Assessment of shallow groundwater in Lake Nyos catchment (Cameroon,Central-Africa): implications for hydrogeochemical controls and uses

In 1986, carbon dioxide gas exploded from Lake Nyos and killed about 1,800 people. After that disaster, various administrative and research activities have been conducted to mitigate subsequent disasters. However, none of those endeavors have characterized the groundwater chemistry to identify hydrogeochemical processes that control the water chemistry, and the quality of the water for domestic and agricultural uses that support the lives of un-official resettlers around Lake Nyos. Conventional hydrochemical techniques coupled with statistical and graphical analysis were therefore employed to establish the baseline hydrochemical conditions, assess processes controlling solutes distribution in shallow groundwater in the Lake Nyos catchment and explore its usability. Groundwater samples were analyzed for their physical and chemical properties. The wide ranges of electrical conductivity and total dissolved solid values reveal the heterogeneous distribution of groundwater within the watershed. The relative abundance of major dissolved species was Ca > Mg > Na > K for cations and HCO₃ >>> Cl > SO₄ > NO₃ for anions. Piper diagram classified almost all water samples into mixed CaMg–HCO₃ water type. Major ion geochemistry reveals that, in addition to silicates weathering (water–rock interaction), ion exchange processes regulate the groundwater chemistry. Principal component analysis supports the occurrence of water rock interaction. Hierarchical cluster analysis showed that the chemistry of groundwater in the study area is controlled by three main factors, and suggests no hydraulic connectivity between deep lake water and groundwater in the catchment. The quality assessment of the groundwater showed that groundwater parameters are within the acceptable limit of the World Health Organization and Nigeria guidelines for drinking and domestic uses, and water found to be good for irrigation.     

Disaster prevention,disaster preparedness and local community resilience within the context of disaster risk management in Cameroon

This paper presents a simulation of three components of near-field ground shaking recorded during the main shock at three stations of the September 16, 1978, Tabas (M _w = 7.4), Iran, earthquake, close to the causative fault. A hybrid method composed of a discrete wavenumber method developed by Bouchon (Bouchon in Bull Seismol Soc Am 71:959–971, 1981; Cotton and Coutant in Geophys J Int 128:676–688, 1997) and a stochastic finite-fault modeling based on a dynamic corner frequency proposed by Motazedian and Atkinson (Bull Seismol Soc Am 95:995–1010, 2005), modified by Assatourians and Atkinson (Bull Seismol Soc Am 97:935–1949, 2007), is used for generating the seismograms at low (0.1–1.0 Hz) and high frequencies (1.0–20.0 Hz), respectively. The results are validated by comparing the simulated peak acceleration, peak velocity, peak displacement, Arias intensity, the integral of velocity squared, Fourier spectrum and acceleration response spectrum on a frequency-by-frequency basis, the shape of the normalized integrals of acceleration and velocity squared, and the cross-correlation with the observed time-series data. Each characteristic is compared on a scale from 0 to 10, with 10 being perfect agreement. Also, the results are validated by comparing the simulated ground motions with the modified Mercalli intensity observations reported by reconnaissance teams and showed reasonable agreement. The results of the present study imply that the damage distribution pattern of the 1978 Tabas earthquake can be explained by the source directivity effect.     

Age of the metamorphic sole of the Papuan Ultramafic Belt ophiolite, Papua New Guinea

The Papuan Ultramafic Belt (PUB) ophiolite is former oceanic crust and upper mantle emplaced onto continental crust in Papua New Guinea (PNG) in a zone of general convergence between the Pacific and Australian plates. The metamorphic sole beneath the ophiolite is best exposed in the Musa–Kumusi divide and comprises a 40- to 300-m-thick body of granulite and amphibolite facies rocks. Geochronological studies on the metamorphic sole, using amphiboles from the granulites and amphibolites, yield measured K–Ar ages ranging from 65.0±0.7 to 57.2±0.6 Ma and average ⁴⁰Ar–³⁹Ar direct total fusion ages ranging from 67.0±0.7 to 59.5±0.2 Ma. Five of the six ⁴⁰Ar–³⁹Ar plateau ages, derived from age spectra, lie between 58.6±0.2 and 57.8±0.2 Ma, with an overall mean age of 58.3±0.4 Ma. The large spread in measured K–Ar and ⁴⁰Ar–³⁹Ar total fusion ages is thought to be caused by the presence of variable amounts of excess argon. The mean plateau age for five samples of 58.3±0.4 Ma is interpreted to mark the time of cooling of the metamorphic sole following peak metamorphism. We suggest that the development of the metamorphic sole and emplacement of the PUB ophiolite onto the PNG crust occurred in a relatively short time interval in the Paleocene.     

Evidence for Non-Conservative Behaviour of Chlorine in Humid Tropical Environments

The knowledge of the biogeochemical cycle of chlorine (Cl)is important since this element is used as a tracer of geochemical and hydrological processes in oceanic or continental environments. More specifically, Cl can be used to correct surface water composition from atmospheric contribution in order to calculate precise chemical weathering rates in watersheds. Beyond the problem of potential Cl sources in a given watershed, which is directly related to the lithology, vegetation, and industrial activities, the Cl normalization is based on the assumption that this element behaves conservatively during surface processes (e.g., chemical weathering, adsorption/desorption processes).The purpose of the present study is to forecast the geochemical behavior of Cl in a forested ecosystem located under humid tropical environment.For this reason, we have analyzed the Cl (and also Ca and Na) concentrations ofsurface waters (rainwater, groundwater, river water) over a two-year period in the Nsimi–Zoetele watershed (Cameroon).The Cl mass balance for the watershed appears to be equilibrated over the studied period (1995–1996) but Cl behavior in Mengong River draining the watershed suggests a non-conservative behavior. Indeed, Cl concentrationsin the Mengong River are low during dry seasons and high during wet seasons, which is the reverse tendency to what is usually observed taking into account dilution and evaporation processes. As Cl concentrations in the Mengong River are lower than those measured in all the feeding reservoirs, Cl should be adsorbed onto the soils of the watershed. However, as the Cl mass balance is equilibrated over the whole-year, Cl should be adsorbed and releasedat a seasonal scale. The results we obtained for this small watershed were not generalized for a larger studied basin (i.e., Nyong River basin). Even if these results should be followed by further investigations, this study suggests that Cl normalization should be used with caution to avoid under- or over-estimation of chemical weathering rates.     

The Aitape 1998 Tsunami: Reconstructing the Event from Interviews and Field Mapping

— On the evening of 17 July 1998, on th e Aitape Coast of Papua New Guinea, a strongly felt earthquake was followed some 10–25 minutes later by a destructive tsunami. The tsunami comprised three waves, each estimated to be about 4 m high. The second of the three waves rose to a height of 10–15 m above sea level after it had crossed the shoreline and caused most damage. Maximum wave heights and the greatest damage were recorded along a 14-km sector of coast centered on Sissano Lagoon. In this sector the wavefronts moved from east to west along the coast; all structures were destroyed, and in the two main villages 20–40 percent of the population was killed. Partial destruction extended 23 km to the southeast and 8 km to the northwest, and effects of the tsunami were felt as far as 250 km to the west–northwest, beyond the international border. More than 1600 people are known to have died, with some estimates as high as 2200; 1000 were seriously injured, and 10,000 survivors were displaced. This paper presents information from interviews with eye-witnesses and from mapping of damage and inundation, and includes new information on the height, shape and timing of the waves; on the possible escape of petroleum and other gases from beneath the seafloor before and during the tsunami; on unusual sound effects that preceded the waves, and lighting effects that followed; on possible deep circulation (to 250 m) of sea water in the waves; on subsidence of the order of 50–70 cm at the coastal sand barrier; and on the resilience and potential protective capacity of certain species of trees. Eye-witness accounts indicate that the tsunami reached the shore at between 09:00 and 09:08 UT, which is earlier than is proposed in published models of the timing and location of the source of the tsunami.     

Present weathering rates in a humid tropical watershed: Nsimi, South Cameroon

The study of biogeochemical and hydrological cycles in small experimental watersheds on silicate rocks, common for the Temperate Zone, has not yet been widely applied to the tropics, especially humid areas. This paper presents an updated database for a six-year period for the small experimental watershed of the Mengong brook in the humid tropics (Nsimi, South Cameroon). This watershed is developed on Precambrian granitoids (North Congo shield) and consists of two convexo-concave lateritic hills surrounding a large flat swamp covered by hydromorphic soils rich in upward organic matter. Mineralogical and geochemical investigations were carried out in the protolith, the saprolite, the hillside lateritic soils, and the swamp hydromorphic soils. Biomass chemical analyses were done for the representative species of the swamp vegetation. The groundwater was analysed from the parent rock/saprolite weathering front to the upper fringe in the hillside and swamp system. The chemistry of the wet atmospheric and throughfall deposits and the Mengong waters was monitored.In the Nsimi watershed the carbon transfer occurs primarily in an organic form and essentially as colloids produced by the slow biodegradation of the swamp organic matter. These organic colloids contribute significantly to the mobilization and transfer of Fe, Al, Zr, Ti, and Th in the uppermost first meter of the swamp regolith. When the organic colloid content is low (i.e., in the hillside groundwater), Th and Zr concentrations are extremely low (<3 pmol/L, ICP-MS detection limits). Strongly insoluble secondary thorianite (ThO₂) and primary zircon (ZrSiO₄) crystals control their mobilization, respectively. This finding thus justifies the potential use of both these elements as inert elements for isoelement mass balance calculations pertaining to the hillside regolith.Chloride can not be used as a conservative tracer of hydrological processes and chemical weathering in this watershed. Biogenic recycling significantly influences the low-Cl input fluxes. Sodium is a good tracer of chemical weathering in the watershed. The sodium solute flux corrected from cyclic salt input was used to assess the chemical weathering rate. Even though low (2.8 mm/kyr), the chemical weathering rate predominates over the mechanical weathering rate (1.9 mm/kyr). Compared to the Rio Icacos watershed, the most studied tropical site, the chemical weathering fluxes of silica and sodium in the Mengong are 16 and 40 times lower, respectively. This is not only related to the protective role of the regolith, thick in both cases, but also to differences in the hydrological functioning. This is to be taken into account in the calculations of the carbon cycle balance for large surfaces like that of the tropical forest ecosystems on a stable shield at the global level.