Extreme Ultraviolet Variability Experiment (EVE) Multiple?EUV Grating Spectrographs (MEGS): Radiometric Calibrations and Results

The NASA Solar Dynamics Observatory (SDO), scheduled for launch in early 2010, incorporates a suite of instruments including the Extreme Ultraviolet Variability Experiment (EVE). EVE has multiple instruments including the Multiple Extreme ultraviolet Grating Spectrographs (MEGS) A, B, and P instruments, the Solar Aspect Monitor (SAM), and the Extreme ultraviolet SpectroPhotometer (ESP). The radiometric calibration of EVE, necessary to convert the instrument counts to physical units, was performed at the National Institute of Standards and Technology (NIST) Synchrotron Ultraviolet Radiation Facility (SURF III) located in Gaithersburg, Maryland. This paper presents the results and derived accuracy of this radiometric calibration for the MEGS A, B, P, and SAM instruments, while the calibration of the ESP instrument is addressed by Didkovsky et?al. (Solar Phys., 2010, doi: 10.1007/s11207-009-9485-8 ). In addition, solar measurements that were taken on 14 April 2008, during the NASA 36.240 sounding-rocket flight, are shown for the prototype EVE instruments.     

XUV Photometer System (XPS): Improved Solar Irradiance Algorithm Using CHIANTI Spectral Models

Solar soft X-ray (XUV) radiation is highly variable on all time scales and strongly affects Earth’s ionosphere and upper atmosphere; consequently, the solar XUV irradiance is important for atmospheric studies and for space weather applications. Although there have been several recent measurements of the solar XUV irradiance, detailed understanding of the solar XUV irradiance, especially its variability during flares, has been hampered by the broad bands measured in the XUV range. In particular, the simple conversion of the XUV photometer signal into irradiance, in which a static solar spectrum is assumed, overestimates the flare variations by more than a factor of two as compared to the atmospheric response to the flares. To address this deficiency in the simple conversion, an improved algorithm using CHIANTI spectral models has been developed to process the XUV Photometer System (XPS) measurements with its broadband photometers. Model spectra representative of quiet Sun, active region, and flares are combined to match the signals from the XPS and produce spectra from 0.1 to 40 nm in 0.1-nm intervals for the XPS Level 4 data product. The two XPS instruments are aboard NASA’s Solar Radiation and Climate Experiment (SORCE) and Thermosphere, Ionosphere, Mesosphere, Energetics, and Dynamics (TIMED) satellites. In addition, the XPS responsivities have been updated for the latest XPS data processing version. The new XPS results are consistent with daily variations from the previous simple conversion technique used for XPS and are also consistent with spectral measurements made at wavelengths longer than 27 nm. Most importantly, the XPS flare variations are reduced by factors of 2 – 4 at wavelengths shorter than 14 nm and are more consistent, for the first time, with atmospheric response to solar flares. Along with the details of the new XPS algorithm, several comparisons to dayglow and photoelectron measurements and model results are also presented to help verify the accuracy of the new XUV irradiance spectra.     

Direct observation of heavy metal-mineral association from the Clark Fork River Superfund Complex: Implications for metal transport and bioavailability

Two sets of samples from riverbeds and adjacent floodplains, separated by 80 river kilometers, were collected from the Clark Fork River Superfund Complex, Montana, (the largest Superfund site in the United States), and studied primarily with transmission electron microscopy (TEM) with several supporting techniques to determine heavy metal-mineral association. Seven of the eight samples studied were strongly influenced by material that once resided in mining and smelting dumps and impoundments; this material was transported downstream sometime during the last century and a half from the Butte/Anaconda areas. The eighth sample was from a deeper floodplain level and dates to premining days. The TEM observations afford a direct look, down to the nanometer level, at secondary mineral formation as a result of the breakdown of sulfides and silicates in the acid environment of this massive mine-drainage system. In the shallow, oxic floodplain sediments, heavy metals of concern in this system (As, Cu, Pb, and Zn) are taken up by the formation of sulfates (particularly Pb in jarosite), as well as hydrous metal oxides (As, Cu, Pb, and Zn in and on ferrihydrite, and a possibly new vernadite-like mineral). The oxides are long-lived in these systems, as they were also found in the anoxic riverbeds. Metals are also taken up by the formation of sulfides in sulfate-reducing environments as observed in the formation of nanoclusters of chalcopyrite and sphalerite. In all samples, clays make up between 5 and 20% of the sediment and carry significant amounts of Cu and Zn. The hydrous oxides, secondary sulfides, and clays provide several routes for metal transport downstream over long distances. Besides the potential bioavailability of heavy metals exchanged on and off the hydrous metal oxides and clays, nanometer-sized sulfides may also be highly reactive in the presence of biologic systems.     

Modeling of the 2011 Japan Tsunami: Lessons for Near-Field Forecast

During the devastating 11 March 2011 Japanese tsunami, data from two tsunami detectors were used to determine the tsunami source within 1.5 h of earthquake origin time. For the first time, multiple near-field tsunami measurements of the 2011 Japanese tsunami were used to demonstrate the accuracy of the National Oceanic and Atmospheric Administration (NOAA) real-time flooding forecast system in the far field. To test the accuracy of the same forecast system in the near field, a total of 11 numerical models with grids telescoped to 2 arcsec (~60 m) were developed to hindcast the propagation and coastal inundation of the 2011 Japanese tsunami along the entire east coastline of Japan. Using the NOAA tsunami source computed in near real-time, the model results of tsunami propagation are validated with tsunami time series measured at different water depths offshore and near shore along Japan’s coastline. The computed tsunami runup height and spatial distribution are highly consistent with post-tsunami survey data collected along the Japanese coastline. The computed inundation penetration also agrees well with survey data, giving a modeling accuracy of 85.5 % for the inundation areas along 800 km of coastline between Ibaraki Prefecture (north of Kashima) and Aomori Prefecture (south of Rokkasho). The inundation model results highlighted the variability of tsunami impact in response to different offshore bathymetry and flooded terrain. Comparison of tsunami sources inferred from different indirect methods shows the crucial importance of deep-ocean tsunami measurements for real-time tsunami forecasts. The agreement between model results and observations along Japan’s coastline demonstrate the ability and potential of NOAA’s methodology for real-time near-field tsunami flooding forecasts. An accurate tsunami flooding forecast within 30 min may now be possible using the NOAA forecast methodology with carefully placed tsunameters and large-scale high-resolution inundation models with powerful computing capabilities.     

Grain size partitioning of metals in contaminated,coarse-grained river floodplain sediment: Clark Fork River,Montana, U.S.A.

The traditional concept of the relationship between metal content and grain size assumes that the fine fraction carries most of the metals in natural sediments. This concept is supported in many cases by strong, significant linear relationships between total-sediment metal concentrations and percentages of various fine-size fractions. Such observations have led to development of methods to correct for the effects of grain size in order to accurately document geographical and temporal variations and identify trends in metal concentrations away from a particular source. Samples from the floodplain sediment of a large, coarse-grained river system indicates that these concepts do not hold for sediments contaminated by mining and milling wastes. In this particular system, the application of methods to correct for grain-size effects would lead to erroneous conclusions about trends of metals in the drainage. This indicates that the a priori application of grain-size correction factors limits interpretation of actual metal distributions and should not be used unless data indicate that correlations exist between metals and particular size fractions.     

Pd-oxide equilibration: a new experimental method for the direct determination of oxide activities in melts and minerals

We have developed a new technique for the experimental determination of the activities of oxide components in melts and minerals using the equilibrium between Pd alloy, oxygen, and the oxide component in the sample of interest. If a melt or mineral sample is equilibrated with Pd metal at fixed P, T, and f _{O 2}, a small amount of each constituent oxide will reduce to metal and dissolve into the Pd, forming an alloy. Due to the extraordinary stability of dilute alloys of Pd with Mg, Al, and Si, these metals dissolve into the Pd in amounts easily measured with the electron microprobe at f _{O 2} s that can be achieved with conventional gas-mixing techniques. We determined the activity-composition relations for Pd–Mg, –Al, and –Si alloys by equilibrating Pd at fixed f _{O 2}and T with periclase, corundum, and cristobalite (a _oxide1). Because Mg, Al, and Si have constant activity coefficients in Pd at low concentrations, the activity of the oxide of each metal is a simple function of the ratio of the concentration of the metal in Pd in equilibrium with the sample to that in Pd in equilibrium with the pure oxide. Therefore, if Pd plus a melt or mineral and Pd plus pure oxide standards are equilibrated simultaneously at fixed T and f _{O 2}, the precision of the analytical technique is the major limitation on the determination of oxide activities. We used Pd-oxide equilibration to explore activities in silicate melts analogous to Type B Ca–Al-rich inclusions (CAIs) from carbonaceous chondrites; the measured activities deviate systematically from model valves but agree to within 1–30%. The activities imply that Type B CAIs did not condense as liquids from a gas of solar composition, and that only very aluminous compositions are potential liquid condensates from the solar nebula. We also used Pd-oxide equilibration to determine the free energy of formation from the oxides, G _f ^/O , of the spinel end-member MgAl₂O₄ at 1150 to 1400°C to a precision of 2–19% (1). Because the technique reflects equilibration at high temperature, the G _f ^/O _s accurately represent the mineral with equilibrium Mg–Al disorder at temperature, a feature not true of drop calorimetric results because of partial reordering during quenching. Our results indicate more negative G _f ^Emphasis>/O and hence higher entropy of formation, S _f ^Emphasis>/O , than given in most compilations of thermodynamic data for spinel.Division of Geological and Planetary Sciences Contribution #5278     

Magnesium Isotopic Compositions of International Geological Reference Materials

Magnesium isotopic compositions are reported for twenty‐four international geological reference materials including igneous, metamorphic and sedimentary rocks, as well as phlogopite and serpentine minerals. The long‐term reproducibility of Mg isotopic determination, based on 4‐year analyses of olivine and seawater samples, was ≤ 0.07‰ (2s) for δ²⁶Mg and ≤ 0.05‰ (2s) for δ²⁵Mg. Accuracy was tested by analysis of synthetic reference materials down to the quoted long‐term reproducibility. This comprehensive dataset, plus seawater data produced in the same laboratory, serves as a reference for quality assurance and inter‐laboratory comparison of high‐precision Mg isotopic data.