Sorption of carbon dioxide–methane mixtures

The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH₄ and CO₂ to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO₂ and CH₄, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH₄ and other gases in comparison with the isotherms of sorption of CO₂ and a CO₂/CH₄ mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO₂ molecules to the system: coal with a higher degree of metamorphism—CH₄, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs.     

Rapid ground deformation corresponding to a mining-induced seismic event followed by a massive collapse

Natural Hazards - On 17 April 2015, the Wujek/?l?sk underground coal mine in Poland was struck by a strong induced tremor of magnitude M4.0. The event was followed by a massive rock burst...     

Galactic Dynamo and Spiral Arms - 3D MHD Simulations

In the present project we investigate the evolution of a three-dimensional (3D), large-scale galactic magnetic field under the influence of gas flows in spiral arms and in the presence of dynamo action. Our principal goal is to check how the dynamical evolution of gaseous spiral arms affects the global magnetic field structure and to what extent our models could explain the observed spiral patterns of polarization B-vectors in nearby galaxies. A two-step scheme is used: the N-body simulations of a two-component, self-gravitating disk provide the time-dependent velocity fields which are then used as the input to solve the mean-field dynamo equations. We found that the magnetic field is directly influenced by large-scale non-axisymmetric density wave flows yielding the magnetic field locally well-aligned with gaseous spiral arms in a manner similar to that discussed already by Otmianowska-Mazur et al. 1997. However, an additional field amplification, introduced by a non-zero -term in the dynamo equations, is required to cause a systematic increase of magnetic energy density against the diffusive losses. Our simulated magnetic fields are also used to construct the models of a high-frequency (Faraday rotation-free) polarized radio emission accounting for effects of projection and limited resolution, thus suitable for direct comparisons with observations.     

Pure cross-anisotropy for geotechnical elastic potentials

The pure cross-anisotropy is understood as a special scaling of strain (or stress). The scaled tensor is used as an argument in the elastic stiffness (or compliance). Such anisotropy can be overlaid on the top of any elastic stiffness, in particular on one obtained from an elastic potential with its own stress-induced anisotropy. This superposition does not violate the Second Law. The method can be also applied to other functions like plastic potentials or yield surfaces, wherever some cross-anisotropy is desired. The pure cross-anisotropy is described by the sedimentation vector and at most two constants. Scaling with more than two purely anisotropic constants is shown impossible. The formulation was compared with experiments and alternative approaches. Static and dynamic calibration of the pure anisotropy is also discussed. Graphic representation of stiffness with the popular response envelopes requires some enhancement for anisotropy. Several examples are presented. All derivations and examples were accomplished using the algebra program Mathematica.

     

Abnormal features of Macoma balthica (Bivalvia) in the Baltic Sea: alerting symptoms of environmental adversity?

Recent studies of the Baltic clam Macoma balthica (L.) from the southern Baltic (the Gulf of Gdansk) have revealed striking morphological, histological and cytogenetic features. Strong deformation of the shell, including elongation of the posterior end and the appearance of an easily visible flexure in this part, has been recorded. The population contribution of the deformed blunt shelled ("irregular") clams ranged from 0% to 65% and tended to increase with depth. The morphologically "irregular" clams had higher accumulated tissue concentrations of trace metals (As, Ag, Cd, Pb, Cu and Zn), indicating a different metal handling ability. Adverse conditions in deeper water regions of the Gulf (e.g. hypoxia, hydrogen sulphide, elevated bioavailability of contaminants) have been suggested as inducers of the phenotypical changes (morphological deformation) in part of the population and, in parallel, of the specific physiological adaptations that result in higher metal accumulation in the "irregular" clams. Cytogenetic and histological analyses showed the presence of tumours in gill cells and digestive system of the affected clams, the prevalence of disseminated neoplasia ranging from 0% to 94% depending on the site. The disease was manifested by a modified karyotype (i.e. an abnormal number and morphology of chromosomes), a higher activity of nucleolar organizer regions (AgNORs), and tissue lesions (enlarged cells, actively proliferative with pleomorphic nuclei). Bottom sediments showed acute toxicity and have been proposed as a source of an initialising carcinogenic factor. However, none of the ecotoxicological studies provided was successful in the clear demonstration of a single (or multifactorial) agent that can account for the disseminated neoplasia.     

The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.     

Effect of Time on Dynamic Shear Modulus of Selected Cohesive Soil of One Section of Express Way No. S2 in Warsaw

Several researches published comprehensive reports on dynamic soil properties of cohesive soils, in which many of them outlined, i.e., key factors affecting the dynamic shear modulus. For cohesive soils, the modulus at small strains (g < 10^t-3 %) is, first of all, a function of void ratio and effective confining stress. For clays, however, secondary time effects and clay mineralogy (fabric and structure) also appear to be important. The influence of confinement of laboratory-prepared as well as naturally deposited clays consists in an increase of shear modulus logarithmically as a function of time. In this paper, the effect of duration of the various confining pressures on dynamic shear modulus (G) of selected cohesive soils from Warsaw area was evaluated. Shear modulus was determined on the basis of resonant column tests, at low and high shearing strain amplitudes. It is shown that the calculated shear modulus is time-dependent; during approximately first 1000 minutes of consolidation, the moduli increased by almost 50%. Moreover, it is characterized by two phases: an initial one results from primary consolidation and a second one, which occurs after the end of primary consolidation, herein about 16-17 hours, and is called “long-term time effect”. This effect was found also for modulus at higher shearing strains (γ > 10³%, e.g., 3 × 10³%, 5 × 10³%, 8 × 10³%, 2 × 10³%).     

How do granitoid magmas mix with each other? Insights from textures,trace element and Sr–Nd isotopic composition of apatite and titanite from the Matok pluton (South Africa)

In plutonic systems, magma mixing is often modelled by mass balance based on whole-rock geochemistry. However, magma mixing is a chaotic process and chemical equilibration is controlled by non-linear diffusive–advective processes unresolved by the study of bulk samples. Here we present textural observations, LA-(MC-)ICP-MS trace element and Sr–Nd isotopic data of accessory apatites and titanites from a hybrid granodiorite of the Neoarchean Matok pluton (South Africa), collected in a zone of conspicuous mixing between mafic and felsic magmas. Apatite grains mostly show a pronounced zoning in CL images, corresponding to abrupt changes in REE and HFSE concentrations recording their transfer through compositionally different melt domains during mixing. These grains crystallized early, at temperatures of 950–1000 °C. Titanite grains crystallized at temperatures of 820–900 °C (Zr-in-sphene thermometry). They show limited intra-grain chemical variations but huge inter-grain compositional scatter in REE and HFSE, pinpointing crystallization within a crystal mush, from isolated melt pockets having different composition from one another owing to incomplete chemical homogenization and variable Rayleigh fractionation. These chemical–textural characteristics, in combination with partitioning models and Polytopic Vector Analysis, point to “self-mixing” between co-genetic dioritic and granodioritic/granitic magmas. Both resulted from differentiation of mantle-derived mafic melts, showing that mixing does not necessarily involve magmas from contrasted (crust vs. mantle) sources. Systematic variations in εNd _t (?4.5 to ?2.5) and ⁸⁷Sr/⁸⁶Sr_(i) (0.703–0.707) of titanite and apatite grains/domains crystallized from the two magmas point to an isotopically inhomogeneous mantle source, which is not resolved by bulk-rock isotopic data. Interaction between the two magmas must have occurred at relatively high temperatures (ca. 900°C) so that their viscosity contrast remained low, allowing efficient mechanical mixing. Despite this, chemical homogenization was incomplete, as recorded by diffusive fractionation between REE–HFSE and Sr. Modelling thereof reveals that chemical exchange between the liquid phases of the two mixed magmas did not last more than a few tens to hundreds of years. The chemical equilibration between mixed magmas thus strongly depends on the considered elements and observational length scales.     

Foraging strategy of little auks under divergent conditions on feeding grounds

A dual foraging strategy (long versus short trips) has been described for some species of seabirds, such as petrels, albatrosses (Procellariiformes) and penguins (Sphenisciphormes). Such a strategy has recently been reported for little auks ( Alle alle ) from the central coast of west Spitsbergen, Svalbard. This has been explained as a response to poor trophic conditions close to the breeding colony, and better conditions further away (150 km). In the present study, we investigated the foraging strategy of little auks in Hornsund, southern Spitsbergen, during two seasons with contrasting oceanographic conditions. During 2004, foraging conditions for little auks were good: cold Arctic waters rich in profitable high-energy food were dominant in their feeding grounds. Conversely, during 2006 there was a great influx of warm Atlantic water in the feeding area, inducing poor foraging conditions. In both seasons we examined the pattern of foraging trip lengths automatically with a video camera (both adults from four nests in each year), and by direct non-stop observation of 20–54 individually marked birds. Our results showed that the dual strategy and the ratio of short and long trips were consistent, regardless of the conditions in the feeding grounds. This suggests that the strategy is inherent and may be crucial for the self-maintenance of adults.