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Using experimental results at 1·0 GPa for the systemsCaOSiO2, MgOSiO2, CaMgSi2O6SiO2 and CaMgSi2O6Mg2SiO4,and all the currently available phase equilibria and thermodynamicdata at 1 bar, we have optimized the thermodynamic propertiesof the liquid phase at 1·0 GPa. The new optimized thermodynamicparameters indicate that pressure has little effect on the topologyof the CaOSiO2, CaMgSi2O6SiO2, and CaMgSi2O6Mg2SiO4systems but a pronounced one on the MgOSiO2 binary. Themost striking change concerns passage of the MgSiO3 phase fromperitectic melting at 1 bar to eutectic melting at 1·0GPa. This transition is estimated to occur at 0·41 GPa.For the CaMgSi2O6SiO2 and CaMgSi2O6Mg2SiO4 pseudo-binaries,the size of the field clinopyroxene + liquid increases withincreasing pressure. This change is related to the shift ofthe piercing points clinopyroxene + silica + liquid (from 0·375mol fraction SiO2 at 1 bar to 0·414 at 1·0 GPa)and clinopyroxene + olivine + liquid (from 0·191 molfraction SiO2 at 1 bar to 0·331 at 1·0 GPa) thatbound the clinopyroxene + liquid field in the CaMgSi2O6·SiO2and CaMgSi2O6·Mg2SiO4 pseudo-binaries, respectively. KEY WORDS: CaOSiO2; CaMgSi2O6Mg2SiO4; CaMgSi2O6SiO2; experiments; MgOSiO2 相似文献
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