Regional distribution pattern of groundwater heavy metals resulting from agricultural activities

Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km² between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004. The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However, the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants.     

Hydrogeological assessment of the Tabarteh fault zone by physicochemical analysis and multivariate statistical methods

Hydrogeologically, faults may impede, conduit, exert no influence, or may play a combination of these roles on groundwater flow. The object of this paper is to study the hydrogeological role of the Tabarteh fault, which is located on the border of Zagros and Central Iran tectonic zones in an alluvial aquifer. The recorded data of water table levels, chemical parameters, and discharge rate of wells, in addition to geological maps and geophysical results, were collected and evaluated. The outcrop of travertine in limited areas and the emergence of a few small springs within the alluvium show a barrier role of the fault in the groundwater flow. The spatial analysis of chemical components, head time series, and groundwater flow direction assessment demonstrated that the fault acts as both a barrier and a non-barrier in different sections. The multivariate statistical methods of cluster and discriminant analyses also confirm the dual role of the fault.     

Local site effect of a clay site in Shiraz based on seismic hazard of Shiraz Plain

Propagation of seismic waves through soil layers would drastically change the frequency content and amplitude-based features of ground motions at the surface. These alterations are known as seismic site effects. Computation of site effects of high-populated areas such as large cities is of great importance (e.g., it is used in development of seismic microzonation of a region). Shiraz is one of the most populous cities of Iran and is located in a high seismic hazardous region. A representative clay site in this city is selected to assess local site effects. The time series and random vibration theory procedure in the frequency domain are implemented to analyze the aforementioned site. Furthermore, the nonlinear dynamic soil behavior is simulated by the equivalent linear method and the nonlinear method via DEEPSOIL program. Three types of soil column uncertainties such as shear wave velocity, modulus reduction, and damping ratio of soil layers as well as depth of underlying rock half-space (D _bed) are considered herein. The mean amplification and standard deviation of natural logarithm of amplification factors are computed for a variety of analysis types. The results of the current study show that the computed mean and standard deviation of amplification factor in ln units by considering only V _S uncertainty are in good agreement with the corresponding ones by considering V _S and modulus reduction and damping ratio variabilities simultaneously for the studied site. Furthermore, it seems that the effect of bedrock depth in definition of spectral shapes of the Iranian seismic building code should be taken into account.     

Petrogenesis of post-collisional A-type granitoids from the Urumieh–Dokhtar magmatic assemblage,Southwestern Kerman,Iran: Constraints on the Arabian–Eurasian continental collision

Three plutons (Deh-Siahan, Bande-Bagh and Baghe-Khoshk Sharghi, collectively referred to as the DBB hereafter) in southwestern Kerman, in the southeastern part of the Urumieh–Dokhtar magmatic assemblage (UDMA) of the Zagros orogenic belt differ from the typical calc-alkaline metaluminous, I-type intrusions of the region. The DBB intrusions have a distinct lithological assemblage varying from diorite through monzogranite and monzonite to alkali feldspar syenite and alkali granite. The DBB granitoids are metaluminous to slightly peraluminous, alkaline to shoshonitic in composition and have high total alkali contents with K₂O > Na₂O, high FeO_T/MgO values, and low CaO and MgO contents. They are enriched in some LILEs (such as Rb and Th) and HFSEs (such as Zr, Y and REEs except Eu) and depleted in Sr and Ba relative to primordial mantle, and have low concentrations of transitional metals. These features along with various geochemical discriminant diagrams suggest that the DBB granitoids are post-collisional A-type granitoids, which had not been recognized previously in the UDMA. The chondrite-normalized REE patterns of the DBB granitoids show slightly enriched light REEs [(La/Sm)_N = 2.26–4.13], negative Eu anomalies [(Eu/Eu*)_N = 0.19–0.74] and flat heavy REE patterns [(Gd/Yb)_N = 0.80–1.87]. The negative Eu anomaly indicates an important role for plagioclase and/or K-feldspar during fractional crystallization. Whole-rock Rb–Sr isotope analysis yields an isochron age of 33 ± 1 Ma with an initial ⁸⁷Sr/⁸⁶Sr value of 0.7049 ± 0.0001. Whole-rock Sm–Nd isotope analysis gives ε_Nd^t values from + 2.56 to + 3.62 at 33 Ma. The positive ε_Nd^t and low I_Sr values of the DBB granitoids together with their T_DM of 0.6–0.7 Ga suggest their formation from partial melting of a lithospheric mantle source, modified by fluids or melts from earlier subduction processes. Melting of lithospheric mantle occurred via a dehydration melting process at pressures below the garnet stability field, as a consequence of lithospheric mantle delamination or break-off of a subducted slab and melting of the lithospheric mantle by upwelling of hot asthenosphere. On the basis of Rb/Sr age dating and the post-collisional geochemical signatures of the DBB granitoids, along with extensive pre-collisional volcanic eruptions in Middle Eocene, we suggest Late Eocene for the time of collision between the Arabian and Central Iranian plates. This also implies that the calc-alkaline I-type intrusions in the southwestern Kerman and in other parts of the UDMA may have formed in a post-collisional context.     

Extraction of velocity pulses of pulse-like ground motions using empirical Fourier decomposition

Journal of Seismology - Pulse-like ground motions may have only a distinct strong pulse or multiple pulses within the velocity time-history. These intrinsic pulses are hidden in low-frequency...     

Probabilistic analysis of soil‐structure interaction effects on the seismic performance of structures

This paper revisits the phenomenon of dynamic soil‐structure interaction (SSI) with a probabilistic approach. For this purpose, a twofold objective is pursued. First, the effect of SSI on inelastic response of the structure is studied considering the prevailing uncertainties. Second, the consequence of practicing SSI provisions of the current seismic design codes on the structural performance is investigated in a probabilistic framework. The soil‐structure system is modeled by the sub‐structure method. The uncertainty in the properties of the soil and the structure is described by random variables that are input to this model. Monte Carlo sampling analysis is employed to compute the probability distribution of the ductility demand of the structure, which is selected as the metrics for the structural performance. In each sample, a randomly generated soil‐structure system is subjected to a randomly selected and scaled ground motion. To comprehensively model the uncertainty in the ground motion, a suite of 3269 records is employed. An extensive parametric study is conducted to cover a wide range of soil‐structure systems. The results reveal the probability that SSI increases the ductility demand of structures designed based on the conventional fixed‐based assumption but built on flexible soil in reality. The results also show it is highly probable that practicing SSI provisions of modern seismic codes increase the ductility demand of the structure. Copyright © 2016 John Wiley & Sons, Ltd.     

Artificial recharge efficiency assessment by soil water balance and modelling approaches in a multi-layered vadose zone in a dry region

To assess recharge through floodwater spreading, three wells, approx. 30 m deep, were dug in a 35-year-old basin in southern Iran. Hydraulic parameters of the layers were measured. One well was equipped with pre-calibrated time domain reflectometry (TDR) sensors. The soil moisture was measured continuously before and after events. Rainfall, ponding depth and the duration of the flooding events were also measured. Recharge was assessed by the soil water balance method, and by calibrated (inverse solution) HYDRUS-1D. The results show that the 15 wetting front was interrupted at a layer with fine soil accumulation over a coarse layer at the depth of approx. 4 m. This seemed to occur due to fingering flow. Estimation of recharge by the soil water balance and modelling approaches showed a downward water flux of 55 and 57% of impounded floodwater, respectively.     

Factors associated with unnecessary requests for an ambulance by non-traumatic patients after the acute earthquake responding phase: a qualitative content analysis

The pre-hospital emergency staff played a key role in transferring the injured patients to health centers. Usually, they reported changes in their decisions on the transfer of non-traumatic patients to hospitals. So, this study was aimed to explore the reasons for unnecessarily requesting an ambulance by non-traumatic patients after the acute responding-to-earthquake phase. This study was a qualitative study that data were analyzed by content analysis approach. Participants were eleven pre-hospital emergency technicians. Data were collected by three sessions of focus group discussion. Data analysis was led to emergence of a main theme: “feeling urgency due to turmoil and uncertainty.” This theme illustrates the basic approach of the inhabitants of the earthquake-stricken region when unnecessarily requesting an ambulance. This theme was derived from two main categories of “turbulent and uncertain conditions” and “psychological turmoil.” The category of “turbulent and uncertain conditions” was comprised of three subcategories: “unreliable care,” “inadequate facilities” and “turbulent living conditions.” The category of “psychological turmoil” was comprised of three subcategories: “psychological turmoil in survivors,” “healthcare providers deciding under pressure” and “turmoil in providing psychological and psychiatric services.” Ambulance dispatch may be unnecessarily performed owing to turbulent and unsure conditions and psychological turmoil in earthquake-stricken people and pre-hospital emergency staff. Providing earthquake-stricken people with psycho-medical services in their place of residence can significantly reduce the workload of pre-hospital emergency staff and consequently that of hospital staff and therefore save time and treatment costs and increase the quality of health services provided for the injured.

     

Constitutive model for cyclic behaviour of cohesionless sands

This paper presents a constitutive model for describing the stress-strain response of sands under cyclic loading. The model, formulated using the critical state theory within the bounding surface plasticity framework, is an upgraded version of an existing model developed for monotonic behaviour of cohesionless sands. With modification of the hardening law, plastic volumetric strain increment and unloading plastic modulus, the original model was modified to simulate cyclic loading. The proposed model was validated against triaxial cyclic loading tests for Fuji River sand, Toyoura sand and Nigata sand. Comparison between the measured and predicted results suggests that the proposed modified model can capture the main features of cohesionless sands under drained and undrained cyclic loading.