Re-Os isotope systematics and fractionation of siderophile elements in metal phases from CBa chondrites

We report Os isotope compositions of metal grains in two CB_a chondrites (Bencubbin and Gujba) determined using a micromilling sampling coupled with thermal ionization mass spectrometry, together with the abundances of major and trace siderophile elements obtained by electron probe microanalysis and femtosecond laser ablation inductively coupled plasma–mass spectrometry. The CB_a metal grains presented ¹⁸⁷Os/¹⁸⁸Os ratios akin to carbonaceous chondrites with limited variations (0.1257–0.1270). Most of the CB_a metal grains were scattered along a ¹⁸⁷Re-¹⁸⁷Os reference isochron of IIIAB iron meteorites, indicating that the CB_a metals experienced limited Re-Os fractionation at the time of their formation. The Re/Os ratios of sampling spots for the CB_a metals, recast from the observed ¹⁸⁷Os/¹⁸⁸Os ratios, had a positive correlation with their Os/Ir ratios. In addition, the metal grains showed a positive correlation in a Pd/Fe versus Ni/Fe diagram. These correlations suggest that the CB_a metal grains have formed via equilibrium condensation or evaporation from a gaseous reservoir at ~10⁻⁴ bar with enhanced metal abundances. Compared to the Bencubbin metals, the Gujba metals are characterized by having systematically lower Pd/Fe and Ni/Fe ratios that span subchondritic values. Such a difference was most likely induced by the compositionally heterogeneous impact plume from which the metals were condensed.     

Upwelling of Deep-seated Fluid in the Sikhote-Alin Region,Far East of the Eurasian Plate

Aquatic Geochemistry - Spring waters with high-pCO2 content are widely distributed in the Sikhote-Alin region in Russia. Mukhen spa is one such spring located in the northern Sikhote-Alin region....     

Mixing relations of the howardite‐eucrite‐diogenite suite: A new statistical approach of independent component analysis for the Dawn mission

Dawn has recently revealed that the surface of Vesta is heterogeneously covered by polymictic regoliths represented by mixtures of howardite, eucrite, and diogenite (HED) meteorites. Mixing relations of the HED suite are examined here using a new computational statistical approach of independent component analysis (ICA). We performed eight‐component ICA (Si, Ti, Al, Cr, Fe, Mn, Mg, and Ca) for 209 HED bulk‐rock compositions. The ICA results indicate that the HED bulk‐rock compositions can be reduced into three independent components (IC) and these IC vectors can reasonably explain compositional variation, petrographic observations, and the mixing relations of the HED suite. The IC‐1 vector represents a eucrite variation that extends from cumulate eucrite toward main‐group (MG) and incompatible‐element enriched eucrites. The IC‐2 vector represents a compositional variation of howardites that extends from diogenites to MG‐eucrites, indicating the well‐known two‐component mixing trend of diogenite and eucrite. The IC‐3 vector represents a compositional variation defined by diogenites and olivine‐bearing diogenites, suggesting mixing of olivine and orthopyroxene. Among the three ICs, the diogenite‐eucrite mixing trend IC‐2 is most statistically robust and dominates the compositional variations of the HED suite. Our ICA study further indicates that the combination of only three elements (Mg, Si, and Fe) approximates the eight‐component ICA model, and that the limited number of resolvable γ‐ray spectra obtained by the Dawn mission possibly discriminates olivine lithologies from the olivine‐free regolith breccias on the surface of Vesta.     

Generation of adakites in a cold subduction zone due to double subducting plates

Adakites have been found in various tectonic settings, since the first report for the distinct lavas as a product of slab melting in Adak Island by Kay (J Volcanol Geotherm Res 4:117–132, 1978). In this study, we present geochemical data for an ‘adakite’ and ‘adakitic rock’ suite in central Japan with a cold subduction environment due to the two overlapping subducting plates: the Pacific plate and the Philippine sea plate. Based on the major, trace and isotopic compositions of the rocks, elemental transport from initial slab inventory at the trench to the volcanic rocks as a final product is quantitatively analyzed, considering the thermal structure, slab dehydration, elemental mobility, slab-fluid migration and melting of fluid-added mantle. The analysis demonstrates a large compositional impact of slab-fluid in the arc magma generation in central Japan. The melting conditions have been also estimated inversely by optimizing the predicted magma composition to the observed composition of volcanic rock, with the two parameters: the degree of melting and the proportion of spinel and garnet lherzolites involved in melting. Consequently, a moderately low degree of near-solidus melting of dominantly garnet lherzolite with a high fluid flux from the two overlapping slabs beneath the region has been argued to be responsible for the compositional characteristics, including the adakitic signatures, of the studied rocks. These results imply that the geochemical approach may provide useful constraints on the P–T condition of melting in the mantle wedge and the thermal structure in subduction zones, being complementary to the geophysical approach.     

Tectonic reconstruction of batholith formation based on the spatiotemporal distribution of Cretaceous–Paleogene granitic rocks in southwestern Japan

The spatiotemporal distribution of Cretaceous–Paleogene granitic rocks in southwestern Japan is investigated to understand the origin of the granitic batholith belt and to reconstruct the tectonic setting of emplacement. New U–Pb zircon ages for 92 samples collected from a region measuring 50 km (E–W) by 200 km (N–S) reveals a stepwise northward younging of granitic rocks aged between 95 and 30 Ma with an age‐data gap between 60 and 48 Ma. Based on the spatiotemporal distribution of granite ages, we examine two plausible models to explain the pattern of magmatic activity: (i) subduction of a segmented spreading ridge and subsequent slab melting (ridge‐subduction model), and (ii) subduction with a temporally variable subduction angle and corresponding spatial distribution of normal arc magmatism (subduction angle model). We optimize the model parameters to fit the observed magmatism in time and space, and compare the best‐fit models. As to ridge subduction model, the best‐fit solution indicates that the spreading ridge started to subduct at approximately 100 Ma, and involved a 45‐km‐wide section of the ridge segment, a subduction obliquity of 30°, and a slow migration velocity (～1.6 cm/y) of the ridge. These values are within the ranges of velocities observed for present‐day ridge subduction at the Chile trench. On the other hand, the best‐fit solution of subduction angle model indicates that the subduction angle decreases stepwise from 37° at 95 Ma, 32° at 87 Ma, 22° at 72 Ma, to 20° at 65 Ma, shifting magmatic region towards the continental side. These results and comparison, together with constraints on the geometry of the tectonic setting provided by previous studies, suggest that the ridge subduction model better explains the limited duration of magmatism, although both models broadly fit the data and cannot be ruled out.     

Contribution of slab-fluid in arc magmas beneath the Japan arcs

Identifying the amount and composition of slab-derived fluid and its spatial variation is key to quantifying fluid processes in subduction zones. Based on the isotopic systematics of arc lavas, we found regional variations over the Japan arcs in terms of the amount and composition of slab-derived fluid added to the melting source region. The average amounts of slab-derived fluid differ among the arcs: 2.6 wt.% for Central Japan, 0.69 wt.% for Ryukyu, 0.17 wt.% for NE Japan, and 0.12 wt.% for both Kurile and Izu–Bonin. These differences may be attributed to the arc setting (oceanic or continental) and the geometry of the slabs. Contribution of sediment involved in the slab-derived fluid is dominant in NE Japan compared to the Izu–Bonin and Central Japan arcs. This could be attributed to mechanical features such as fractures near the subducting plate surface, in addition to the arc setting and the slab geometry. Therefore, the amount and composition of slab-derived fluid are thought to be controlled not only by the thermal conditions, but also by the tectonic and mechanical features around the subduction zone. On top of the variability of slab-derived fluid, the mantle wedge shows the regional variation in terms of proportion of the Pacific-type and Indian-type MORB-source mantle components, which also contributes to the compositional variations of arc magmas.     

Geochemical composition of dykes along the Cameroon Line (CL): Petrogenesis and similarities with the Central Atlantic Magmatic Province

We report whole-rock geochemistry and Sr–Nd–Pb isotopic compositions of mafic dykes intruded in the Precambrian granito-gneissic basement complex, exposed at Nyos, Batibo, Dschang and Foumban on the Cameroon Line. The dykes are alkaline (Batibo), transitional (Foumban), and subalkaline (Nyos, Batibo and Dschang) with SiO₂ of 45–54 wt% and MgO of 2–9 wt%, similar to dykes reported in other areas of the Cameroon Line (CL) and the Central Atlantic Magmatic Province (CAMP). The abundances of rare earth elements (REE) and the Primitive Mantle normalised patterns for the Nyos, Batibo and Dschang dykes are similar to those of MORB, indicating that the dykes formed at shallower depths by a higher degree of partial melting relative to the Foumban dykes and the alkaline lavas of the CL. The transitional basaltic dykes with steeper REE patterns have their sources at deeper levels in the lithospheric mantle, possibly the garnet-spinel transition zone and were generated by a lower degree partial melting of the lithospheric and plume components. The Nyos and Batibo subalkaline dykes show similar isotopic compositions with a spectrum extending from depleted (DMM-like) to enriched (EM1-like) mantle, indicating the similarity in their source components. The Dschang dykes show distinct isotopic characteristics with relatively unradiogenic Nd-Pb isotope compositions compared to the Batibo and Nyos dykes. The Foumban transitional dykes with characteristic wide ranges in Sr-Nd-Pb isotopic compositions reveal varying contributions from enriched mantle components (EM1 and EM2) in addition to its plume signature similar to those of CL lavas. The Nyos and Batibo dykes alongside other dykes on the CL have low TiO₂ abundances (<2 wt%), negative PM-normalised Nb-anomalies, and moderately to strongly enriched REE patterns, and isotopic composition that overlaps with those of CAMP, suggesting a similar lithospheric origin.     

Progressive evolution of whole‐rock composition during metamorphism revealed by multivariate statistical analyses

The geochemical evolution of metamorphic rocks during subduction‐related metamorphism is described on the basis of multivariate statistical analyses. The studied data set comprises a series of mapped metamorphic rocks collected from the Sanbagawa metamorphic belt in central Shikoku, Japan, where metamorphic conditions range from the pumpellyite–actinolite to epidote–amphibolite facies. Recent progress in computational and information science provides a number of algorithms capable of revealing structures in large data sets. This study applies k‐means cluster analysis (KCA) and non‐negative matrix factorization (NMF) to a series of metapelites, which is the main lithotype of the Sanbagawa metamorphic belt. KCA describes the structures of the high‐dimensional data, while NMF provides end‐member decomposition which can be useful for evaluating the spatial distribution of continuous compositional trends. The analysed data set, derived from previously published work, contains 296 samples for which 14 elements (Si, Ti, Al, Fe, Mn, Mg, Ca, Na, K, P, Rb, Sr, Zr and Ba) have been analysed. The KCA and NMF analyses indicate five clusters and four end‐members, respectively, successfully explaining compositional variations within the data set. KCA indicates that the chemical compositions of metapelite samples from the western (Besshi) part of the sampled area differ significantly from those in the east (Asemigawa). In the west, clusters show a good correlation with the metamorphic grade. With increasing metamorphic grade, there are decreases in SiO₂ and Na₂O and increases in other components. However, the compositional change with metamorphic grade is less obvious in the eastern area. End‐member decomposition using NMF revealed that the evolutional change of whole‐rock composition, as correlated with metamorphic grade, approximates a stoichiometric increase of a garnet‐like component in the whole‐rock composition, possibly due to the precipitation of garnet and effusion of other components during progressive dehydration. Thermodynamic modelling of the evolution of the whole‐rock composition yielded the following results: (1) the whole‐rock composition at lower metamorphic grade favours the preferential crystallization of garnet under the conditions of the garnet zone, with biotite becoming stable together with garnet in higher‐grade rock compositions under the same P–T conditions; (2) with higher‐grade whole‐rock compositions, more H₂O is retained. These results provide insight into the mechanism suppressing dehydration under high‐P metamorphic conditions. This mechanism should be considered in forward modelling of the fluid cycle in subduction zones, although such a quantitative model has yet to be developed.