Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite

Background  

The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.     

Water and Boating Activity as Dispersal Vectors for <Emphasis Type="Italic">Schinus terebinthifolius</Emphasis> (Brazilian pepper) Seeds in Freshwater and Estuarine Habitats

Schinus terebinthifolius (Brazilian pepper), a native of South America, is currently naturalized in 20 countries worldwide and can alter native systems by displacing flora and forming monotypic stands. The primary described mechanism of seed dispersal is through consumption of fruits by birds and mammals. We evaluated an alternative dispersal method by evaluating the potential for S. terebinthifolius growing in freshwater and estuarine environments to disperse via water currents. Specifically, we: (1) determined the duration fruits remained buoyant in three salinities, (2) estimated the viability of seeds after 7 days in water, (3) estimated the dispersal rate of floating solitary fruits, and (4) examined the role of boat wakes in moving seeds above mean high water at the shoreline. The length of time fruits floated in 0 ppt water (4.9 days) was significantly less than 15 ppt saltwater (6.2 days), and 30 ppt saltwater (6.9 days). After 7 days, over 13% of seeds remained viable in 0 ppt, 15 ppt, and 30 ppt water. By combining mean dispersal rates and the mean number of days fruits floated, we calculated individual fruits could be transported 16.9 km in 0 ppt and over 22 km in 15 and 30 ppt water. To increase germination, seeds must be stranded above the intertidal zone. Wind wakes alone never achieved this result; however, boat wakes plus wind wakes significantly increased the movement of fruits above the intertidal region into drier soils. The use of both vertebrate dispersal vectors and water dispersal may potentially increase the rate of invasion, establishment, and survival of S. terebinthifolius in freshwater and estuarine environments.     

Factors controlling the interannual variations of MJO intensity

The interannual variations of intensity of the Madden-Julian Oscillation (MJO) during boreal winter are investigated by using the observed outgoing longwave radiation (OLR) and the reanalysis data of ECMWF and NCEP. The standard deviation of 20-80-day filtered OLR anomaly is used to measure the MJO intensity. The dominant spatial structure of the interannual variability is revealed by an EOF analysis of the MJO intensity field. It is found that the leading mode is associated with eastern Pacific type ENSO, whereas the second mode is related to central Pacific type ENSO. A simple atmospheric model is used to investigate the relative roles of background moisture and wind changes in affecting the overall strength of MJO. The numerical experiments indicate that the background moisture effect is dominant while the background wind change has a minor effect.     

Characterising the vertical separation of shale-gas source rocks and aquifers across England and Wales (UK)

Shale gas is considered by many to have the potential to provide the UK with greater energy security, economic growth and jobs. However, development of a shale gas industry is highly contentious due to environmental concerns including the risk of groundwater pollution. Evidence suggests that the vertical separation between exploited shale units and aquifers is an important factor in the risk to groundwater from shale gas exploitation. A methodology is presented to assess the vertical separation between different pairs of aquifers and shales that are present across England and Wales. The application of the method is then demonstrated for two of these pairs—the Cretaceous Chalk Group aquifer and the Upper Jurassic Kimmeridge Clay Formation, and the Triassic sandstone aquifer and the Carboniferous Bowland Shale Formation. Challenges in defining what might be considered criteria for ‘safe separation’ between a shale gas formation and an overlying aquifer are discussed, in particular with respect to uncertainties in geological properties, aquifer extents and determination of socially acceptable risk levels. Modelled vertical separations suggest that the risk of aquifer contamination from shale exploration will vary greatly between shale–aquifer pairs and between regions and this will need to be considered carefully as part of the risk assessment and management for any shale gas development.     

Computer controlled cutting of multiple identical joints in real rock

Summary This novel method for reproducibly cutting joints in real rock will allow shearing of identical joints under varying stress paths. Shearing of such identical joints will greatly reduce the effect of sample variation and the need for scaling results.Joint surfaces are cut with a diamond band saw through a computer controlled feed table. As constructed, the system is capable of cutting samples 20.3 cm (8 in) thick and 30.5 cm (12 in) long. The 6.35 mm (0.25 in) blade used in these tests allows cuts with a maximum radius of curvature of 1.6 cm (0.625 in). A maximum asperity inclination (i) of 28 degrees is possible with the largest samples. These characteristics, in general, are not inherent in the method but rather imposed by the current dimensions of the device.The resulting surfaces, which have been produced in limestone, are analyzed in terms of surface finish at a micro scale, geometrical conformity to the desired surface, reproducibility of the surface and matchability of the two surfaces produced by one cut. These measures indicate a high level of accuracy which should produce repeatable test results when the joints are sheared under laboratory conditions.     

Mapping a Brine Plume Using Surface Geophysical Methods in Conjunction with Ground Water Quality Data

Oil field brine was applied to a gravel roadbed at an instrumented study site in Newark, Ohio, to simulate the use of brine as a deicer on roads in certain areas of Ohio. Brine was applied on a weekly basis eight times during the winter of 1988 as part of the deicing simulation. Eleven wells were installed at the site prior to brine application to permit collection of ground water quality samples. Surface geophysical methods — electrical resistivity and electromagnetic conductivity — were used to map the resulting brine plume. The accuracy of the methods was evaluated by comparing geophysical and ground water quality data. The presence of brine in ground water resulted in a decrease in resistivity and an increase in conductivity. Specific conductance measured in the field was used as a general indicator of the presence of the brine plume in ground water. Chloride concentration was an indicator of brine in the ground water. Results of the surface geophysical surveys correlated best with chloride and dissolved solids concentrations, and with specific conductance in ground water. The surface geophysical methods were found to be useful for qualitative interpretations of ground water quality changes resulting from the application of brine on roads.     

Transfer functions under no-analog conditions: Experiments with Indian Ocean planktonic Foraminifera

This paper documents and investigates an important source of inaccuracy when paleoecological equations calibrated on modern biological data are applied downcore: fossil assemblages for which there are no modern analogs. Algebraic experiments with five calibration techniques are used to evaluate the sensitivity of the methods with respect to no-analog conditions. The five techniques are: species regression; principal-components regression [e.g., Imbrie, J., and Kipp, N. G. (1971). In “The Late Cenozoic Ages,” 71–181]; distance-index regression [Hecht, A. D. (1973). Micropaleontology19, 68–77]; diversity-index regression (Williams, D. F., and Johnson, W. C. (1975). Quaternary Research5, 237–250]; weighted-average method [Jones, J. I. (1964). Unpublished Ph. D. Thesis, Univ. of Wisconsin]. The experiments indicate that the four regression techniques extrapolate under no-analog conditions, yielding erroneous estimates. The weighted-average technique, however, does not extrapolate under no-analog conditions and consequently is more accurate than the other techniques. Methods for recognizing no-analog conditions downcore are discussed, and ways to minimize inaccuracy are suggested. Using several equations based on different calibration techniques is recommended. Divergent estimates suggest that no-analog conditions occur and that estimates are unreliable. The value determined by the weighted-average technique, however, may well be the most accurate.     

Mesozooplankton biomass and grazing responses to Cyclone Opal, a subtropical mesoscale eddy

As part of E-Flux III cruise studies in March 2005, plankton net collections were made to assess the effects of a cyclonic cold-core eddy (Cyclone Opal) on the biomass and grazing of mesozooplankton. Mesozooplankton biomass in the central region of Cyclone Opal, an area of uplifted nutricline and a subsurface diatom bloom, averaged 0.80±0.24 and 1.51±0.59 g DW m⁻², for day and night tows, respectively. These biomass estimates were about 80% higher than control (OUT) stations, with increases more or less proportionately distributed among size classes from 0.2 to >5 mm. Though elevated relative to surrounding waters south of the Hawaiian Islands (Hawai’i lee), total biomass and size distribution in Cyclone Opal were almost exactly the same as contemporary measurements made at Stn. ALOHA, 100 km north of the islands, by the HOT (Hawaii Ocean Time-series) Program. Mesozooplankton biomass and community composition at the OUT stations were also similar to ALOHA values from 1994 to 1996, preceding a recent decadal increase. These comparisons may therefore provide insight into production characteristics or biomass gradients associated with decadal changes at Stn. ALOHA. Gut fluorescence estimates were higher in Opal than in ambient waters, translating to grazing impacts of 0.11±0.02 d⁻¹ (IN) versus 0.03±0.01 d⁻¹ (OUT). Over the depth-integrated euphotic zone, mesozooplankton accounted for 30% of the combined grazing losses of phytoplankton to micro- and meso-herbivores in Opal, as compared to 13% at control stations. Estimates of active export flux by migrating zooplankton averaged 0.81 mmol C m⁻² d⁻¹ in Cyclone Opal and 0.37 mmol C m⁻² d⁻¹ at OUT stations, 53% and 24%, respectively, of the carbon export measured by passive sediment traps. Migrants also exported 0.18 mmol N m⁻² d⁻¹ (117% of trap N flux) in Cyclone Opal compared to 0.08 mmol N m⁻² d⁻¹ (51% of trap flux) at control stations. Overall, the food-web importance of mesozooplankton increased in Cyclone Opal both in absolute and relative terms. Diel migrants provided evidence for enhanced export flux in the eddy that was missed by sediment trap and ²³⁴Th techniques, and migrant-mediated flux was the major export term in the observed bloom-perturbation response and N mass balance of the eddy.     

Determination of asperity damage parameters for constitutive models of rock discontinuities

Dilatancy and contact surface damage are important phenomena affecting the behaviour of rock joints and other geological discontinuities. Effective constitutive laws that incorporate these behaviours have recently been developed but require the specification of new material parameters that govern damage of asperity surfaces. Determination of the parameters that control damage is currently a difficulty that confronts practitioners. This brief will summarize the findings of Hutson and Dowding's investigation of joint surface asperity degradation and elaborate on the implications for application.