Trace metals in the Western Pacific: temporal and spatial variability in the concentrations of Cd, Cu, Mn and Ni

Profiles of total dissolvable Cd, Cu, Mn and Ni are reported for samples collected from the southwest Pacific in 1989, from the western equatorial Pacific along 155°E at 5°S, 0° and 5°N in 1990 and 1993, and along the equator from 143°E to 152°E and in the Bismarck Sea in 1997 and 2000. Profiles of Cd along 155°E in 1990 and along the equator were essentially the same but, in 1993, Cd values at 5°N were higher by a factor of about 1.5–2 than at 5°S over the depth range 500–1500 m. Similar, but less pronounced, differences were observed for PO₄ and Ni. Cd and Ni were both strongly correlated with PO₄, and an even stronger correlation was found between Ni and Cd. The concentration of Ni did not fall below ≈2 nmolkg⁻¹, even in the nitrate-depleted waters of the western equatorial Pacific, where primary production is strongly dependent on recycled nitrogen (mainly ammonia and urea). It is proposed that this residual Ni is not bioavailable and that Ni could be biolimiting, since the metabolism of urea requires the nickel-containing enzyme urease. The impact of the Sepik River on Cd, Cu and Ni concentrations was small but elevated concentrations of Mn were observed near the Sepik River and close to the coast suggesting that the rivers and sediments on the north coast of New Guinea are a significant local source of Mn to the Bismarck Sea. Simple mass balance calculations show that the elevated levels of Mn observed in the Equatorial Undercurrent cannot be due to input from the rivers of New Guinea and they were attributed to the trapping of particulate matter due to strong current shear. A strong hydrothermal source of Mn was observed in the central Bismarck Sea.     

An original semi‐discrete approach to assess gas conductivity of concrete structures

For civil engineering structures with a tightness role, structural permeability is a key issue. In this context, this paper presents a new proposition of a numerical modelling of leakage rate through a cracked concrete structure undergoing mode I cracking. The mechanical state of the material, considered in the framework of continuum mechanics based on finite element modelling, is described by means of the stress‐based nonlocal damage model which takes into account the stress state and provides realistic local mechanical fields. A semi‐discrete method based on the strong discontinuity approach to estimate crack opening is then considered in the post‐treatment phase. Using a Poiseuille's like relation, the coupling between the mechanical state of the material and its dry gas conductivity is performed. For validation purposes, an original experimental campaign is conducted on a dry concrete disc loaded in a splitting setup. During the loading, gas conductivity and digital image correlation analysis are performed. The comparison with the 3D experimental mechanical global response highlights the performance of the mechanical model. The comparison between crack openings measured by digital image correlation and estimated by the strong discontinuity method shows a good agreement. Finally, the results of the semi‐discrete approach coupled with the gas conductivity compared with experimental data show a good estimation of the structural conductivity. Consequently, if the mechanical problem is well modelled at the global scale, then the proposed approach provides good estimation of gas conductivity. Copyright © 2016 John Wiley & Sons, Ltd.     

Were merely storm-landslides driven by the 2015-2016 Niño in the Mendoza River valley?

Since Holocene time, above-mean precipitations recorded during the El Niño warm ENSO phase have been linked to the occurrence of severe debris flows in the arid Central Andes. The 2015–2016 El Niño, for its unusual strength, began driving huge and dangerous landslides in the Central Andes (32°) in the recent South Hemisphere summer. The resulting damages negatively impacted the regional economy. Despite this, causes of these dangerous events were ambiguously reported. For this reason, a multidisciplinary study was carried out in the Mendoza River valley. Firstly, a geomorphological analysis of affected basins was conducted, estimating morphometric parameters of recorded events such as velocity, stream flow, and volume. Atmospheric conditions during such events were analyzed, considering precipitations, snow cover, temperature range, and the elevation of the zero isotherm. Based on our findings, the role of El Niño on the slope instability in the Central Andes is more complex in the climate change scenario. Even though some events were effectively triggered by intense summer rainstorm following expectations, the most dangerous events were caused by the progressive uplifting of the zero isotherm in smaller basins where headwaters are occupied by debris rock glaciers. Our research findings give light to the dynamic coupled system ENSO–climate change–landslides (ECCL) at least in this particular case study of the Mendoza River valley. Landslide activity in this Andean region is driven by wetter conditions linked to the ENSO warm phase, but also to progressive warming since the twentieth century in the region. This fact emphasizes the future impact of the natural hazards on Andean mountain communities.     

Activity and kinematic behaviour of deep-seated landslides from PS-InSAR displacement rate measurements

Large landslides and deep-seated gravitational slope deformations (DSGSD) represent an important geo-hazard in relation to the deformation of large structures and infrastructures and to the associated secondary landslides. DSGSD movements, although slow (from a few millimetres to several centimetres per year), can continue for very long periods, producing large cumulative displacements and undergoing partial or complete reactivation. Therefore, it is important to map the activity of such phenomena at a regional scale. Ground surface displacements at DSGSD typically range close to the detection limit of monitoring equipment but are suitable for synthetic aperture radar (SAR) interferometry. In this paper, permanent scatterers (PSInSAR?) and SqueeSAR? techniques are used to analyse the activity of 133 DSGSD, in the Central Italian Alps. Statistical indicators for assigning a degree of activity to slope movements from displacement rates are discussed together with methods for analysing the movement and activity distribution within each landslide. In order to assess if a landslide is active or not, with a certain degree of reliability, three indicators are considered as optimal: the mean displacement rate, the activity index (ratio of active PS, displacement rate larger than standard deviation, overall PS) and the nearest neighbor ratio, which allows to describe the degree of clustering of the PS data. According to these criteria, 66% of the phenomena are classified as active in the monitored period 1992–2009. Finally, a new methodology for the use of SAR interferometry data to attain a classification of landslide kinematic behaviour is presented. This methodology is based on the interpretation of longitudinal ground surface displacement rate profiles in the light of numerical simulations of simplified failure geometries. The most common kinematic behaviour is rotational, amounting to 41 DSGSDs, corresponding to the 62.1% of the active phenomena.     

Crystal-chemical examination of natural diopsides: Some geometrical indications of Si-Ti tetrahedral substitution

Summary The crystal structures of 20 natural diopsides have been refined. For some samples, microprobe analyses show a Si deficiency in the tetrahedron with no A1 present; this suggests that some Ti⁴⁺ may enter the tetrahedral site. Geometrical variations in these samples with respect to the others are discussed in the light of this Si Ti⁴⁺ substitution. The volumes of their M1 sites are larger because of the absence of R³⁺ cations, the octahedron being very regular; in the same way, the volumes of M2 sites of these samples are greater not because of different site occupancies but because of significant charge modifications around the O3 and O1 oxygens, caused by the tetrahedral site. The low distortion of M1 site and the lengthening of (M2-O1) and M2-O3 bond lengths are a clue to the presence of small amounts of Ti at the tetrahedral site.

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Kristallchemische untersuchung natürlicher diopside: Geometrische hinweise für tetraedrische Si-Ti substitution

Zusammenfassung Die Kristallstrukturen von zwanzig natürlichen Diopsiden sind verfeinert worden. In einigen Proben zeigen Mikrosondenanalysen zu geringe Si-Werte im Tetraeder ohne daß A1 anwesend wäre. Dies weist darauf hin, daß Ti⁴⁺ Tetraederplätze einnehmen könnte. Geometrische Variationen in diesen Proben werden im Lichte der genannten Substitution diskutiert. Die Volumen von M1-Plätzen sind größer wegen der Abwesenheit von R³⁺ Kationen, wobei das Oktaeder sehr gleichmäßig ist. Die Volumina von M2-Plätzen sind noch größer nicht wegen verschiedener Besetzungen dieser Plätze sondern wegen signifikanter Ladungsmodifikationen im Bereich von O3 und O1 Sauerstoffen, die durch die tetraedrische Position bewirkt wird. Die geringe Distortion der M1-Plätze und die Verlängerung der (M2-O1) und (M2-O3) Abstände weisen auf die Anwesenheit von geringen Titangehalten auf Tetraederplätzen hin.

     

Petrogenesis of calc-alkaline,shoshonitic and associated ultrapotassic Oligocene volcanic rocks from the Northwestern Alps,Italy

Along the Western Alps there is geological evidence of late-Alpine (Oligocene) magmatic activity which clearly postdates the Lepontine (Eocene-early Oligocene) metamorphism and related deformation of the Alpine nappe pile. This magmatic activity was notably delayed in relation to the most important convergent processes and may be related to buoyancy of lithosphere, tensional tectonics and thermal updoming subsequent to the collision between the Eurasian and African plates. The geochemical features of the rocks and the geophysical characteristics of the Alpine chain, suggest that: (a) shoshonitic and calcalkaline melts may have been generated by partial melting of metasomatized peridotitic material and subsequent fractional crystallization and crustal contamination; silicic andesites and latites, however, could have been also derived from metasomatized eclogite or deep continental crust material; (b) the ultrapotassic lamprophyres with high K, P, LREE, Th, Zr, U and high ⁸⁷Sr/⁸⁶Sr ratios were generated by partial melting of strongly metasomatized mantle; the varied Sr-isotopic ratios may partially also reflect additional radiogenic component from the continental crust following magma segregation from the source.     

Coupling of oceanic and continental crust during Eocene eclogite-facies metamorphism: evidence from the Monte Rosa nappe,western Alps

High precision U–Pb geochronology of rutile from quartz–carbonate–white mica–rutile veins that are hosted within eclogite and schist of the Monte Rosa nappe, western Alps, Italy, indicate that the Monte Rosa nappe was at eclogite-facies metamorphic conditions at 42.6 ± 0.6 Ma. The sample area [Indren glacier, Furgg zone; Dal Piaz (2001) Geology of the Monte Rosa massif: historical review and personal comments. SMPM] consists of eclogite boudins that are exposed inside a south-plunging overturned synform within micaceous schist. Associated with the eclogite and schist are quartz–carbonate–white mica–rutile veins that formed in tension cracks in the eclogite and along the contact between eclogite and surrounding schist. Intrusion of the veins at about 42.6 Ma occurred at eclogite-facies metamorphic conditions (480–570°C, >1.3–1.4 GPa) based on textural relations, oxygen isotope thermometry, and geothermobarometry. The timing of eclogite-facies metamorphism in the Monte Rosa nappe determined in this study is identical to that of the Gran Paradiso nappe [Meffan-Main et al. (2004) J Metamorphic Geol 22:261–281], confirming that these two units have shared the same Alpine metamorphic history. Furthermore, the Gran Paradiso and Monte Rosa nappes underwent eclogite-facies metamorphism within the same time interval as the structurally overlying Zermatt-Saas ophiolite [∼50–40 Ma; e.g., Amato et al. (1999) Earth Planet Sci Lett 171:425–438; Mayer et al. (1999) Eur Union Geosci 10:809 (abstract); Lapen et al. (2003) Earth Planet Sci Lett 215:57–72]. The nearly identical P–T–t histories of the Gran Paradiso, Monte Rosa, and Zermatt-Saas units suggest that these units shared a common Alpine tectonic and metamorphic history. The close spatial and temporal associations between high pressure (HP) ophiolite and continental crust during Alpine orogeny indicates that the HP internal basement nappes in the western Alps may have played a key role in exhumation and preservation of the ophiolitic rocks through buoyancy-driven uplift. Coupling of oceanic and continental crust may therefore be critical in preventing permanent loss of oceanic crust to the mantle.     

Modelling of mantle postglacial relaxation in axisymmetric geometry with a composite rheology and a glacial load interpolated by adjusted spherical harmonics analysis

Although studies on glacial isostatic adjustment usually assume a purely linear rheology, we have previously shown that mantle relaxation after the melting of Laurentide ice sheet is better described by a composite rheology including a non-linear term. This modelling is, however, based on axially symmetric geometry and glacial forcing derived from ICE-3G and suffers from a certain amount of arbitrariness in the definition of the ice load. In this work we apply adjusted spherical harmonics analysis to interpolate the ice thicknesses of ICE-3G and ICE-1 glaciological models. This filters out the non-axisymmetric components of the ice load by considering only the zonal terms in the spherical harmonics expansion. The resulting load function is used in finite-element simulation of postglacial rebound to compare composite versus purely linear rheology. Our results confirm that composite rheology can explain relative sea level (RSL) data in North America significantly better than a purely linear rheology. The performance of composite rheology suggests that in future investigations, it may be better to use this more physically realistic creep law for modelling mantle deformation induced by glacial forcing.     

Tertiary age and paleostructural inferences of the eclogitic imprint in the Austroalpine outliers and Zermatt–Saas ophiolite, western Alps

The Austroalpine Sesia-Lanzo inlier and upper Austroalpine Dent Blanche, Mt. Mary and Pillonet outliers occur on top of the western-Alpine orogenic wedge and, as a whole, override the structurally composite ophiolitic Piemonte zone. Instead, the Mt. Emilius, Glacier-Rafray, Etirol-Levaz and other lower Austroalpine eclogitic outliers are inserted within the Piemonte zone, between its upper (Combin) and lower (Zermatt-Saas) tectonic elements, or within the latter. Rb-Sr dating on phengitic micas show that the eclogitic imprint in the lower Austroalpine outliers, conventionally regarded as Late Cretaceous by comparison with the Sesia-Lanzo inlier, is of Eocene age (49-40 Ma), like the underlying Zermatt-Saas ophiolite (45-42 Ma) between the Aosta valley and Gran Paradiso massif. ⁴⁰Ar-³⁹Ar plateau ages on the same mica concentrates of the ophiolitic Zermatt-Saas nappe (46-43 Ma) are consistent with Rb-Sr dating, whereas that on the Austroalpine Glacier-Rafray klippe (92 Ma) is influenced by argon excess. The lower Austroalpine outliers underwent the subduction metamorphism concurrently with the Zermatt-Saas nappe, 20-25 Ma later than the eclogitic Sesia-Lanzo inlier and blueschist Pillonet klippe. The temporal gap and present intra-ophiolitic position mean that the lower Austroalpine outliers were probably derived from an intraoceanic extensional allochthon (Mt. Emilius domain) stranded inside the Piemonte-Ligurian ocean far from the Dent Blanche-Sesia domain and Adriatic margin.     

Eruptive history and petrologic evolution of the Albano multiple maar (Alban Hills, Central Italy)

A comprehensive volcanological study of the Albano multiple maar (Alban Hills, Italy) using (i) ⁴⁰Ar/³⁹Ar geochronology of the most complete stratigraphic section and other proximal and distal outcrops and (ii) petrographic observations, phase analyses of major and trace elements, and Sr and O isotopic analyses of the pyroclastic deposits shows that volcanic activity at Albano was strongly discontinuous, with a first eruptive cycle at 69±1 ka producing at least two eruptions, and a second cycle with two peaks at 39±1 and 36±1 ka producing at least four eruptions. Contrary to previous studies, we did not find evidence of magmatic or hydromagmatic eruptions younger than 36±1 ka. The activity of Albano was fed by a new batch of primary magma compositionally different from that of the older activity of the Alban Hills; moreover, the REE and ⁸⁷Sr/⁸⁶Sr data indicate that the Albano magma originated from an enriched metasomatized mantle. According to the modeled liquid line of descent, this magma differentiated under the influence of magma/limestone wall rock interaction. Our detailed eruptive and petrologic reconstruction of the Albano Maar evolution substantiates the dormant state of the Alban Hills Volcanic District. Electronic Supplementary Material Supplementary material is available for this article at Editorial responsibility: J. Donnelly-Nolan An erratum to this article can be found at