfs) for monthly mean January and July temperature conditional on the present day occurrence of single taxa. Gaussian distributions sufficiently approximate pdfs of many, although not all, studied taxa. On the assumption of statistical independence, the procedure calculates a joint pdf as the product of the pdfs of the individual taxa. This algorithm weights each taxon according to the extent of its climate response range expressed by its covariance structure. We interpret the maximum of the resulting pdf as the most likely climate and its confidence interval as the uncertainty range. To avoid an artificial reduction of uncertainty arising from the use of numerous similar pdfs, a preselection method is proposed based on the Mahalanobis distance between pdfs. The pdf method was applied to the Carpinus phase of a profile from Gröbern, Germany, that spans the last interglaciation (Eemian). The reconstructed most probable January and July temperatures of about 0.0°C and 18.4°C barely differ from the modern values of −0.5°C and 18.3°C.     

A new technique for precise uranium-series dating of travertine micro-samples

Secondary carbonate formations, such as travertine and calcareous tufa deposits, are important archives for quaternary continental climate studies and archaeology. The extremely complex growth mechanisms result in some serious problems for precise mass spectrometric uranium-series dating. Often, detrital and organic particles contaminate the carbonate and large pore volumes yield a great potential for open system behavior. We utilized microscopic, mineralogical and geochemical methods prior to sample selection to determine the abundance of primary calcite, i.e. micrite and spar. Furthermore, the state of alteration was characterized by cathodoluminescence and trace-element analysis. We conclude that travertine and calcareous tufa are appropriate for precise U-series age determination if a) micrite and/or spar are the dominant phases; b) cathodoluminescence of both phases is weak or absent; c) Fe and Al levels are low; and d) Sr concentrations are close to the average of the studied site. We mapped and sampled solely areas of major micrite/spar abundance having minor alteration for accurate U-series dating. When this new method was applied, travertines located in eastern Germany (sites Bad Langensalza, Burgtonna and Weimar-Ehringsdorf) gave single ²³⁰Th/²³⁸U-ages consistent with the lithological growth sequence and greatly improved compared to previously published chronologies. In addition, we determined ²³⁰Th/U isochron ages on bulk samples that confirm our single ages. In contrast to primary calcite, pore cements are homogeneously distributed throughout the travertine fabric and reflect early diagenetic processes and/or weathering.