An ecosystem model with iron limitation of primary production in the equatorial Pacific at 140°W

We construct a one-dimensional ecosystem model (nitrate, ammonium, phytoplankton, zooplnakton and detritus) with simple physics and biology in order to focus on the structural relations and intrinsic properties of the food web that characterizes the biological regime in the central equatorial Pacific at 140°W. When possible, data collected during the EgPac and other cruises were used to calibrate model parameters for two simulations that differ in the limiting nutrient, i.e. nitrogen or iron. Both simulations show annual results in good agreement with the data, but phytoplankton biomass and primary production show a more pronounced annual variability when iron is used as the limiting nutrient. This more realistically reproduces the variability of biological production and illustrates the greater coupling between vertical physical processes and biological production when the limiting nutrient is iron rather than nitrogen. The iron simulation also illustrates how iron supply controls primary production variability, how grazingbalances primary production and controls phytoplankton biomass, and how both iron supply and grazingcontrol primary production. These results suggest that it is not possible to capture primary production variability in the central equatorial Pacific with biological models using nitrogen as the limiting nutrient. Other indirect results of this modeling study were: (1) partitioning of export production between dissolved and particulate matter is almost equal, suggesting that the importance of DOC export may have been previously overestimated; (2) lateral export of live biomass has to be taken into account in order to balance the nitrogen budget on the equator at 140°W; and (3) preferential uptake of ammonium (i.e. nitrate uptake inhibition by ammonium) associated with high regeneration of nitrogen (low f ratio as a consequence of the food web structure imposed by iron limitation) largely accounts for the surface build-up of upwelled nitrate.     

Water fluxes through the Cretan Arc Straits, Eastern Mediterranean Sea: March 1994 to June 1995

Five research cruises were undertaken incorporating ADCP sections along the Cretan Arc Straits and CTD surveys covering the entire area of the Straits and the Cretan Sea. In addition, six moorings (with 15 current meters) were deployed within the Straits, which monitored flows in the surface (50 m), intermediate (250 m), and deep (50 m from the bottom) layers. The ADCP, CM, and CTD datasets enable the derivation of water transports through the Cretan Arc Straits to be assessed. Flow structure through the Cretan Arc Straits is not the typical flow regime with a surface inflow and deep outflow, instead there is a persistent deep outflow of Cretan Deep Water (CDW) (σ_θ>29.2) with an annual mean of ˜0.6 Sv, through the Antikithira and Kassos Straits at depths below 400 m and 500 m, respectively. CDW outflowing transports are higher (˜0.8 Sv) in April–June, and lower (˜0.3 Sv) in October–December. Within the upper water layer (0–˜400 m), the transport and the water exchanges through the Straits are controlled by local circulation features, which weaken substantially below 200 m. The Asia Minor Current (AMC) influences the Rhodes and the Karpathos Straits, resulting in a net inflow of water. In contrast, the Mirtoan/West Cretan Cyclone influences the Antikithira and Kithira Straits, where there is a net outflow. In the Kassos Strait, there is a complex interaction between the East Cretan Cyclone, the Ierapetra Anticyclone and the westward extension of the Rhodes Gyre, which results in a variable flow regime. There is a net inflow in autumn and early winter, and a switch to a net outflow in early spring and summer. The total inflow and outflow, throughout all of the Straits, ranged from ˜2 to ˜3.5 Sv, with higher values in autumn and early winter and lower in summer. The AMC carries ˜2 Sv of inflow through the Rhodes and Karpathos Straits, and this accounts for 60–80% of the total inflow. About 10–15% of the total outflow is of CDW, and a further 45–70% occurs through the upper 400 m of the Kithira and Antikithira Straits. The Kassos Strait exhibits a net inflow of ˜0.7 Sv in autumn and early winter, with a net outflow of ˜0.5 Sv in early spring and summer.     

A synthesis of the circulation and hydrography of the South Aegean Sea and the Straits of the Cretan Arc (March 1994–January 1995)

Four seasonal oceanographic cruises were carried out in the Eastern Mediterranean Sea, within the framework of the CEC/MAST-MTP Project PELAGOS, during 1994–1995. The surveys covered the South Aegean Sea and the adjacent open sea regions (southeastern Ionian, northwestern Levantine). Analysis of CTD data revealed that a multiscaled circulation pattern prevails in the area. It differs from the circulations detected during the 1986–87, thus indicating interannual variability. Cyclonic and anticyclonic gyres and eddies are interconnected by currents and jets variable in space and time. Most of the features are persistent, others seem transitional or recurrent. The hydrological structure is also complex and apart from the upper layer does not present basinwide any significant seasonality. Dynamical and hydrological regimes are variable in the upper and intermediate layers at the Straits of the Cretan Arc, while the deep regime seems rather constant. Topographic control is evident on the flows through the straits. The new very dense deep water mass, namely the Cretan Deep Water (CDW) and a well-defined intermediate layer of minimum temperature and salinity, the so-called Transition Mediterranean Water (TMW), consists the new important structural elements of the South Aegean Sea. The CDW outflows towards the deep and bottom layers of the Eastern Mediterranean, thus considerably contributing to the formation of the new, denser Deep and Bottom Water of the Eastern Mediterranean, which sinks and displaces the Eastern Mediterranean Deep Water of Adriatic origin in the adjacent sea regions outside the Aegean Sea.     

Deconstructing the Transvaal Supergroup, South Africa: implications for Palaeoproterozoic palaeoclimate models

Current correlations between the Pretoria and Postmasburg Groups of the Transvaal Supergroup are shown to be invalid. The Postmasburg Group is also demonstrated to be broadly conformable with the underlying Ghaap Group and therefore considerably older (2.4 Ga) than previously supposed. The new stratigraphy documents an extensive (100 Ma) and continuous cold-climate episode with a glacial maximum at the Makganyene Formation diamictite. Iron formations of the underlying Asbesheuwels and Koegas Subgroups and overlying Hotazel Formation have similar origins, related, respectively, to the onset and cessation of the glacial event. This interpretation of the Transvaal Supergroup stratigraphy has significant implications for various Palaeoproterozoic environmental models and for the timing of the development of an oxygenated atmosphere.     

First evidence for the Cenomanian–Turonian oceanic anoxic event (OAE2, ‘Bonarelli’ event) from the Ionian Zone,western continental Greece

Integrated biostratigraphic (planktonic foraminifera, calcareous nannofossils), chemostratigraphic (bulk C and O isotopes) and compound-specific organic geochemical studies of a mid-Cretaceous pelagic carbonate—black shale succession of the Ionian Zone (western Greece), provide the first evidence for the Cenomanian–Turonian oceanic anoxic event (OAE2, ‘Bonarelli’ event) in mainland Greece. The event is manifested by the occurrence of a relatively thin (35 cm), yet exceptionally organic carbon-rich (44.5 wt% TOC), carbonate-free black shale, near the Cenomanian–Turonian boundary within the Vigla limestone formation (Berriasian–Turonian). Compared to the ‘Bonarelli’ black-shale interval from the type locality of OAE2 in Marche–Umbria, Italy, this black shale exhibits greatly reduced stratigraphic thickness, coupled with a considerable relative enrichment in TOC. Isotopically, enriched δ¹³C values for both bulk organic matter (−22.2‰) and specific organic compounds are up to 5‰ higher than those of underlying organic-rich strata of the Aptian-lower Albian Vigla Shale member, and thus compare very well with similar values of Cenomanian–Turonian black shale occurrences elsewhere. The relative predominance of bacterial hopanoids in the saturated, apolar lipid fraction of the OAE2 black shale of the Ionian Zone supports recent findings suggesting the abundance of N₂-fixing cyanobacteria in Cretaceous oceans during the Cenomanian–Turonian and early Aptian oceanic anoxic events.     

Iodine and bromine contents in the Palaeoproterozoic Hotazel iron formation, Transvaal Supergroup, South Africa: A reconnaissance study

A reconnaissance bulk geochemical study was carried out on ten samples from the Palaeoproterozoic Hotazel iron formation, South Africa, with emphasis on iodine and bromine abundances. Very low-absolute contents recorded for both halogens, i.e. 0.08–0.26 μg/g for I and 0.35–1.23 μg/g for Br, indicate that they should largely have been lost during burial diagenesis. Bulk I/Br ratios (0.08–0.50), however, show marginal variation across the selected sample set and broadly resemble those that typify recent marine sediments containing organic matter. The possibility emerges that both elements are organic matter-sourced and may thus provide a potential proxy for the role of biological processes during deposition and diagenesis of Precambrian iron formations.     

No evidence for thermogenic methane release in coal from the Karoo-Ferrar large igneous province

The Early Jurassic Toarcian oceanic anoxic event (T-OAE) and concurrent negative carbon-isotope (δ¹³C) excursion have recently been attributed to either the release of methane (CH₄) clathrates or thermogenic CH₄ gas associated with the Karoo-Ferrar large igneous province (LIP) into coals and organic-rich shales. ¹²C-enriched thermogenic CH₄ production associated with the Karoo-Ferrar would result in residual material being ¹²C-depleted nearer the intrusions. In this study, geochemical analyses (carbon isotopes, volatile matter (VM), vitrinite reflectance (R_o)) are reported for two coal transects associated with dykes intruding the No. 4L coal in the Highveld Coalfield, Karoo Basin, South Africa. VM decreases from over 35% to around 15% in one transect, and the second transect shows a less pronounced decrease (from > 25% to ~ 16%). Accompanying the decrease in VM content is an increase in R_o from background levels of around 0.7% to over 4% adjacent to the dyke; used as a palaeo-geothermometer, R_o values indicate background temperatures of ~ 100 °C increasing to > 300 °C close to the contact. Despite changes in VM and R_o, there are no significant changes in δ¹³C, certainly not of the magnitude that would be expected associated with large-scale thermogenic CH₄ generation. These and other Gondwanan coals have low vitrinite and liptinite contents (components more prone to CH₄ generation), in part explaining the modest decreases in VM adjacent to the dykes. This, combined with the relatively narrow metamorphic aureole surrounding the intrusions and the likelihood that at least some of the volatiles generated by the intrusion were trapped as coalbed CH₄ or condensed as pyrolytic carbon, suggests only limited CH₄ release. In addition, based on original estimates of moisture contents in these coals and the depth at time of intrusion (1,000–2,000 m) the dykes would have lost most of their energy heating and evaporating water, thus having very little remaining energy to generate thermogenic CH₄.     

An empirical analysis of IOPCF oil spill cost data

This paper reports on recent analysis of oil spill cost data assembled by the International Oil Pollution Compensation Fund (IOPCF). Regression analyses of clean-up costs and total costs have been carried out, after taking care to convert to current prices and remove outliers. In the first place, the results of this analysis have been useful in the context of the ongoing discussion within the International Maritime Organization (IMO) on environmental risk evaluation criteria. Furthermore, these results can be useful in estimating the benefit of regulations that deal with the protection of marine environment and oil pollution prevention.     

Geochemistry of Some Marine Fe–Mn Nodules and Crusts with Respect to Pt Contents

Bulk chemical analyses for Pt and Pd in marine Fe–Mn nodules and crusts from different provenances are presented, together with a wide range of elements. Platinum contents vary from 70–328 ppb, whereas Pd contents extend from 0.6–4.7 ppb only. Bromine and Pb show strong positive correlations with Pt. Lead is remarkably enriched in Fe–Mn precipitates over seawater, but Br is a conservative‐type element in seawater and shows no enrichment in Fe–Mn precipitates. Hence, the Pt–Br–Pb element association combines two elements, Br and Pb, of extremely contrasting enrichment factors in Fe–Mn precipitates.