Origin of nickel in water solution of the chalk aquifer in the north of France and influence of geochemical factors

In the north of France, high registers of nickel are sometimes recorded within the chalk aquifer. In a confined context, the presence of pyrite in the covering clays or in the marcasite nodules encrusted in the clay may constitute a natural source of trace metals. With an objective of sanitary control, the limits of chemical contents regulating the quality of water destined for human consumption have been lowered by the European Framework Directive in the field of water policy (2000/60/EC). As a result, nickel limits have been reduced from 50 to 20 μg/l. The analyses, carried out on three water catchment fields in our area of study, were centred on variable parameters (Eh, O₂(d), pH, Conductivity, T°), major elements (SO₄, NO₃) and metals (Fe, Ni, Mn, Co). The acquired data enabled us to identify from one hand, the conditions which are presented within the site, special thanks to the evolution of nitrate and iron contents and on the other hand, the natural origin (geological) of nickel for two of the three sites studied based essentially on the evaluation of the Nickel/Cobalt ratio. Thus, on the first site, the evolution of nickel content and nitrate content showed the influence of the phenomenon of denitrification on the re-mobilisation of the nickel. Whereas on the second site, a high variation of total iron content and oxygen dissolved in solution highlighted a particular phenomenon of oxidation of the pyrite through molecular oxygen. Finally, the correlation with the sulphates clearly showed behaviour of the nickel, once released, that was entirely dependent on the phenomenon of adsorption on the iron and manganese hydroxides.     

Seasonal variation of carbon fluxes in a sparse savanna in semi arid Sudan

Background

Large spatial, seasonal and annual variability of major drivers of the carbon cycle (precipitation, temperature, fire regime and nutrient availability) are common in the Sahel region. This causes large variability in net ecosystem exchange and in vegetation productivity, the subsistence basis for a major part of the rural population in Sahel. This study compares the 2005 dry and wet season fluxes of CO₂ for a grass land/sparse savanna site in semi arid Sudan and relates these fluxes to water availability and incoming photosynthetic photon flux density (PPFD). Data from this site could complement the current sparse observation network in Africa, a continent where climatic change could significantly impact the future and which constitute a weak link in our understanding of the global carbon cycle.

Results

The dry season (represented by Julian day 35–46, February 2005) was characterized by low soil moisture availability, low evapotranspiration and a high vapor pressure deficit. The mean daily NEE (net ecosystem exchange, Eq. 1) was -14.7 mmol d^-1 for the 12 day period (negative numbers denote sinks, i.e. flux from the atmosphere to the biosphere). The water use efficiency (WUE) was 1.6 mmol CO₂ mol H₂O^-1 and the light use efficiency (LUE) was 0.95 mmol CO₂ mol PPFD^-1. Photosynthesis is a weak, but linear function of PPFD. The wet season (represented by Julian day 266–273, September 2005) was, compared to the dry season, characterized by slightly higher soil moisture availability, higher evapotranspiration and a slightly lower vapor pressure deficit. The mean daily NEE was -152 mmol d^-1 for the 8 day period. The WUE was lower, 0.97 mmol CO₂ mol H₂O^-1 and the LUE was higher, 7.2 μmol CO₂ mmol PPFD^-1 during the wet season compared to the dry season. During the wet season photosynthesis increases with PPFD to about 1600 μmol m^-2s^-1 and then levels off.

Conclusion

Based on data collected during two short periods, the studied ecosystem was a sink of carbon both during the dry and wet season 2005. The small sink during the dry season is surprising and similar dry season sinks have not to our knowledge been reported from other similar savanna ecosystems and could have potential management implications for agroforestry. A strong response of NEE versus small changes in plant available soil water content was found. Collection and analysis of flux data for several consecutive years including variations in precipitation, available soil moisture and labile soil carbon are needed for understanding the year to year variation of the carbon budget of this grass land/sparse savanna site in semi arid Sudan.     

Probabilistic seismic hazard zonation of Syria

Earthquake hazard maps for Syria are presented in this paper. The Peak Ground Acceleration (PGA) and the Modified Mercalli Intensity (MMI) on bedrock, both with 90% probability of not being exceeded during a life time of 50, 100 and 200 years, respectively are developed. The probabilistic PGA and MMI values are evaluated assuming linear sources (faults) as potential sources of future earthquakes. A new attenuation relationship for this region is developed. Ten distinctive faults of potential earthquakes are identified in and around Syria. The pertinent parameters of each fault, such as theb-parameter in the Gutenberg-Richter formula, the annual rate ₄ and the upper bound magnitudem ₁ are determined from two sets of seismic data: the historical earthquakes and the instrumentally recorded earthquake data (AD 1900–1992). The seismic hazard maps developed are intended for preliminary analysis of new designs and seismic check of existing civil engineering structures.     

Effect of aluminum and chromium on the germination and growth of two Vigna species

The study deals with the effect of metal toxicity (aluminum, chromium and combination of both the metals) on seed germination, root length, shoot length, seedling length and dry biomass of Vigna radiata and V. sinensis. Chromium adversely affected the seedling by significantly reducing the growth whereas aluminum did not show such effect in both the species. Percentage of germination was good in both the species at different concentration of treatment (aluminum, chromium and combined treatment). Shoot length was also not much affected in V. sinensis as it was greatly inhibited in V. radiata. Both the species showed the purpling of stem. Dry biomass of V. radiata showed positive effect than V. sinensis. However, dry biomass decreased to a lesser extent when treated with aluminum, chromium and combined treatment as compared to control.     

De nouveaux éléments structuraux du complexe aquifère profond du bassin du Rharb (Maroc) : implications hydrogéologiques

The Rharb basin is located in northwestern Morocco. It is a part of one of the most important hydrogeological basins of Morocco, and extends over some 4000 km². The nature of its Plio-Quaternary sedimentary fill and its structural and palaeoenvironmental contexts are reflected by great variations in aerial and temporal facies distribution. This distribution, in turn, is a direct cause of the observed complexity in the geometry of potentially water-bearing beds. In the present work, we present an image of potential new hydrogeological reservoirs and define new structures that partially explain their architecture. To cite this article: M. Kili et al., C. R. Geoscience 338 (2006).     

Evaluation of three waterborne polymers as stabilizers for sandy soil

This study reports on waterborne polymer emulsion systems that were used for structural modification of sandy soils. The first emulsion used was a styrene-acrylic, copolymer emulsion; the second and third were vinyl-acrylic, copolymer-based emulsions. Specimens were prepared by adding different polymer emulsions to the sand and water in prescribed amounts. The performance of the different emulsion systems as sand stabilizers was estimated through measurement of the hydraulic conductivity and compressive strength. Measurements of hydraulic conductivity were conducted in a flexible membrane test apparatus. The hydraulic conductivity for the three emulsions decreased at different rates, with an increase in polymer content up to 3 wt. (i.e., % by weight). Additional increase of polymer content did not introduce significant decrease in hydraulic conductivity, and, at 5 wt.%, the three emulsions had essentially the same effect. Measurements made on dry cylindrical specimens disclosed remarkable enhancement in the mechanical behavior of the system. The compressive strength and modulus of elasticity of the examined emulsions increased with a higher concentration of polymer. Scanning electron microscope (SEM) revealed that the reduction in the permeability and the improved mechanical properties can be attributed to three dominant structural changes: the development of interconnecting ties between the sand particles, the development of adhesion between neighboring sand particles in contact, and the covering of the sand particles with a thin polymer film.     

Tectonic and hydrodynamic control of landslides in the northern area of the Central Rif, Morocco

The northern edge of the Central Rif (Morocco) is subject to numerous landslides where mechanisms do not correspond to the classical models used by geomechanics specialists. It is necessary to adopt a multidisciplinary approach that combines geomorphology, geology, hydrogeology, and geotechnics in order to understand how such slope failures are generated, especially in a region with a heterogeneous structure characterised by significant lithological differences, severe fracturing, and thrust sheets where tectonic contacts play a major role in groundwater circulation. This report shows that these failures are essentially controlled by the tectonic contact separating the Tisirene and Chouamat thrust sheets and by subsurface hydrodynamic conditions. A model of spatial and temporal variations in the factor of safety is proposed.     

Modelling the Shimokita deep coalbed biosphere over deep geological time: Starvation,stimulation, material balance and population models

Basin models can simulate geological, geochemical and geophysical processes and potentially also the deep biosphere, starting from a burial curve, assuming a thermal history and utilizing other experimentally obtained data. Here, we apply basin modelling techniques to model cell abundances within the deep coalbed biosphere off Shimokita Peninsula, Japan, drilled during Integrated Ocean Drilling Program Expedition 337. Two approaches were used to simulate the deep coalbed biosphere: (a) In the first approach, the deep biosphere was modelled using a material balance approach that treats the deep biosphere as a carbon reservoir, in which fluxes are governed by temperature-controlled metabolic processes that retain carbon via cell-growth and cell-repair and pass it back via cell-damaging reactions. (b) In the second approach, the deep biosphere was modelled as a microbial community with a temperature-controlled growth ratio and carrying capacity (a limit on the size of the deep biosphere) modulated by diagenetic-processes. In all cases, the biosphere in the coalbeds and adjacent habitat are best modelled as a carbon-limited community undergoing starvation because labile sedimentary organic matter is no longer present and petroleum generation is yet to occur. This state of starvation was represented by the conversion of organic carbon to authigenic carbonate and the formation of kerogen. The potential for the biosphere to be stimulated by the generation of carbon-dioxide from the coal during its transition from brown to sub-bituminous coal was evaluated and a net thickness of 20 m of lignite was found sufficient to support an order of magnitude greater number of cells within a low-total organic carbon (TOC) horizon. By comparison, the stimulation of microbial populations in a coalbed or high-TOC horizon would be harder to detect because the increase in population size would be proportionally very small.