Origin of nickel in water solution of the chalk aquifer in the north of France and influence of geochemical factors

In the north of France, high registers of nickel are sometimes recorded within the chalk aquifer. In a confined context, the presence of pyrite in the covering clays or in the marcasite nodules encrusted in the clay may constitute a natural source of trace metals. With an objective of sanitary control, the limits of chemical contents regulating the quality of water destined for human consumption have been lowered by the European Framework Directive in the field of water policy (2000/60/EC). As a result, nickel limits have been reduced from 50 to 20 μg/l. The analyses, carried out on three water catchment fields in our area of study, were centred on variable parameters (Eh, O₂(d), pH, Conductivity, T°), major elements (SO₄, NO₃) and metals (Fe, Ni, Mn, Co). The acquired data enabled us to identify from one hand, the conditions which are presented within the site, special thanks to the evolution of nitrate and iron contents and on the other hand, the natural origin (geological) of nickel for two of the three sites studied based essentially on the evaluation of the Nickel/Cobalt ratio. Thus, on the first site, the evolution of nickel content and nitrate content showed the influence of the phenomenon of denitrification on the re-mobilisation of the nickel. Whereas on the second site, a high variation of total iron content and oxygen dissolved in solution highlighted a particular phenomenon of oxidation of the pyrite through molecular oxygen. Finally, the correlation with the sulphates clearly showed behaviour of the nickel, once released, that was entirely dependent on the phenomenon of adsorption on the iron and manganese hydroxides.     

Probabilistic seismic hazard zonation of Syria

Earthquake hazard maps for Syria are presented in this paper. The Peak Ground Acceleration (PGA) and the Modified Mercalli Intensity (MMI) on bedrock, both with 90% probability of not being exceeded during a life time of 50, 100 and 200 years, respectively are developed. The probabilistic PGA and MMI values are evaluated assuming linear sources (faults) as potential sources of future earthquakes. A new attenuation relationship for this region is developed. Ten distinctive faults of potential earthquakes are identified in and around Syria. The pertinent parameters of each fault, such as theb-parameter in the Gutenberg-Richter formula, the annual rate ₄ and the upper bound magnitudem ₁ are determined from two sets of seismic data: the historical earthquakes and the instrumentally recorded earthquake data (AD 1900–1992). The seismic hazard maps developed are intended for preliminary analysis of new designs and seismic check of existing civil engineering structures.     

Effect of aluminum and chromium on the germination and growth of two Vigna species

The study deals with the effect of metal toxicity (aluminum, chromium and combination of both the metals) on seed germination, root length, shoot length, seedling length and dry biomass of Vigna radiata and V. sinensis. Chromium adversely affected the seedling by significantly reducing the growth whereas aluminum did not show such effect in both the species. Percentage of germination was good in both the species at different concentration of treatment (aluminum, chromium and combined treatment). Shoot length was also not much affected in V. sinensis as it was greatly inhibited in V. radiata. Both the species showed the purpling of stem. Dry biomass of V. radiata showed positive effect than V. sinensis. However, dry biomass decreased to a lesser extent when treated with aluminum, chromium and combined treatment as compared to control.     

De nouveaux éléments structuraux du complexe aquifère profond du bassin du Rharb (Maroc) : implications hydrogéologiques

The Rharb basin is located in northwestern Morocco. It is a part of one of the most important hydrogeological basins of Morocco, and extends over some 4000 km². The nature of its Plio-Quaternary sedimentary fill and its structural and palaeoenvironmental contexts are reflected by great variations in aerial and temporal facies distribution. This distribution, in turn, is a direct cause of the observed complexity in the geometry of potentially water-bearing beds. In the present work, we present an image of potential new hydrogeological reservoirs and define new structures that partially explain their architecture. To cite this article: M. Kili et al., C. R. Geoscience 338 (2006).     

Tectonic and hydrodynamic control of landslides in the northern area of the Central Rif, Morocco

The northern edge of the Central Rif (Morocco) is subject to numerous landslides where mechanisms do not correspond to the classical models used by geomechanics specialists. It is necessary to adopt a multidisciplinary approach that combines geomorphology, geology, hydrogeology, and geotechnics in order to understand how such slope failures are generated, especially in a region with a heterogeneous structure characterised by significant lithological differences, severe fracturing, and thrust sheets where tectonic contacts play a major role in groundwater circulation. This report shows that these failures are essentially controlled by the tectonic contact separating the Tisirene and Chouamat thrust sheets and by subsurface hydrodynamic conditions. A model of spatial and temporal variations in the factor of safety is proposed.     

SWAT‐simulated hydrological impact of land‐use change in the Zanjanrood basin,Northwest Iran

Understanding the impacts of land‐use changes on hydrology at the watershed scale can facilitate development of sustainable water resource strategies. This paper investigates the hydrological effects of land‐use change in Zanjanrood basin, Iran. The water balance was simulated using the Soil and Water Assessment Tool (AVSWAT2000). Model calibration and uncertainty analysis were performed with sequential uncertainty fitting (SUFI‐2). Simulation results from January 1998 to December 2002 were used for parameter calibration, and then the model was validated for the period of January 2003 to December 2004. The predicted monthly streamflow matched the observed values: during calibration the correlation coefficient was 0·86 and the Nash–Sutcliffe coefficient 0·79, compared with 0·80 and 0·79, respectively, during validation. The model was used to simulate the main components of the hydrological cycle, in order to study the effects of land‐use changes in 1967, 1994 and 2007. The study reveals that during 1967 a 34·5% decrease of grassland with concurrent increases of shrubland (13·9%), rain‐fed agriculture (12·1%), bare ground (5·5%) irrigated agriculture (2·2%), and urban area (0·7%) led to a 33% increase in the amount of surface runoff and a 22% decrease in the groundwater recharge. Furthermore, the area of sub‐basins that was influenced by high runoff (14–28 mm) increased. The results indicate that the hydrological response to overgrazing and the replacing of rangelands (grassland and shrubland) with rain‐fed agriculture and bare ground (badlands) is nonlinear and exhibits a threshold effect. The runoff rises dramatically when more than 60% of the rangeland is removed. For groundwater this threshold lies at an 80% decrease in rangeland. Copyright © 2009 John Wiley & Sons, Ltd.     

Neogene aquifer properties specified through the interpretation of electrical sounding data,Salamiyeh region,central Syria

Twenty‐nine Schlumberger electrical soundings were carried out in the Salamiyeh region in Syria using a maximum current electrode separation of 1 km. Three soundings were made at existing boreholes for comparison. Aquifer parameters of hydraulic conductivity and transmissivity were obtained by analysing pumping test data from the existing boreholes. An empirical relationship between hydraulic conductivity determined from the pumping test and both resistivity and thickness of the Neogene aquifer has been established for these boreholes in order to calculate the geophysical hydraulic conductivity. A close agreement has been obtained between the computed hydraulic conductivity and that determined from the pumping test. The relationship established has, therefore, been generalized in the study area in order to evaluate hydraulic conductivity and transmissivity at all the points where geoelectrical measurements have been carried out. This generalization allows one to derive maps of the hydraulic conductivity and transmissivity in the study area based on geoelectrical measurements. These maps are important in future modelling processes oriented towards better exploitation of the aquifers. Copyright © 2006 John Wiley & Sons, Ltd.