Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

Considerations for conducting incubations to study the mechanisms of As release in reducing groundwater aquifers

Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment.     

The Role of Kelvin Number on Bulge Formation from Estuarine Buoyant Outflows

This investigation examines the influence of the Kelvin number (K) and fractional depth (h/D) on bulge formation from buoyant outflows from an estuary or strait perpendicular to the coastline. Here K = W/R is the ratio of the width (W) at the mouth of the estuary to the deformation radius (R), and h and D are the buoyant layer and ambient ocean depths, respectively. Measurements of velocity and lateral shear (≈ relative vorticity ζ) at the baymouth are reported for experiments on a flat-bottomed rotating turntable. The form of the velocity profile across the mouth depends on the value of K. The buoyant outflow flows across the entire width of the estuary for narrow estuaries (i.e., K ≤ 1). In contrast, for wide estuaries (K > 2), dense oceanic water inflows on the left and the buoyant waters outflow on the right (looking seaward). Velocity profiles of the inflowing oceanic waters are laterally uniform with velocities (V/C ≈ −0.4), whereas velocity profiles of the outflowing buoyant waters are laterally sheared with peak velocities of V/C ≈ 1.0 at the right hand exit. The flow pathways when bulges form comprises an anticyclonic turn offshore of the mouth and a downshelf propagating coastal current. Anticyclonic bulges form for surface-advected outflows h/D < 0.25. Anticyclonic bulges do not form for sufficiently large magnitudes of non-dimensional relative vorticity ζ/f (>0.4), and an additional flow pathway is that buoyant waters recirculate back cyclonically into the estuary at the left-hand (upshelf) side of the estuary. The offshore extent of buoyant waters associated with this cyclonic recirculation can be as large as 7R.     

Urban Dispersion Modelling and Experiments in the Daytime and Nighttime Atmosphere

An analytical model of atmospheric dispersion in urban areas in both daytime and nighttime conditions is presented. The model is based on a Gaussian formulation where the horizontal and vertical diffusion coefficients are determined according to analytical theories. The model is validated with dispersion measurements from field experiments conducted in Oklahoma City, Salt Lake City, St. Louis and London, U.K. The theory is in good agreement with the data for both daytime and nighttime conditions. The data support the conclusion that the magnitude of the nighttime stratification in the urban atmosphere is weak; however, its effects on dispersion are not negligible. The predicted existence of two distinct dispersion regimes, in the near and in the far field, is also confirmed by the data. The good collapse of the data suggests that urban dispersion is governed by the characteristic length scales of atmospheric boundary-layer turbulence, rather than urban canopy length scales that are more likely to affect dispersion only in the vicinity of the source.     

Evaluation of Probe-Induced Flow Distortion of Campbell CSAT3 Sonic Anemometers by Numerical Simulation

The Campbell CSAT3 sonic anemometer is one of the most popular instruments for turbulence measurements in basic micrometeorological research and ecological applications. While measurement uncertainty has been characterized by field experiments and wind-tunnel studies in the past, there are conflicting estimates, which motivated us to conduct a numerical experiment using large-eddy simulation to evaluate the probe-induced flow distortion of the CSAT3 anemometer under controlled conditions, and with exact knowledge of the undisturbed flow. As opposed to wind-tunnel studies, we imposed oscillations in both the vertical and horizontal velocity components at the distinct frequencies and amplitudes found in typical turbulence spectra in the surface layer. The resulting flow-distortion errors for the standard deviations of the vertical velocity component range from 3 to 7%, and from 1 to 3% for the horizontal velocity component, depending on the azimuth angle. The magnitude of these errors is almost independent of the frequency of wind speed fluctuations, provided the amplitude is typical for surface-layer turbulence. A comparison of the corrections for transducer shadowing proposed by both Kaimal et al. (Proc Dyn Flow Conf, 551–565, 1978) and Horst et al. (Boundary-Layer Meteorol 155:371–395, 2015) show that both methods compensate for a larger part of the observed error, but do not sufficiently account for the azimuth dependency. Further numerical simulations could be conducted in the future to characterize the flow distortion induced by other existing types of sonic anemometers for the purposes of optimizing their geometry.     

Simultaneous adoption of risk management strategies to manage the catastrophic risk of maize farmers in Bangladesh

GeoJournal - Risk and uncertainty are distinctive features of agricultural cultivation, which significantly affect the production and income. Risk management is an important way for farmers to...     

Climate negotiations beyond Kyoto: developing countries concerns and interests

Five years down the road from Kyoto, the Protocol that bears that city’s name still awaits enough qualifying ratifications to come into force. While attention has been understandably focussed on the ratification process, it is time to begin thinking about the next steps for the global climate regime, particularly in terms of a deeper inclusion of developing countries’ concerns and interests. This paper begins doing so from the perspective of the developing countries. The principal argument is that we need to return to the basic principles outlined in the Framework Convention on Climate Change in searching for a north-south bargain on climate change. Such a bargain may be achievable if we can realign the policy architecture of the climate regime to its original stated goals of sustainable development.     

Spatial and temporal variation of picoplanktic cyanobacteria population in a density stratified estuary,and the introduction of a cellular gradient number

Spatial and temporal variations in the distribution of the marine picoplanktic cyanobacteria population and mixing conditions were found in the Ebro River estuary outflow to the Mediterranean Sea in Spain. Six sampling surveys were undertaken between July 1999 and February 2000 for distances up to 15 km from the river mouth. Measurements were taken of flow velocity, salinity, temperature, depth and picocyanobacteria (PCB) abundances. Gradient Richardson (Rig) and Reynolds (Re) numbers were determined to evaluate hydrodynamics. In summer, large values of Rig arise from the small flow rates, and small values of velocity shear between the surface fresh water layer and the bottom saline layer; conversely, in winter the large flow rates and attendant large velocity shears between the layers give rise to small values of Rig. Flow conditions in the fall are an intermediate case between the summer and winter cases. Vertical abundance distributions were resolved through the river water, interfacial region, and the bottom salt wedge; longitudinal gradients of PCB abundances were also resolved. Seasonal differences in the PCB abundance values were observed. Analysis of cell numbers (C) showed that the variable dC/dS, the dependence of cell number upon salinity gradient (dS) was critical. A non-dimensional number; the cellular gradient number (Cg) is introduced. Cg has useful biological interpretations that can potentially be included in ecological modeling. For example, Cg = 1 pertains to perfect adaptability of the organism to adjust to changing environmental conditions, whereas Cg = 0 describes total mortality. For a system with strong advection there is insufficient time for cells to adapt to the changing environment, and so those cell counts are unchanged. This is the case for the Ebro estuary in winter as advection of salinity (and hence PCB abundance) dominates the other loss processes for large flow rates.