Fluoride enrichment in aquifers of the Thar Desert: controlling factors and its geochemical modelling

The groundwater is the only source of drinking water in the Jaisalmer district of Rajasthan, India. The study area is a part of the Thar Desert. It has low and scattered population and no industries; hence, the possibility of anthropogenic input of fluoride is almost negligible. Thus, the enrichment of fluoride is only possible due to geochemical processes taking place in the groundwater of the region. A total of 100 groundwater samples, 34 samples from Jaisalmer and 66 samples from the Pokharan administrative blocks, were collected. It was observed that the concentration of fluoride ranged from 0.08 mg/l to 4.56 mg/l in the groundwater of Jaisalmer and from 0.56 mg/l to 6.60 mg/l in the samples of the Pokharan block. The alkaline condition (average pH, 7.7 ± 0.22 and 8.01 ± 0.25 in Jaisalmer and the Pokharan administrative block, respectively) in the region favours fluorite dissolution. Ion exchange, dissolution of calcite, semi‐arid climate, alkaline conditions and weathering are responsible for fluoride enrichment in the groundwater of the study area. Copyright © 2012 John Wiley & Sons, Ltd.     

Geochemical modeling,fate distribution,and risk exposure of potentially toxic metals in the surface sediment of the Shyok suture zone,northern Pakistan

The objective of the current study was to assess the contamination of potentially toxic metals (PTMs) in weathered surface sediment, along stream tributaries, and surrounding area of the river Chitral, Shyok suture zone district Chitral, Pakistan. To understand the geochemical features of 113 sediment, samples were collected from the Mirkhani and Drosh area. Then, different statistical tools including the geo-accumulation index (Igeo), cluster analysis (CA), principal component analysis (PCA), and ecological risk assessment (ERA) were used to unravel the origin, intensity, and exposure level of PTMs to control risk and restore the ecosystem within the study area. The results for the PTMs namely nickle (Ni), chromium (Cr), copper (Cu), cadmium (Cd), lead (Pb), zinc (Zn), and cobalt (Co) in Mirkhani and Drosh were in the following ranges: 10–150, 15–210, 15–250, 0.08–1.00, 10–70, 76–240 and 14–51; and 13–240, 17–210, 15–150, 0.08–0.60, 7–140, 47–150 and 13–36 mg/kg, respectively. In consequence, the potential ecological risk caused by Pb, Ni, Cu, Co, Cr, and Zn is reflected by the percentages of samples with an ecological risk index (ERI) greater than one which were 100%, 91%, 100%, 100%, 92%, and 100%, respectively. However, the overall mean decreasing order of ecological risk of PTMs in the district Chitral was Pb > Ni > Cu > Co > Cr > Zn > Cd. Moreover, the PCA yielded 78% variability which indicated that mineral prospects play an important role in the contamination of sediment. Furthermore, the mineral phases of Pb and Zn suggested supersaturation, while that for Cd revealed unsaturation. The results of Igeo, ERI, and CA indicated contamination of PTMs in the study area. The ERI value of Pb, Ni, Cu, Co, Cr, and Zn was higher than 1 suggesting an ecological risk in the study area. Moreover, the current study showed the dominance of geogenic contamination with major contributions from ultramafic rock and known mineral prospects. Therefore, contaminated sediment of the Shyok suture zone is extremely detrimental to the aquatic ecosystem of the study area.     

Hydrochemistry and sediment characteristics of polar periglacial lacustrine environments on Fisher Island and Broknes Peninsula,East Antarctica

Fisher Island and Broknes Peninsula in the Larsemann Hills constitute part of a polar lowland periglacial environment between marine and glacial ecosystems. The landscape is characterized by gently rolling hills and broad valleys interspersed with lakes formed in glacially scoured basins. We analyzed the physieochemical parameters and the ionic constituents of water samples from 10 lakes in each of these two locations. Our results showed considerable differences between the two regions and demon- strated the influence of lithology and processes including weathering, evaporation, and atmospheric precipitation. All major cations and anions in the lake waters showed positive correlations indicating balanced ionic concentrations. Unconsolidated sediments were sparsely distributed and scattered over glacial deposits, valley fills, and occasional moraine ridges. The type and rate of sedi- mentation was mainly controlled by surface run-off and aeolian influx. The sediment samples from lake beds and the catchment area on Fisher Island were immature and poorly to very poorly sorted, consisting of gravelly sand with negligible silt and finer fractions. Sediments had a polymodal grain size distribution with the two major populations lying between -2 and 1 phi and be- tween 0 and 1.5 phi. The sediments were lithic arenite to arkosic in composition and the microtextures imprinted over quartz grains were dominated by mechanical textures resulting from several stages of glacial crushing and grinding. The presence of deep disso- lution cavities, cryptocrystalline precipitation, and euhedral crystal growth signified the effect of chemical activity after the deposition of grains in the lacustrine environment.     

Geospatial and geostatistical approach for groundwater potential zone delineation

Over the past few decades, groundwater has become an essential commodity owing to increased demand as a result of growing population, industrialization, urbanization and so on. The water supply situation is expected to become more severe in the future because of continued unsustainable water use and projected change in hydrometeorological parameters due to climate change. This study is based on the integrated approach of remote sensing, geographical information system and multicriteria decision‐making techniques to determine the most important contributing factors that affect the groundwater resources and to delineate the groundwater potential zones. Ten thematic layers, namely, geomorphology, geology, soil, topographic elevation (digital elevation model), land use/land cover, drainage density, lineament density, proximity of surface water bodies, surface temperature and post‐monsoon groundwater depth, were considered for the present study. These thematic layers were selected for groundwater prospecting based on the literature; discussion with the experts of the Central Ground Water Board, Government of India; field observations; geophysical investigation; and multivariate techniques. The thematic layers and their features were assigned suitable weights on Saaty's scale according to their relative significance for groundwater occurrence. The assigned weights of the layers and their features were normalized by using the analytic hierarchy process and eigenvector method. Finally, the selected thematic maps were integrated using a weighted linear combination method to create the final groundwater potential zone map. The final output map shows different zones of groundwater potential, namely, very good (16%), good (35%), moderate (28%) low (17%) and very low (2.1%). The groundwater potential zone map was finally validated using the discharge and groundwater depth data from 28 and 98 pumping wells, respectively, which showed good correlation. Copyright © 2014 John Wiley & Sons, Ltd.     

Causes of landslide recurrence in a loess platform with respect to hydrological processes

Irrigation-induced landslide is a recurring problem in the Heifangtai loess platform of northwest China. The landslide sites are characterized by a concave topography. Numerical modeling indicates that the groundwater table at the past-landslide site rises more quickly than the other natural platform borders under irrigation conditions. This is consistent with the field observations that seepage of the groundwater appeared in the hollow is higher than that of lateral slopes. In order to investigate the response of soil behavior due to rise in groundwater table, stress-path tests were performed on undisturbed specimens. It has been observed that the increase in pore water pressure in loess can trigger soil liquefaction and eventually results in landslide. Hence, the concave past-landslide site is much more prone to landsliding, which contributed to the landslide recurrence.     

Characteristics of mountain glacier surge hazard: learning from a surge event in NE Pamir,China

Abnormal glacier movement is likely to result in canyon-type hazards chain, such as the barrier lake of Yarlung Zangbo Grand Canyon formed by glacier debris flow in October 2018 in China.Glacier hazard usually evolves from the glacier surge and may occur in a regular cycle. Understanding the characteristics and process of glacier surge is important for early hazard recognition and hazard assessment. Based on field investigations, remote sensing interpretations and SAR offset-tracking surveys, this study confirms a typical glacier surge in the northeast Pamir, and presents its characteristics and processes. "Black ice" mixed moraines choking uplift and overflowing lateral marine are the most important scenic characteristics, which were formed under the conditions of stagnant glacier downstream and abundant super-glacial moraine. Glacier movement event can be divided into a five-period cycle including quiescent, inoculation, initiation,fracture and decline. This surge event lasted for about 300 days, initiated in February 2015 developed extensive fracturing zone in spring and early summer at maximum velocity of 10±0.95 m/day, declined after August 2015 and recovered to quiescent status in October 2015 for the next inoculation. The average height of glacier "receiving" area increased by 20-40 m with 2.7-3.6×10~8 m~3 ice transferred from glacier "reservoir", and this volume accumulation again require 50-100 years for glacier mass balance which gives approximately 100 years frequency of the glacier surge. Nevertheless, long-period increase of precipitation and temperature were favorable for the occurrence, hydrological instability is the direct triggering mechanism, and while the Glacier Lake Outburst Flood(GLOF) hazards are unlikely to occur with this surge.     

A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.     

Outlining a stepwise,multi-parameter debris flow monitoring and warning system: an example of application in Aizi Valley,China

In recent years, the increasing frequency of debris flow demands enhanced effectiveness and efficiency of warning systems. Effective warning systems are essential not only from an economic point of view but are also considered as a frontline approach to alleviate hazards. Currently, the key issues are the imbalance between the limited lifespan of equipment, the relatively long period between the recurrences of such hazards, and the wide range of critical rainfall that trigger these disasters. This paper attempts to provide a stepwise multi-parameter debris flow warning system after taking into account the shortcomings observed in other warning systems. The whole system is divided into five stages. Different warning levels can be issued based on the critical rainfall thresholds. Monitoring starts when early warning is issued and it continues with debris flow near warning, triggering warning, movement warning and hazard warning stages. For early warning, historical archives of earthquake and drought are used to choose a debris flow-susceptible site for further monitoring. Secondly, weather forecasts provide an alert of possible near warning. Hazardous precipitation, model calculation and debris flow initiation tests, pore pressure sensors and water content sensors are combined to check the critical rainfall and to publically announce a triggering warning. In the final two stages, equipment such as rainfall gauges, flow stage sensors, vibration sensors, low sound sensors and infrasound meters are used to assess movement processes and issue hazard warnings. In addition to these warnings, community-based knowledge and information is also obtained and discussed in detail. The proposed stepwise, multi-parameter debris flow monitoring and warning system has been applied in Aizi valley China which continuously monitors the debris flow activities.