Isotope fractionation of neon during stepheating extraction?: a comment on ‘Re‐interpretation of the existence of a primitive plume under Australia based on neon isotope fractionation during step heating’ by Gautheron and Moreira (2003)

Using a Rayleigh distillation fractionation model, we calculate that the maximum isotope fractionation potentially achievable is less than 5% during the early stages of gas release from a sample. Our calculation corrects the erroneous conclusions of Gautheron and Moreira (2003), who re‐interpreted the plume‐like neon isotopic compositions found in metasomatic apatite from a south‐eastern Australian xenolith (Matsumoto et al., 1997) to be the result of Rayleigh‐type isotope fractionation of originally MORB‐type neon during stepheating gas extraction. We stress that the modelling of neon isotopic fractionation by Gautheron and Moreira (2003) is incorrect, and that the finding of a plume‐like neon isotopic composition in the apatite by Matsumoto et al. (1997) remains a quite valid and robust conclusion.     

Double-diffusive convection with a non-linear equation of state: Part I. The accurate conservation of properties in a two-layer system

If the equation of state is nonlinear, a given flux of heat across a double diffusive interface causes different buoyancy fluxes in the upper and lower layers. This results in different convective activity in the two layers and can lead to preferential entrainment across the interface in one direction (i.e. a migration of the interface). In this paper we derive the conservation equations for properties (e.g. heat and a solute) across a double diffusive interface between two well-mixed layers. A nondimensional measure of the entrainment across an interface and the most suitable choice for the buoyancy flux ratio are presented. Some surprising facts emerge. First, even for a linear equation of state and in the absence of direct entrainment across the interface, the flux of water across a finger interface is shown to be important. Second, for the heat-solute system, the heat balance equations for each well-mixed layer contain terms proportional to the heat of solution of the solute and the partial specific enthalpy of pure water in a seawater solution. Third, the rate of change of gravitational potential energy of the two-layer system is shown to have several extra terms in addition to the two commonly quoted major terms.     

A non-hydrostatic model for the numerical study of landslide-generated waves

This paper proposes and demonstrates a two-layer depth-averaged model with non-hydrostatic pressure correction to simulate landslide-generated waves. Landslide (lower layer) and water (upper layer) motions are governed by the general shallow water equations derived from mass and momentum conservation laws. The landslide motion and wave generation/propagation are separately formulated, but they form a coupled system. Our model combines some features of the landslide analysis model DAN3D and the tsunami analysis model COMCOT and adds a non-hydrostatic pressure correction. We use the new model to simulate a 2007 rock avalanche-generated wave event at Chehalis Lake, British Columbia, Canada. The model results match both the observed distribution of the rock avalanche deposit in the lake and the wave run-up trimline along the shoreline. Sensitivity analyses demonstrate the importance of accounting for the non-hydrostatic dynamic pressure at the landslide-water interface, as well as the influence of the internal strength of the landslide on the size of the generated waves. Finally, we compare the numerical results of landslide-generated waves simulated with frictional and Voellmy rheologies. Similar maximum wave run-ups can be obtained using the two different rheologies, but the frictional model better reproduces the known limit of the rock avalanche deposit and is thus considered to yield the best overall results in this particular case.     

The age,extent and geomorphological significance of the Sassafras basalt,south‐eastern New South Wales

Basalt at Sassafras was erupted in the Middle Eocene. The K‐Ar ages average 45.3 ± 4.9 Ma on whole rock and 48.4 ± 1.9 Ma on plagioclase. The basalt is not limited to a plateau capping, but extends 150 m down into adjacent valleys. Comparison with nearby Eocene basalts shows that there was in excess of 250 m of local relief in the central Shoalhaven valley by the Early Tertiary. The basalts were extruded at high elevation, and denudation of the coastal margin of the upland was already well advanced. Post‐basaltic denudation has been very slow, and the Early Tertiary landscape is well preserved.     

Depositional environments of the Hart coal zone (Paleocene), Willow Bunch Coalfield, southern Saskatchewan, Canada from petrographic, palynological, paleobotanical, mineral and trace element studies

Coal petrology, palynology, paleobotany and mineralogy of the Hart coal indicate deposition under wet, warm-temperate to subtropical climatic conditions in low-lying backswamps with fluvial channels and locally ponded areas. The coal is dominated by mixed xylitic/attrital lithotypes and by huminite macerals with secondary inertinite macerals and minor liptinite macerals. Good correlation exists between lithotypes and maceral composition. Local and vertical variations in proportions of huminites and inertinites reflect frequent fluctuations in water levels, periodic flooding, desiccation and burning of the peat. Swamps were dominated by Glyptostrobus-Taxodium forest with Betula-Myrica-Alnus communities and, locally, Laevigatosporites, which are the dominant contributors to the xylite-rich lithotypes. Attrital lithotypes with abundant Pandanus, Typha and Azolla are consistent with wetter areas of a fluvial environment, including ponds and channels. Trace elements Cr, Cu, Mo, Ni, Si, Ti, U, Se, V, W, K and Th, typically associated with synergetic minerals kaolinite, calcite and quartz, may have a volcanic source. High concentrations of Na, Ba and Ca found in organic complexes are of secondary origin and probably originate in deep source brines rather than marine surface waters.     

40Ar39Ar and KAr dating of altered glassy volcanic rocks: the Dabi Volcanics,P.N.G.

KAr and ${}^{40}\text{Ar}{}^{39}\text{Ar}$ ages have been determined for altered submarine tholeiitic and boninite (high-Mg andesite) lavas from the Dabi Volcanics, Cape Vogel Peninsula, Papua New Guinea. ${}^{40}\text{Ar}{}^{39}\text{Ar}$ whole rock total fusion and plateau ages identify a Late Paleocene age for the tholeiitic lavas (58.9 ± 1.1 Ma) and also for the boninitic lavas (58.8 ± 0.8 Ma). Apparent KAr ages for the same samples range from 27.2 ± 0.7 to 63.9 ± 4.5 Ma, and young KAr ages for glassy boninites are probably due to variable radiogenic ⁴⁰Ar (⁴⁰Ar¹) loss. These new ages effectively reconcile previously ambiguous age data for the Dabi Volcanics and indicate contemporaneous tholeiitic and boninitic volcanism occurring in southeast PNG during the Late Paleocene.Smectites, developed as alteration products after glass in oceanic lavas commonly do not retain ³⁹Ar during or subsequent to irradiation, but in some cases may contain ⁴⁰Ar1. In the absence of other factors modifying K and Ar contents, samples which have not lost ⁴⁰Ar¹ from smectite and suffer ³⁹Ar loss only, are interpreted to have been altered immediately subsequent to the crystallization of the lava; whereas samples which have lost ⁴⁰Ar¹ as well as ³⁹Ar may be the result of either recent alteration, or of continuous ⁴⁰Ar¹ loss since the time of crystallization.     

Geochronology of Gran Canaria,Canary Islands: Age of shield building volcanism and other magmatic phases

Forty-six new K-Ar age determinations are presented on whole rock samples and mineral separates from volcanic and subvolcanic rocks of Gran Canaria. The main subaerial shield building basaltic volcanism with estimated volume of about 1000 km³ was confined to the interval about 13.7 m.y. to 13.5 m.y. ago in the middle Miocene. Substantial volume (～100 km³) of silicic volcanics (trachyte and peralkaline rhyolite) were erupted with no detectable time break following the basaltic volcanism, essentially contemporaneous with formation of a large collapse caldera at 13.4±0.3 m.y. ago. Trachytic to phonolitic volcanism continued intermittently in the waning states of activity until about 9 m.y. ago. Following a long hiatus there was resurgence of volcanism with eruption of about 100 km³ of basanitic to hauyne phonolitic rocks of the Roque Nublo Group between about 4.4 m.y. and 3.4 m.y. ago in the Pliocene. After a hiatus of less than 1.0 m.y., olivine nephelinite magmas were erupted and this activity continued intermittently until relatively recent times, the younger eruptives being mainly basanitic in composition. The volume of volcanic products in this phase probably does not exceed 10 km³. Thus the volume of all the resurgent volcanism comprises less than 10 percent of the subaerially exposed part of Gran Canaria. The results show that the subaerial main shield building phase of volcanism in Gran Canaria, consisting of mildly alkali to transitional basalts, occurred over a time interval that was less than 0.5 m.y. Magmatic evolution on Gran Canaria appears to be similar to that found on other basaltic volcanoes in oceanic regions. Thus volcanoes in the Hawaiian, Marquesas and Society Islands all were built by basaltic lavas in similar short-lived episodes of volcanism. In some Hawaiian volcanoes, a resurgent phase of volcanism of strongly undersaturated basalts of small volume is recognized following a long hiatus, again similar to that found on Gran Canaria. The relatively large volume of silicic lavas erupted in Gran Canaria immediately following the main basaltic shield building phase is, however, not matched in the Pacific volcanoes mentioned.