在可控制的相对湿度下矿物表面上多环芳烃的降解

多环芳香烃由于诱发突变和致癌的性质威胁着人类的健康,近年来,其降解问题得到了广泛的关注。笔者研究了在没有光照的条件下,改变相对湿度(5%至30%之间),苯并芘(一种典型的多环芳烃物质)在石英,矾土,蒙脱石,高岭石,腐殖酸和吸附了腐殖酸的石英上的稳定性,继而可以检测出矿物表面催化多环芳烃降解的效果。苯并芘的稳定性主要是由吸附剂的物化性质决定的。石英表现出很好的催化效果,即便其表面被腐殖酸所包覆。在整个实验过程中(3天)吸附在蒙脱石和腐殖酸表面的苯并芘依然很稳定。实验装置中的湿度影响在某些特定的矿物中的苯并芘的稳定性。特…     

Decomposition of Polycyclic Aromatic Hydrocarbon （PAHs） on Mineral Surface under Controlled Relative Humidity

The fate of Polycyclic Aromatic Hydrocarbons （PAHs） residing in the atmosphere has received enormous attention in recent years due to their mutagenic and carcinogenic risks on human health. In this context, the stability of pyrene （as a representative PAHs） on quartz, alumina, montmorillonite, kaolinite, humic acid and quartz coated with sorbed humic acid was investigated at controlled relative humidity （RH： i.e. 5% and 30%） without light irradiation in order to detect the presence of catalytic effect of mineral surface on PAHs decomposition. The stability of pyrene was found to depend strongly on the physicochemical properties of the substrates. Quartz showed a strong catalytic effect for the decomposition of pyrene even though it was coated with sorbed humic acid. Pyrene sorbed on montmorillonite and humic acid remained stable during the experimental period （i.e. 3 days）. Moisture in the experimental cell also affected the stability of pyrene in particular minerals. Especially, pyrene sorbed on alumina was rapidly decomposed at higher RH. However, there were almost no effect in the case of quartz, kaolinite and humic acid. Depending on the physicochemical properties of aerosols and RH, PAHs associated with minerals in the atmosphere would be decomposed and/or stably reside in the atmosphere.     

RATES OF SLOPE DECLINE,TALUS GROWTH AND CLIFF RETREAT ALONG THE SHOMYO RIVER IN CENTRAL JAPAN: A SPACE‐TIME SUBSTITUTION APPROACH

On the basis of a space–time substitution, rates of cliff retreat and talus development overthe pasttens ofthousands of years were quantified for valley‐side slopes along the Shomyo River with a known rate of waterfall recession. Detailed profiles of the valley‐side slopes were obtained at 19 sites along the river by map reading and field survey, and the morphologic characteristics of the slopes were then measured. By combining the locations of the slopes with the recession rate of Shomyo Falls, it is estimated that the growth rate of the talus slope is 3.9–7.2 mm/yr, the rate of decline of the cliff is 2.0–4.0 × 10^?4 deg/yr, and the retreat rate of the cliff top is 6.2–11.6 mm/yr.     

Seasonal Variability of Polycyclic Aromatic Hydrocarbons (PAHs) in a Coastal Marine Area in the Northwestern Region of the Sea of Japan/East Sea (Possiet Bay)

Ocean Science Journal - Contamination by persistent organic pollutants including polycyclic aromatic hydrocarbons (PAHs) constitutes a major concern in relation to aquatic ecosystems. To study the...     

POST-VOLCANIC EROSION RATES OF SHOMYO FALLS IN TATEYAMA, CENTRAL JAPAN

Post‐eruptive fluvial erosion of welded pyroclastic flow deposits often depends on the recession of waterfalls because of their rapid erosion involved. We examine the recession rate of Shomyo Falls, which consists of Pleistocene welded pyroclastic flow deposits in Tateyama, north‐central Japan. The mean recession rate of the waterfall obtained from lithological and topographical evidences is 0.08‐0.15 m/a for 100000 a. However, the recession rate estimated by means of an empirical equation comprising physical parameters of erosive force and bedrock resistance is 0.006‐0.011 m/a with small uncertainties. The discrepancy between the geology‐based and equation‐based recession rates indicates that some factors, not taken account of in the equation, significantly influence the recession rate. We suggest that a factor in the rapid erosion of the waterfall is a large amount of transported sediment acting as abrasive material, which is supplied from high mountains in the watershed above the waterfall.