On features of structure of bottom gravity current frontal zone

The results of qualitative laboratory and numerical experiments on two-dimensional non-linear model are described, aiming at an investigation of the structure of the front of bottom gravity current. Non-coincidence of frontal interfaces in density and velocity fields within the bottom gravity current leading (frontal) part is stated on the base of comparative analysis of numerical and laboratory experiments. This fact is experimentally confirmed by field example of marine water inflow into a brackish lagoon. The density gradient along the stream line is shown to be an additional effective criterion for the localization of the frontal zone.     

Metamorphic-hydrothermal parkerite and associated minerals in the Noril’sk ore field

In the Noril’sk ore field, parkerite is a characteristic mineral of sulfide ore that metamorphosed under conditions of zeolite and prehnite-pumpellyite facies and of arsenide-calcite veins. The mineral occurs in ores containing bornite, anhydrite, magnetite, mackinawite (3–5 wt % Ni), valleriite, calcite, ankerite, native silver, native bismuth, violarite, Te-rich bismutohauchecornite, cupropentlandite enriched in Fe, Pd-rich breithauptite (1.5–2.5 wt % Pd), galena enriched in Cu (3.8 wt % Cu), and Ni arsenides and antimonides. Parkerite occurs in those place, where the primary ores have contained pockets and veins of graphic galena and chalcopyrite aggregates with associated Pt-Pd-Au-Ag minerals. Parkerite metacrysts in galena and Fe-Cu-Ni sulfides contain 6–16 and up to 5 wt % Pb, respectively. Parkerite rims replacing PGM aggregates and galena contain 1–3 wt % Pb. In calcite veins hosted in metamorphosed sulfide ores, parkerite is associated with native silver and bismuth, maucherite, cobaltite, chalcocite, and uraninite. Parkerite from these veins contains up to 0.5 wt % Pb. Thus, the Pb and Bi contents in parkerite basically depend on those of replaced minerals. Rare bismutohauchecornite is associated with parkerite.     

The frontal and jet structure south of Africa based on the data of the SR02 section in December of 2009

The frontal structure in the region south of Africa is investigated on the basis of CTD and SADCP measurements along the SR02 hydrophysical section carried by the R/V Akademik Ioffe in December of 2009 from the Cape of Good Hope to 57° S at the Prime Meridian. Eleven jets of the Antarctic Circumpolar Current (ACC) were revealed along the section. These were six jets of the Subantarctic Current (SAC), three jets of the South Polar Current (SPC), and two jets of the Southern Antarctic Current (SthAC). The jet combining the Weddell Front and the Southern Boundary of the ACC was also revealed. All the jets of the SPC based on the data of direct measurements were joined into a single “superjet.” The others were manifested by the local velocity maxima in the surface layer of the ocean. The subtropical water along the section from the Southern Subtropical Front to the Shelf-Slope Front near the African shore was almost completely represented by the Indian Ocean (Agulhas Retroflection) water modified by mixing with the fresher water of the southeastern periphery of the Subtropical Atlantic.     

Transport of Antarctic Bottom Water through passages in the East Azores Ridge (37° N) in the East Atlantic

The structure of northerly overflow of Antarctic Bottom Water (AABW) through passages in the East Azores Ridge (37° N) in the East Atlantic from the Madeira Basin to the Iberian Basin is studied on the basis of hydrographic measurements carried out by the Institute of Oceanology, Russian Academy of Sciences (RAS) in October 2011, historical World Ocean Data Base 2009, and recent data on the bottom topography. The overflow of the coldest layers of this water occurs through two passages with close depths at 16° W (Discovery Gap) and at 19°30′ W (nameless Western Gap). It is shown that it is likely that the role of the latter passage in water transport was underestimated in earlier publications because the water (2.01°C) found in the region north of the Western Gap was cooler than in the region north of the Discovery Gap (2.03°C). In 2011, we found a decrease of 0.01°C in the AABW temperature near the bottom compared to previous measurements in 1982 (from 2.011°C to 2.002°C). Analysis of the historical database shows that this decrease is most likely caused by the cooling trend in the abyssal waters in the East Atlantic basins.     

Calorimetric Study of Natural Basic Copper Phosphate—Pseudomalachite

The thermochemical study of a natural basic copper phosphate, pseudomalachite Cu₅(PO₄)₂(OH)₄ (Virneberg deposit, Germany), was carried out using high-temperature melt solution calorimetry method with a Tian–Calvet microcalorimeter. The enthalpy of formation of the mineral from elements was obtained to be Δ _f H_el(298.15 K) =–3214 ± 13 kJ/mol. The value of the Gibbs energy of pseudomalachite formation calculated using literature data on its standard entropy is Δ _f H_el^°(298.15 K) =–2812 ± 13 kJ/mol.