Meteoroid ablation spheres from deep-sea sediments

We present analyses of spheres magnetically extracted from mid-Pacific abyssal clays 0–500,000 years old. The concentration of spheres >200 μm is a few times 10 ppb. The spheres were divided into three groups using their dominant mineralogy, and are named iron, glassy, and silicate. Most spheres were formed from particles that completely melted as they separated from their parent meteoroids during the ablation process. However, some of the silicate spheres contain relict grains of the parent meteoroids that did not experience any melting. Typically, these relict grains are olivine crystals whose cores are Mg-rich (Fo_89–99). Commonly the outer rims of these grains were altered during heating. Other relict mineral grains include enstatite, ferrous spinel, chromite, and pentlandite.The three groups of spheres may possibly indicate some genetic significance. It seems reasonable to expect iron-rich spheres to be produced during ablation of iron and metal-rich silicate meteoroids. Metal spheres are probably not produced by ablation of predominantly silicate meteoroids because studies of fusion crusts and laboratory ablated silicate materials have never yielded separate metal spheres, but rather have produced spheres with intergrown iron oxide and silicate phases. The iron spheres possess identical mineralogy with the fusion crusts of Boguslavka, Norfork, and N'Kandhla iron meteorites as well as with the ablation debris created in the laboratory using iron and nickel-iron samples.The glassy spheres are considerably more Fe-rich than the silicate spheres. They consist of magnetite and a Fe-rich glass which is relatively low in Si. Some of these spheres may have experienced pronounced volatile depletion during the ablation process and could have been derived from silicate or metal-rich silicate meteoroids.The silicate spheres are undoubtedly derived from ablation of stony meteoroids. Two of the mineral assemblages occurring in these spheres (olivine-magnetite-glass and sulfide) are identical to those described in the natural fusion crusts of Allende, Orgueil, and Murchison meteorites, laboratory-made ablation debris, and melted interplanetary dust collected from the stratosphere. Bulk compositions and relict grains are useful for determining the parent meteoroid types for the silicate spheres. Bulk analyses of spheres have non-volatile elemental abundances similar to chondritic abundances. Analyses of relict grains identified high-temperature minerals which often occur as larger crystals in a fine-grained matrix that is characterized by voids. These voids were caused by escaping volatiles as minerals decomposed during ablation. Because larger crystals of higher-temperature minerals are associated with fine-grained, low-temperature, volatile-rich matrix, the obvious candidates for parent meteoroids of the silicate spheres containing relict grains are carbonaceous chondrites.     

The Permian-Triassic boundary event: a geochemical study of three Chinese sections

Trace elements were determined in two well-documented Chinese Permian-Triassic (P/Tr) boundary sections (Meishan and Shangsi) and in a new section (Liangfenya). Iridium concentrations range from 3 to 87 pg/g, at or below levels in common sedimentary rocks. The results contrast with previous reports of high Ir concentration in the Meishan and Shangsi sections and offer no support to suggestions of a major meteoroid impact at the end of the Permian. A notable feature in each of these widely separated P/Tr sections (500–1500 km) is the existence of 2–5 light-colored clay layers at and near the boundary. These clay layers are strongly enriched in Cs, Zr, Hf, Ta, and Th and depleted in Cr, Co, and Ir, indicating that they are altered ash, apparently from the same massive silicic volcanic eruptions. We estimate the magnitude of these eruptions to be a few thousand km³ of magma, a volume comparable to the great Toba eruption.     

Unmelted meteoritic debris in the Late Pliocene iridium anomaly: Evidence for the ocean impact of a nonchondritic asteroid

Ir-bearing particles have been recovered from 2 piston cores in the Antarctic Basin in the southeastern Pacific. In core E13-3 the particles closely correspond to the Late Pliocene Ir anomaly and have a fluence of ~100 mg cm^?2. In core E13-4, 120 km to the southwest, the particle fluence is ~4 mg/cm^?2. Particles with diameters from 0.5 to 4 mm contain at least 35% of the Ir in this horizon. Three types of particles have been identified: 1) vesicular, 2) basaltic, and 3) metal. The vesicular particles appear to be shock-melted debris derived from the oceanic impact of a howarditic asteroid containing a minor metal component. These particles have recrystallized from a melt and impact into the ocean has resulted in the incorporation of Na, K, Cl, and radiogenic Sr from the ocean water target. The basaltic clasts appear to be unmelted fragments of the original asteroid which may have separated from the main body prior to impact. Combined vesicular and basaltic particles are believed to have formed by collisions in the debris cloud. Estimates of the diameter of the projectile range from 100 to 500 m. By many orders of magnitude this is the most massive achondrite sampled by a single meteorite fall.     

Rb-Sr,Sm-Nd,K-Ca,O, and H isotopic study of Cretaceous-Tertiary boundary sediments,Caravaca, Spain: evidence for an oceanic impact site

Isotopic ratios and trace element abundances were measured on samples of Ir-enriched clay at the Cretaceous-Tertiary boundary, and in carbonate and marl from 5 cm below and 3 cm above the boundary. Samples were leached with acetic acid to remove carbonate, and with hydrochloric acid. Leachates and residues were measured. The Sr, Nd, O and H isotopic compositions of the boundary clay residues are distinct from those of the stratigraphically neighboring materials. The data indicate that most of the clay material was derived from a terrestrial source with relatively low⁸⁷Sr/⁸⁶Sr and high¹⁴³Nd/¹⁴⁴Nd ratios. The δ¹⁸O data suggest that the detritus has been modified by submarine weathering. K-Ca and Rb-Sr systematics, as well as O isotope ratios of K-feldspar spherules within the boundary clay, suggest that they are predominantly authigenic and may have formed after the time of deposition. However, Sm-Nd and Rb-Sr isotopic data indicate that the spherules contain relict material that provides information on the nature of the original detritus. The isotopic evidence for foreign terrestrial detritus in the boundary clay, the low rare earth element concentrations and high Ni concentration, support the hypothesis of a terminal Cretaceous asteroidal impact that produced a global layer of fallout. The data are most easily explained if the impact site was on oceanic crust rather than continental crust, and if a substantial fraction of the fallout was derived from relatively deep within the lithosphere (>3 km). This would probably require a single large impactor.     

Anomalous iridium enrichment at the Triassic–Jurassic boundary, Blomidon Formation, Fundy basin, Canada

We present new analyses that confirm Ir enrichment (up to 0.31 ng/g) in close proximity to the palynological Triassic–Jurassic boundary in strata near the top of the Blomidon Formation at Partridge Island, Nova Scotia. High Ir concentrations have been found in at least two samples within the uppermost 70 cm of the formation. Ratios of other PGEs and Au to Ir are generally higher by an order of magnitude than in ordinary chondrites. No impact-related materials have been identified at this horizon in the Blomidon Formation, therefore we cannot confirm an extraterrestrial source for the anomalous Ir levels. We consider, however, the possibility that regional basaltic volcanism is a potential source for the Ir in these sediments. The elevated Ir concentrations are found in reduced, grey colored mudstones, so redox concentration is a possible explanation for the distribution of Ir in these strata.     

Wave forces on vertical cylinders upon shoals

An experimental study has been carried out on the forces from plunging breaking regular and irregular waves on a vertical cylinder on a shoal. Total as well as local wave forces have been measured. Engineering formulae for the calculation of the horizontal forces and overturning moments have been derived. The duration of the impact forces have been measured and compares fairly well with theoretical values.     

Remote sensing of temporal and spatial patterns of suspended particle size in the Irish Sea in relation to the Kolmogorov microscale

Suspended sediments form an integral part of shelf sea systems, determining light penetration for primary production through turbidity and dispersion of pollutants by adsorption and settling of particles. The settling speed of suspended particles depends on their size and on turbulence. Here a method of determining particle size via remote sensing measurements of ocean colour and brightness has been applied to a set of monthly satellite images of the Irish Sea covering a full year (2006). The suspended sediment concentration was calculated from the ratio between green (555 nm) and red (665 nm) wavelengths in MODIS imagery. Empirical formulae were employed to convert suspended sediment concentrations and irradiance reflectance in the red part of the spectrum into specific scattering by mineral particles and floc size. A geographical pattern was evident in all images with shallow areas with fast currents having high year-average suspended sediment concentrations (7.6 mg l⁻¹), high specific scattering (0.225 m² g⁻¹) and thus small particle sizes (143 μm). The reverse is true for deeper areas with slower currents, e.g. the Gyre southwest of the Isle of Man where turbidity levels are lower (3.3 mg l⁻¹), specific scattering is lower (0.081 m² g⁻¹) and thus particle sizes are larger (595 μm) on average over a year. Temporal signals are also seen over the year in these parameters with minimum seasonal amplitudes (a factor 3.5) in the Turbidity Maximum and maximum seasonal amplitudes twice as large (a factor 7) in the Gyre. In the Gyre heating overcomes mixing in summer and stratification occurs allowing suspended sediments to settle out and flocs to grow large. The size of aggregated flocs is theoretically proportional to the Kolmogorov scale. This scale was calculated using depth, current, and wind speed data and compared to the size of flocculated particles. The proportionality changes through the year, indicating the influence of biological processes in summer in promoting larger flocs.